Evidence of the involvement of plant ligno-cellulosic structure in the sequestration of Pb: an X-ray spectroscopy-based analysis

European walnut (Juglans regia) plants were grown in pots, on peat soil contaminated with lead (Pb), for four years. European walnut was chosen because it grows in Mediterranean climates, it yields a high biomass, and a fine quality wood. In the above ground parts Pb concentration was 1000 times lower than in roots: in 50 g roots there was 450 mg of Pb. Microanalysis of roots found in periderm more than 50% of the total root Pb. Pb L(III) EXAFS spectroscopy was performed on: root powder from Pb-exposed plants, Pb-impregnated cellulose and lignin. Comparison of plant material with lignin and cellulose helped to envisage a plant disposal strategy for Pb. This may consist in establishing links with large organic molecules, which are abundant constituents of cell walls. EXAFS spectroscopy evidenced the presence of Pb-O bindings within the ligno-cellulosic structure in roots. Lead was scantly conveyed to the shoots, giving to walnut plants an added asset in Pb phytostabilization.     

Flow analysis of PCDD/Fs for Tarragona Province, Spain

The present study was intended to establish an inventory of PCDD/F emissions in Tarragona Province (Catalonia, NE Spain), as a preliminary phase in the development of a flow analysis of PCDD/Fs in this Province. In 1999, global PCDD/F emissions reached a value of 2.24 g I-TEQ/y, which means a density of 3.8 micrograms I-TEQ/inhabitant/y. The low amount of PCDD/Fs emitted to air by the only municipal solid waste incinerator in the Province (approximately 0.04% of the total) has been one of the most notable results. As a reflection of uncertainties in the estimates for individual sources, the 90th percentiles of PCDD/F releases for 1999 ranged up to 4.1 g I-TEQ/y.     

Client preferences by Caribbean cleaning gobies: food,safety or something else?

Predation risk is amongst the most pervasive selective pressures influencing behaviour and animals have been repeatedly shown to trade-off foraging success for safety. We examined the nature of this trade-off in cleaning symbioses amongst Caribbean coral reef fishes. We predicted that cleaning gobies (Elacatinus evelynae and Elacatinus prochilos) should prefer fish clients that pose a low risk of predation (e.g. herbivores) over clients that may have more ectoparasites but pose a higher risk (e.g. piscivores). Our field observations revealed that cleaners did clean preferentially client species with more parasites but predatory and non-predatory clients had similar ectoparasite loads. Despite the lack of a foraging advantage for inspecting predators, cleaners did not avoid risky clients. On the contrary, a larger proportion of visiting predators than non-predators was inspected, gobies initiated more interactions with predatory clients, and predators were attended to immediately upon arrival at cleaning stations. This preferential treatment of dangerous clients may allow the rapid identification of cleaners as non-prey item or may be due to the effect of predators on the rest of the cleaners’ clientele, which avoided cleaning stations whilst predators were present. Dealing with potentially risky clients may allow gobies to regain access to their main food source: non-predatory clients.     

Spatial and temporal distribution of illegal dumping sites in the nature protected area: the Ojców National Park,Poland

The existence of illegal dumping continues to be a worldwide problem, even in nature protected areas, and its distribution is not random. An understanding of the distribution of illegal dumping sites is crucial for the enhancement of effective waste management systems. Therefore, this study aims at a better understanding of spatial and temporal changes to illegal dumping sites in a nature protected area (the Ojców National Park) from 1994 to 2016. The most important spatial factors that control the distribution of illegal dumping sites were the distance from roads and from the field-forest edge. In the last two decades, the number of small dumping sites has increased, whereas the number of large illegal dumping sites has decreased. Moreover, this study presents a model of the potential occurrence of illegal dumping sites, which indicates places that should be under the control of the national park and of local authorities.     

Occurrence of Human Enteric Viruses in Commercial Mussels at Retail Level in Three European Countries

In this study, the prevalence of different enteric viruses in commercial mussels was evaluated at the retail level in three European countries (Finland, Greece and Spain). A total of 153 mussel samples from different origins were analysed for human norovirus (NoV) genogroups I and II, hepatitis A virus (HAV) and hepatitis E virus (HEV). Human adenovirus (HAdV) was also tested as an indicator of human faecal contamination. A full set of controls (such as sample process control, internal amplification controls, and positive and negative controls) were implemented during the process. The use of a sample process control allowed us to calculate the efficiencies of extraction, which ranged from 79 to 0.5?%, with an average value of 10?%. Samples were positive in 41?% of cases, with HAdV being the most prevalent virus detected (36?%), but no significant correlation was found between the presence of HAdV and human NoV, HAV and HEV. The prevalences of human norovirus genogroup II, HEV and human NoV genogroup I were 16, 3 and 0.7?%, respectively, and HAV was not detected. The estimated number of PCR detectable units varied between 24 and 1.4?×?10³?g^?1 of digestive tract. Interestingly, there appeared to be a significant association between the type of mussel species (M. galloprovincialis) and the positive result of samples, although a complete overlap between country and species examined required this finding to be confirmed including samples of both species from all possible countries of origin.     

Advances in the antimicrobial and therapeutic potential of siderophores

Environmental Chemistry Letters - The increasing bacterial resistance from antibiotic overuse has fostered the search for novel antimicrobial strategies. In particular, bacterial systems involving...     

Microbial fuel cell-induced production of fungal laccase to degrade the anthraquinone dye Remazol Brilliant Blue R

Environmental Chemistry Letters - The anthraquinone dye Remazol Brilliant Blue R is largely used in the textile industry. However, its removal from wastewaters is costly and complex. Many methods...     

Identifying pathways to visions of future land use in Europe

Regional Environmental Change - Plausible scenarios of future land use derived from model projections may differ substantially from what is actually desired by society, and identifying such...     

Four priorities for new links between conservation science and accounting research

Article impact statement: New collaborations with accounting research can improve conservation impact of ecosystem-based information systems.     

Microwave inactivation of Bacillus atrophaeus spores in healthcare waste

Public healthcare wastes from the region of Ribeirão Preto, Brazil, pre-sterilized in an autoclave, were inoculated with spores of Bacillus atrophaeus for microwave processing on a laboratory scale. The influence of waste moisture (40%, 50% and 60% wet basis), presence of surfactant, power per unit mass of waste (100, 150 and 200 W/kg) and radiation exposure time (from 5 to 40 min) on the heating curves was investigated. The most favorable conditions for waste heating with respect to moisture and use of surfactant were then applied in an experimental analysis of the degree of inactivation of B. atrophaeus spores as a function of time and power per unit mass of waste. Based on Chick’s and Arrhenius laws, the experimental results were adjusted by the least squares method to determine the activation energies (9203–5782 J/mol) and the Arrhenius pre-exponential factor (0.23 min^?1). The kinetic parameters thus obtained enabled us to predict the degree of inactivation achieved for B. atrophaeus spores in typical healthcare waste. The activation energy was found to decrease as the power per waste mass increased, leading to the conclusion that, in addition to the thermal effect on the inactivation of B. atrophaeus spores, there was an effect inherent to radiation.