全文获取类型
收费全文 | 2203篇 |
免费 | 192篇 |
国内免费 | 677篇 |
专业分类
安全科学 | 220篇 |
废物处理 | 110篇 |
环保管理 | 156篇 |
综合类 | 1399篇 |
基础理论 | 354篇 |
污染及防治 | 511篇 |
评价与监测 | 122篇 |
社会与环境 | 96篇 |
灾害及防治 | 104篇 |
出版年
2024年 | 7篇 |
2023年 | 40篇 |
2022年 | 120篇 |
2021年 | 96篇 |
2020年 | 109篇 |
2019年 | 67篇 |
2018年 | 82篇 |
2017年 | 107篇 |
2016年 | 100篇 |
2015年 | 121篇 |
2014年 | 163篇 |
2013年 | 189篇 |
2012年 | 174篇 |
2011年 | 194篇 |
2010年 | 161篇 |
2009年 | 127篇 |
2008年 | 169篇 |
2007年 | 133篇 |
2006年 | 121篇 |
2005年 | 98篇 |
2004年 | 70篇 |
2003年 | 71篇 |
2002年 | 64篇 |
2001年 | 72篇 |
2000年 | 61篇 |
1999年 | 54篇 |
1998年 | 56篇 |
1997年 | 47篇 |
1996年 | 39篇 |
1995年 | 36篇 |
1994年 | 29篇 |
1993年 | 27篇 |
1992年 | 16篇 |
1991年 | 10篇 |
1990年 | 6篇 |
1989年 | 6篇 |
1988年 | 6篇 |
1987年 | 7篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 3篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 3篇 |
1973年 | 1篇 |
排序方式: 共有3072条查询结果,搜索用时 500 毫秒
201.
202.
Ning Hou Fengzhao Feng Yan Shi Huiming Cao Chunyan Li Zhi Cao Yi Cheng 《Environmental science and pollution research international》2014,21(17):10386-10398
A highly efficient demulsifying strain, LH-6, was isolated from petroleum-contaminated soil and identified as Bacillus cereus by 16S rDNA gene analysis. It achieved 95.61 and 95.40 % demulsifying ratios within 12 h for water-in-oil (W/O) and oil-in-water (O/W) model emulsions, respectively. Fourier transform infrared spectroscopy (FT-IR) and thin-layer chromatography (TLC) detections indicated that the LH-6’s extracellular biodemulsifiers were different types of lipopeptides for the W/O and O/W emulsions. Optimization of the culture medium composition was conducted to improve the biosynthesis and demulsifying efficiency of the biodemulsifier. The optimal carbon source was liquid paraffin, while waste frying oil could also be an alternative carbon source. The optimal nitrogen sources were ammonium sulfate and yeast extract. To further enhance the biodemulsifier efficiency, the optimal cultivation conditions were determined using response surface methodology (RSM) based on central composite rotation design (CCRD). Using the optimized cultivation conditions, the demulsifying ratios increased to 98.23 and 97.65 % for the W/O and O/W model emulsions, respectively. 相似文献
203.
N. Hattab M. Soubrand R. Guégan M. Motelica-Heino X. Bourrat O. Faure J. L. Bouchardon 《Environmental science and pollution research international》2014,21(17):10470-10480
The efficiency of aided phytostabilization using organic amendments such as ramial chipped wood (RCW) and composted sewage sludge (CSS) was studied on contaminated techno-soils, on nine experimental plots. The objective was to characterize the role of fulvic (FA) and humic acids (HA) on the mobilization of trace elements, specifically As, Cu, Mo, Pb and Zn. Results showed that the addition of CSS increased the total organic carbon and nitrogen content more than with RCW and as a result, the C/N ratio in the CSS soil was higher than in the RCW and non-amended (NE) soil, reflecting the high decomposition of soil organic matter in the CSS soil compared with the other soils. The RCW and CSS amendments increased the hydrogen index (HI) values and the oxygen index (OI) values compared with the NE soil, especially for the soil treated with CSS which contained more aliphatic than aromatic compounds. The addition of CSS to the techno-soil significantly increased the percentage of C org associated with the HA fractions compared with the RCW and NE soils. The soil amended with CSS showed the highest E 4/E 6 ratio and the lowest E 2/E 3 ratio of FA. Zn and As were more abundant in the FA fraction than in the HA fraction, whereas Pb, Cu and Mo were more associated to HA than to FA in the treated and untreated soils, which may explain the difference in their mobility and availability. 相似文献
204.
