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181.
氮掺杂氧化钛的简易制备及可见光催化活性的研究 总被引:1,自引:1,他引:0
为开发对可见光响应的催化剂,以尿素为氮掺杂剂,采用简易溶胶-凝胶法制备氮掺杂氧化钛,并以2,4-DCP的降解检验其光催化活性。XRD、BET、XPS和UV-Vis漫反射光谱分析表明,随着氮/钛原子比(N/Ti)的增大,各催化剂晶粒尺寸减小,比表面积增大,锐钛矿相向金红石相的转变得到抑制,除0#样品出现金红石相外,其他催化剂均只出现锐钛矿相;掺入催化剂的N位于晶格O位点和晶格间隙,替代N和间隙N掺杂使催化剂的光吸收发生明显的红移。荧光光谱分析表明,当N/Ti在0~6范围内增加时,反应体系中·OH自由基的产生速率增加,当N/Ti增大至8时,速率则下降。相似的规律也表现在氮掺杂量对光催化活性的影响。适量氮掺杂能增强氧化钛的可见光催化活性,该改性催化剂可用于有机污染物的太阳光激催化降解。 相似文献
182.
环糊精聚合物对苯胺的吸附和脱附性能研究 总被引:2,自引:1,他引:1
以环氧氯丙烷为交联剂,合成和表征了β-环糊精聚合物(β-CDP),从动力学和热力学角度研究了β-CDP对苯胺的吸附性能。研究结果表明,β-CDP对水溶液中的苯胺具有一定的吸附量。用Langmuir, Freundlich和DubininRadushkevich(D-R)吸附等温式拟合了平衡等温数据,并计算出每个模型的参数。苯胺在β-CDP上的吸附符合D-R方程,吸附过程是热力学自发行为。在乙醇中,β-CDP的脱附能力很强,且可循环使用多次。 相似文献
183.
The fate and transport processes of a toxic chemical such as atrazine, an herbicide, in a reservoir are significantly influenced
by hydrodynamic regimes of the reservoir. The two-dimensional (2D) laterally-integrated hydrodynamics and mass transport model,
CE-QUAL-W2, was enhanced by incorporating a submodel for toxic contaminants and applied to Saylorville Reservoir, Iowa. The
submodel describes the physical, chemical, and biological processes and predicts unsteady vertical and longitudinal distributions
of a toxic chemical. The simulation results from the enhanced 2D reservoir model were validated by measured temperatures and
atrazine concentrations in the reservoir. Although a strong thermal stratification was not identified from both observed and
predicted water temperatures, the spatial variation of atrazine concentrations was largely affected by seasonal flow circulation
patterns in the reservoir. In particular, the results showed the effect of flow circulation on spatial distribution of atrazine
during summer months as the river flow formed an underflow within the reservoir and resulted in greater concentrations near
the surface of the reservoir. Atrazine concentrations in the reservoir peaked around the end of May and early June. A good
agreement between predicted and observed times and magnitudes of peak concentrations was obtained. The use of time-variable
decay rates of atrazine led to more accurate prediction of atrazine concentrations, while the use of a constant half-life
(60 days) over the entire period resulted in a 40% overestimation of peak concentrations. The results provide a better understanding
of the fate and transport of atrazine in the reservoir and information useful in the development of reservoir operation strategies
with respect to timing, amount, and depth of withdrawal. 相似文献
184.
185.
