Application of a purge and trap TDS-GC/MS procedure for the determination of emissions from flame retarded polymers

Emissions of volatile organic compounds (VOCs) from different thermoplastic polymers used in electrotechnical applications were investigated using a purge and trap procedure that involved adsorption on Tenax GR. Results were compared to those for an operating TV set monitored in a test chamber. The analyses were in both cases carried out using thermodesorption gas chromatography with mass spectrometric detection (TDS-GC/MS). Substances identified were monomers, volatile additives, or related compounds. Special attention was given to the detection of halogenated compounds. Their origin was studied using reference samples and synthetic standards.     

Formation and long-term fate of non-extractable residues in outdoor lysimeter studies

Long-term outdoor lysimeter studies using (14)C-labelled compounds allow the quantification of the 'non-extractable residue fraction'. More than 20 lysimeter studies under realistic environmental conditions showed that more than 80% of residual carbon of the molecule is retained in the topsoil layer even after several years. Generally, 50-90% of this residual radiocarbon is regarded as 'soil bound residue'. Microbial biomass is present in large quantities in topsoil and continuously influences chemical and biochemical alteration of pesticide molecules that may interact directly with the total soil organic matter. Labelling techniques using radioactive isotopes like (14)C have been used to characterize these residues in the humus matrix. Our studies have been directed to the investigation of extractability and/or bioavailability of these residues in long-term investigations.     

Ein neuer Biotest mit der HefeSaccharomyces cerevisiae auf aquatische Toxizit?t

Zusammenfassung  Die G?rleistung der HefeSaccharomyces cerevisiae wird als Bioindikator zur Erfassung aquatoxischer Wirkungen genutzt. Dazu wird die CO₂-Produktion der Hefezellen nach einer Vermehrungsphase unter toxischen Einflüssen gemessen. Als Kennwert (EC₂₀) dient die Schadstoffkonzentration, die die G?rung um 20% mindert. Es werden organische Verbindungen (unpolare und polare Narkotika), anorganische Salze (insbesondere von Schwermetallen), Tenside und Pflanzenschutzmittel geprüft. Die Ergebnisse werden, soweit verfügbar, mit den Daten eines Ciliatentestes mitTetrahymena pyriformis verglichen. Es ergab sich eine übereinstimmung von 90% bei vergleichbarer Testempfindlichkeit. Ergebnisse des Hefetests sind damit ?kotoxikologisch aussagef?hig. Der Test ist reproduzierbar, methodisch einfach zu handhaben und bietet eine Alternative für die Abwasserprüfung, da steriles Arbeiten nicht erforderlich ist. Online-First: 15. Juni 2000     

Spatial and temporal variability of composition of urban effluents in the island of Lesvos, Greece

The spatial and temporal variability in the composition of effluents of the coastal town of Mytilene, island of Lesvos, Greece, was investigated in 8 sewers of the town. Differences were found in the quality of effluents between the old and new parts of the town and were attributed mainly to the different design and construction of the sewers, as well as to the occasional discharge of septage into the sewerage network in parts of the town. During summer the population and water consumption increase, leading to partial dilution of the organic load. However, in the same period (July), the concentrations of dissolved Zn and particulate Pb were enriched. The reasons for such an increase are not clear. At present the seasonal metal peaks (Pb and Zn) are attributed to the increased traffic (Pb and Zn) and to increased corrosion under the prevailing weather conditions of the water supply network, which includes a very large number of galvanized storage tanks (Zn).     

Biotopic Variation and Phenogeography of Dreissena polymorpha (Pallas)

The phenetic structure of Dreissena polymorpha populations in different water bodies is considered. The phenotypes of shell pattern and sculpture are identified and described using a scheme based on elementary characters, or pattern elements. It is shown that the frequencies of phenes in mollusks from different biotopes of the cooling system of two thermal power plants differ significantly. The data on species phenogeography are reviewed.     