Dae-Woon Jeong Won-Jun Jang Jae-Oh Shim Won-Bi Han Kyung-Won Jeon Yong-Chil Seo Hyun-Seog Roh Jae Hoi Gu Yong Taek Lim 《Journal of Material Cycles and Waste Management》2014,16(4):650-656
A comparative study on Fe/Al, Fe/Al/Cu, and Fe/Al/Ni catalysts in high-temperature water–gas shift reaction (HT–WGS) using simulated waste-derived synthesis gas has been carried out. The metal oxide (Cu and Ni) and aluminum incorporated Fe catalysts were designed to get highly active HT–WGS catalysts. Despite the high CO concentration in the simulated waste-derived synthesis gas, Fe/Al/Cu catalyst exhibited the highest CO conversion (84 %) and 100 % selectivity to CO2 at a very high gas hourly space velocity (GHSV) of 40,057 h?1. The outstanding catalytic performance is mainly due to easier reducibility, the synergy effect of Cu and Al, and the stability of the magnetite. 相似文献
205.
通过水培实验,研究钙对铬胁迫下李氏禾幼苗生理生化、草酸分泌及铬吸收量的影响,考察钙对李氏禾体内草酸合成的调控,进而促进李氏禾的铬耐性富集能力的作用。结果显示,不同浓度Cr3+胁迫下缺钙处理,李氏禾生长受抑制及质膜过氧化作用加剧,体内总草酸含量为对照处理的113%~169%,且主要表现为水溶性草酸含量显著高于对照,水溶性草酸含量为对照处理的135%~197%;高钙处理,李氏禾细胞膜透性、丙二醛(MDA)含量低于对照,李氏禾叶部总草酸含量为对照处理的125%~155%,且主要表现为不溶性草酸含量显著高于对照,其含量为对照处理的181%~270%。低浓度(0.2、0.4 mmol/L)铬胁迫下,高钙处理总铬含量分别为对照处理的175%和215%,高浓度(0.8、1.0 mmol/L)铬胁迫下,总铬含量与对照处理无显著差异(P>0.05)。可见,添加Ca2+能在一定Cr3+浓度胁迫下,有效缓解铬对李氏禾的毒害,且能通过提高植物体内不溶性草酸含量达到促进植物富集和耐受铬的能力。 相似文献
206.
在以焦炭为填料的生物滴滤塔对挥发性脂肪酸臭气的处理研究中考察了空床停留时间、臭气浓度、体积负荷以及进气温度等参数对净化效果的影响。结果表明,空床停留时间较长时对臭气降解有利。在停留时间超过97 s时,能实现完全降解;此外,净化率随臭气浓度和体积负荷的不断增加呈先增加后降低的趋势。当臭气浓度为24.29 mg/m3即臭气的体积负荷为3 g/(m3·h)时,去除率约为96%;当臭气浓度增至1 345.74 mg/m3即体积负荷增至18 g/(m3·h),去除率达100%;然而,当臭气浓度增至4 934.38 mg/m3即体积负荷增至66 g/(m3·h)时,去除率降至73.1%。另外,进气温度对净化率也有一定程度影响。当进气温度较低时,净化效率相对较高。 相似文献
207.
208.