风险管理标准化述评 总被引:6,自引:0,他引:6
针对近年来三个重要的风险管理国际标准化文件:Guide 73:2002,澳大利亚的风险管理标准AS/NZS 4360:2004和ISO/CD 31000,以及国际减灾理事会的白皮书,评述了国际标准化文件在风险管理过程环节的基本条款和管理框架.Guide 73指引了风险管理领域最基础的术语,对全球的风险管理制定出通用的语言.它强调对于安全领域,风险管理把焦点放在危害的预防和减轻;AS/NZS 4360明确地确定了相关风险管理的定义,解释了风险管理的程序,重点强调要控制风险产生的后果;ISO/CD 31000聚合了大约26个国家的知识和经验,关注组织建立风险管理流程和不断地进行审评的重要性;IRGC强调群体感知是风险管理的前提,只有当群体认知到可能存在风险时,才会有利于用自己的判断经验去进行风险识别、划分和评价风险,进行风险评估.最后述评了中国风险管理标准化的工作以及在国际风险管理标准化中的贡献. 相似文献
186.
The main focus of this study was to evaluate long term effects of cadmium on forearm bone mineral density after stopping ingestion of cadmium-polluted rice for 10 years in a Chinese population. A total of 532 persons (338 women and 194 men), living in control, moderately and heavily polluted areas, were included in this study. The residents living in the polluted area ceased ingesting cadmium-polluted rice in 1996. All participants were require to answer a questionnaire and the bone mineral density (BMD) was measured by dual energy X-ray absorptiometry (DXA) at the proximal radius and ulna. Samples of urine and blood were collected for determination of cadmium in urine (UCd) and blood (BCd).The BMD of subjects living in the heavily polluted area was significantly lower than that of those living in control area in both men and women (p < 0.01). For the people living in the moderately polluted area, only the women's BMD was greatly lower compared to that in the control area (p < 0.05). The BMD declined with the increasing BCd and UCd in both sexes, especially in the highest level (BCd > 5 µg/L, UCd > 10 µg/g crea) groups (p < 0.01). It was found that there were significant differences in the prevalence of osteoporosis among the different areas (χ2 = 13.046, p = 0.0003) and different UCd groups (χ2 = 4.511, p = 0.0337) in women, but not in men (χ2 = 0.962, p = 0.3268; χ2 = 1.906, p = 0.1675). But a significant difference exists in the prevalence of osteoporosis among different BCd groups in both genders (χ2 = 9.304, p = 0.00229, in women; χ2 = 4603, p = 0.0319, in men). This study suggested that cadmium could play a long-term role on bone and more attention should be paid to cadmium effects on bone metabolism after reduction of exposure. 相似文献
187.
本文以旅游景区的经营模式为研究核心,从现有国内外旅游景区组织结构分析入手,构建了适合我国国情和旅游景区可持续发展要求的两种经营模式:一种是国有国营的次国家公园模式,另一种是完全企业化经营,并且提出了两种模式运作的保障条件。 相似文献
188.
189.
Ka-Hei Lui Wen-Ting Dai Chi-Sing Chan Linwei Tian Bo-Fu Ning Yiping Zhou Xiaolin Song Bei Wang Jinwen Li Jun-Ji Cao Shun-Cheng Lee Kin-Fai Ho 《Environmental science and pollution research international》2017,24(21):17500-17510
Airborne carbonyls were characterized from emitted indoor coal combustion. Samples were collected in Xuanwei (Yunnan Province), a region in China with a high rate of lung cancer. Eleven of 19 types of samples (58%) demonstrated formaldehyde concentrations higher than the World Health Organization exposure limit (a 30-min average of 100 μg m?3). Different positive significant correlations between glyoxal/methylglyoxal and formaldehyde/acetaldehyde concentrations were observed, suggesting possible different characteristics in emissions between two pairs of carbonyl compounds. A sample in the highest inhalation risk shows 29.2 times higher risk than the lowest sample, suggesting different coal sampling locations could contribute to the variation of inhalation risk. Inhabitants in Xuanwei also tend to spend more time cooking and more days per year indoors than the national average. The calculated cancer risk ranged from 2.2–63 × 10?5, which shows 13 types of samples at high-risk level. Cumulative effect in combination with different carbonyls could have contributed to the additive actual inhalation cancer risk. There is a need to explicitly address the health effects of environmentally relevant doses, considering life-long exposure in indoor dwellings. 相似文献
190.