Case study: Management system verification using responsible care® at Rohm & Haas: Lessons learned

In this article, Rohm & Haas' Responsible Care® implementation strategy and management system verification (MSV) experiences are detailed. Recommendations on how to strengthen the verification process are provided.     

An Assessment of the Valuation Methods Used to Calculate the Index of Sustainable Economic Welfare (ISEW), Genuine Progress Indicator (GPI), and Sustainable Net Benefit Index (SNBI)

For some time now, ecological economists have been putting forward a ‘threshold hypothesis’ – the notion that when macroeconomic systems expand beyond a certain size, the additional cost of growth exceeds the flow of additional benefits. In order to support their belief, ecological economists have developed a number of similar indexes to measure and compare the benefits and costs of growth (e.g., the Index of Sustainable Economic Welfare and the Genuine Progress Indicator). In virtually every instance where an index of this type has been calculated for a particular country, the movement of the index appears to reinforce the existence of the threshold hypothesis. Of late, a number of observers have expressed concerns about whether these alternative indexes reflect concrete reality or the prejudices of ecological economists. In view of these concerns, this paper closely examines the valuation methods used in the calculation the Index of Sustainable Economic Welfare, the Genuine Progress Indicator, and the Sustainable Net Benefit Index. It is argued that a consistent and more robust set of valuation techniques is required in order for these alternative indexes to gain broad acceptability.*Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue.     

Associations between grab sample and integrated radon measurements in dwellings in Maine and Texas

Radon concentrations were measured in several locations in each of approximately 100 dwellings in central Maine and in Houston, TX. Integrated samples were taken during the heating (or cooling) seasons with commercially available passive alpha track devices, while grab samples were taken at the time of integrated sampler deployment. It was found that both indoor and outdoor measurements in both areas were distributed log normally, and that the geometric mean of indoor measurements in Maine was three times higher than that of corresponding measurements in the Houston area. It was also noted that the mean of the indoor grab sample measurements was not significantly different from the mean of the indoor integrated measurements, and that the degree of correlation between the grab samples and a given indoor integrated sample was nearly as good as between integrated samples taken at different living area locations.     

Evaluating the long-term metacommunity dynamics of tree hole mosquitoes

Four different conceptual models of metacommunities have been proposed, termed "patch dynamics," "species sorting", "mass effect", and "neutral". These models simplify thinking about metacommunities and improve our understanding of the role of spatial dynamics both in structuring communities and in determining local and regional diversity. We tested whether mosquito communities inhabiting water-filled tree holes in southeastern Florida, U.S.A., displayed any of the characteristics and dynamics predicted by the four models. The densities of the five most common species in 3-8 tree holes were monitored every two weeks during 1978-2003. We tested relationships between habitat variables and species densities, spatial synchrony, the presence of life history trade-offs, and species turnover. Dynamics showed strong elements of species sorting, but with considerable turnover, as predicted by the patch dynamics model. Consistent with patch dynamics, there was substantial asynchrony in dynamics for different tree holes, substantial species turnover in space and time, and an occupancy/colonization trade-off. Substantial correlations of density and occupancy with tree hole volume were consistent with the species-sorting model, but unlike this model, species did not have permanent refuges. No evidence of mass effects was found, and correlations between habitat variables and dynamics were inconsistent with neutral models. Our results did not match a single model and therefore caution against overly simplifying metacommunity dynamics by using one dynamical characteristic to select a particular metacommunity perspective.     

Controls on atrazine leaching through a soil-unsaturated fractured limestone sequence at Brévilles, France

The objective of this study was to identify the main controls on atrazine leaching through luvisols and calcisols overlying fissured limestone using the dual-permeability model MACRO. The model parameterisation was based on a combination of direct measurements (e.g. hydraulic properties, adsorption and degradation), literature data and calibration against bromide leaching experiments in field plots. A Monte Carlo sensitivity analysis was carried out for a typical application pattern, considering two different depths of unsaturated limestone (15 and 30 m). MACRO calibrations to the field experiments demonstrated the occurrence of strong macropore flow in the luvisol, while transport in the calcisol could be described by the advection-dispersion equation. MACRO simulations of tritium and atrazine leaching qualitatively matched tritium concentration profiles measured in the limestone and atrazine concentrations measured in piezometers and in aquifer discharge via a spring. The sensitivity analysis suggested that the thickness of the limestone, as well as the transport properties and processes occurring in the unsaturated rock (e.g. matrix vs. fissure flow) will have little significant long-term effect on atrazine leaching, mainly because degradation is very slow in the limestone. No mineralization of atrazine was detected in one-year incubations and a mean half-life of 10 years was assumed in the simulations. Instead, processes occurring in the soil exerted the main control on predicted atrazine leaching, especially variations in the degradation rate and the strength of sorption and macropore flow. However, fissure flow in unsaturated rock is expected to exert a much more significant control on groundwater contamination for compounds that degrade more readily in the deep vadose zone.     

Chlorinated paraffins: a review of analysis and environmental occurrence

Chlorinated paraffins (CPs), as technical mixtures of polychlorinated alkanes (PCAs), are ubiquitous in the environment. CPs tend to behave in a similar way to persistent organic pollutants (POPs), leading several countries to impose regulations on the use of CPs. In this article, we review the literature on the properties of CPs, the current analytical tools available to determine CPs in various types of environmental matrices, and concentrations found in the environment. In particular, concentrations of CPs in environmental compartments including air, water, sediments, biota, human food products and human tissues are summarized. Priorities for future research are: improvements in analytical methodologies (reducing the complexity of the analysis, producing reference materials and performing interlaboratory studies); determining background levels of chlorinated paraffins in the environment and human populations (this question should be answered using quality assured analytical tools allowing the intercomparison of data); and investigating the sources of CPs to the environment and to humans.     

Reaction mechanism of arsenic capture by a calcium-based sorbent during the combustion of arsenic-contaminated biomass: A pilot-scale experience

Pilot-scale combustion is required to treat arsenic-enriched biomass in China. CaO addition to arsenic-enriched biomass reduces arsenic emission. CaO captures arsenic via chemical adsorption to form Ca₃(AsO₄)₂. Large quantities of contaminated biomass due to phytoremediation were disposed through combustion in low-income rural regions of China. This process provided a solution to reduce waste volume and disposal cost. Pilot-scale combustion trials were conducted for in site disposal at phytoremediation sites. The reaction mechanism of arsenic capture during pilot-scale combustion should be determined to control the arsenic emission in flue gas. This study investigated three Pteris vittata L. biomass with a disposal capacity of 600 kg/d and different arsenic concentrations from three sites in China. The arsenic concentration in flue gas was greater than that of the national standard in the trial with no emission control, and the arsenic concentration in biomass was 486 mg/kg. CaO addition notably reduced arsenic emission in flue gas, and absorption was efficient when CaO was mixed with biomass at 10% of the total weight. For the trial with 10% CaO addition, arsenic recovery from ash reached 76%, which is an ~8-fold increase compared with the control. Synchrotron radiation analysis confirmed that calcium arsenate is the dominant reaction product.