Hong-Guang Guo Nai-Yun Gao Wen-Hai Chu Lei Li Yong-Ji Zhang Jin-Shan Gu Yu-Liang Gu 《Environmental science and pollution research international》2013,20(5):3202-3213
Photochemical degradation of fluoroquinolone ciprofloxacin (CIP) in water by UV and UV/H2O2 were investigated. The degradation rate of CIP was affected by pH, H2O2 dosage, as well as the presence of other inorganic components. The optimized pH value and H2O2 concentration were 7.0 and 5 mM. Carbonate and nitrate both impeded CIP degradation. According to liquid chromatography–tandem mass spectrometry analysis, four and 16 products were identified in UV and UV/H2O2 system, respectively. Proposed degradation pathways suggest that reactions including the piperazinyl substituent, quinolone moiety, and cyclopropyl group lead to the photochemical degradation of CIP. Toxicity of products assessed by Vibrio qinghaiensis demonstrated that UV/H2O2 process was more capable on controlling the toxicity of intermediates in CIP degradation than UV process. 相似文献
209.
Ming-Hong Wu Liang Tang Gang Xu Jing Ma Ning Liu Liang Wang Jian-Qiu Lei 《Environmental science and pollution research international》2013,20(4):2651-2660
Fourteen and 17 sediment samples were collected from three main rivers of Shanghai in July and November, respectively. Eight polybrominated diphenyl ether (PBDE) congeners (BDE-28, BDE-47, BDE-99, BDE-100, BDE-153, BDE-154, BDE-183, and BDE-209) were detected in these samples to clarify the pollution status in the metropolis. Instrumental analyses showed that the concentrations of ∑8PBDEs ranged from 10.97 to 64.05 ng/g dry weight (dw), with an average value of 29.71 ng/g dw. BDE-209 was the predominant congener accounting for more than 97 % of total PBDEs, followed by BDE-47 and BDE-99. Remarkable spatial and seasonal distributions of PBDE concentrations were observed, suggesting that local sources, seasonal climates, and hydrologic conditions might be the influencing factors. Moderate correlations (r 2?=?0.28–0.51, p?<?0.05) were found between total organic carbon and PBDEs, which indicated that organic carbon content influenced the distributions of PBDEs in sediment of Shanghai at some extent. Hazard quotients revealed PBDEs posed no potential risk to benthic organisms in the study area at present. 相似文献
210.
Wen-Xiu Liu Wei He Ning Qin Xiang-Zhen Kong Qi-Shuang He Hui-Ling Ouyang Fu-Liu Xu 《Environmental science and pollution research international》2013,20(4):2033-2045
The levels of organochlorine pesticides (OCPs) in the water, suspended solids, and sediments from Lake Chaohu during the high water level period were measured by a solid-phase extraction gas chromatograph–electron capture detector. The spatial distributions of the three phases and the water/suspended solids and sediment/water partition coefficients were analyzed. The results showed the following: (1) The mean contents of OCPs in the water, suspended solids, and sediments were 132.4?±?432.1 ng/L, 188.1?±?286.7 ng/g dry weight (dw), and 13.7?±?9.8 ng/g dw, respectively. The dominant OCP components were isodrin (85.1 %) for the water, DDTs (64.4 %) for the suspended solids, and both isodrin (48.5 %) and DDTs (31.8 %) for the sediments. (2) β-HCH was the primary isomer of HCHs in the water and sediments, and the proportions were 61.7 and 41.3 %; γ-HCH was the primary isomer in the suspended solids, accounting for 49.3 %; p,p′-DDT was the dominant content of DDTs in the water and suspended solids, whereas p,p′-DDD was the main metabolite of DDTs in the sediments. (3) The concentrations of contaminants in the water from the western lake were greater than those from the eastern lake, but the concentrations in the suspended solids from the western lake were less than those from the eastern lake. (4) There was no significant correlation between the water–suspended solids partition coefficient K d and the n-octanol–water partition coefficient K ow, and between the sediment–water organic-C weighted sorption coefficients K oc and K ow. 相似文献