Uncovering local perspectives on humanitarian assistance and its outcomes

This paper draws on a study of Angolan refugees in Zambia to suggest ways that the perspectives and interests of the local population can be included in the assessment of relief interventions. Taking an actor-oriented approach, the paper suggests stepping back from the categorisation of the situation as an emergency and particular groups of people as the beneficiaries. Such categories are imposed from outside and may not reflect local people's outlook on the situation. In the case of Angolans in Zambia, the category of refugees had dissolved in the border villages to the extent that it was practically impossible to distinguish between refugees and hosts. This was in contrast to the official settlements where people were marked out as refugees and the label was maintained and reproduced over many years. Investigating outcomes in the border villagers in terms of refugees and the refugee problem would have been futile. The paper calls for evaluations of humanitarian assistance in complex emergencies to look beyond the 'beneficiaries' and to investigate the wider context of 'normality'. Neglecting the life and world of local people will make it impossible to understand the process by which external interventions are mediated at the local level to give particular outcomes, and valuable lessons which could help alleviate suffering will be lost.     

The challenge of electronic waste (e-waste) management in developing countries

Information and telecommunications technology (ICT) and computer Internet networking has penetrated nearly every aspect of modern life, and is positively affecting human life even in the most remote areas of the developing countries. The rapid growth in ICT has led to an improvement in the capacity of computers but simultaneously to a decrease in the products lifetime as a result of which increasingly large quantities of waste electrical and electronic equipment (e-waste) are generated annually. ICT development in most developing countries, particularly in Africa, depends more on secondhand or refurbished EEEs most of which are imported without confirmatory testing for functionality. As a result large quantities of e-waste are presently being managed in these countries. The challenges facing the developing countries in e-waste management include: an absence of infrastructure for appropriate waste management, an absence of legislation dealing specifically with e-waste, an absence of any framework for end-of-life (EoL) product take-back or implementation of extended producer responsibility (EPR). This study examines these issues as they relate to practices in developing countries with emphasis on the prevailing situation in Nigeria. Effective management of e-waste in the developing countries demands the implementation of EPR, the establishment of product reuse through remanufacturing and the introduction of efficient recycling facilities. The implementation of a global system for the standardization and certification/labelling of secondhand appliances intended for export to developing countries will be required to control the export of electronic recyclables (e-scarp) in the name of secondhand appliances.     

University of Benin water supply system: Microbiological and physico-chemical assessments

The microbiological and physico-chemical characteristics of the drinking water supplied by the Central Borehole at the University of Benin, Ugbowo Campus were investigated. The investigation entailed assessment of the pH, turbidity, total suspended solids, total dissolved solids, dissolved oxygen, temperature, salinity, conductivity, nitrate, nitrite, phosphate, sulphate, chloride, N-nitroso compounds, cadmium, chromium, nickel, lead, zinc, manganese, iron, coliform count, BOD₅ and COD of the water at the Central Borehole and at ten residential quarters. The assessment indicated that the water was fit for drinking and other domestic applications. Results were also compared with WHO, EU and Nigeria FEPA standards. The results showed that the pH values of the water (5.01–5.86) and total coliform count (1–2/100 ml) expressed as MPN were outside the limits set by the WHO, EU and FEPA. The data also showed that the other water quality parameters assessed were within WHO, EU and FEPA permissible limits. The results of ANOVA showed that significant changes occurred during distribution.     

Do Nutrients Limit Algal Periphyton in Small Blackwater Coastal Plain Streams?1

Abstract: We examine the potential for nutrient limitation of algal periphyton biomass in blackwater streams draining the Georgia coastal plain. Previous studies have investigated nutrient limitation of planktonic algae in large blackwater rivers, but virtually no scientific information exists regarding how algal periphyton respond to nutrients under different light conditions in smaller, low‐flow streams. We used a modification of the Matlock periphytometer (nutrient‐diffusing substrata) to determine if algal growth was nutrient limited and/or light limited at nine sites spanning a range of human impacts from relatively undisturbed forested basins to highly disturbed agricultural sites. We employed four treatments in both shaded and sunny conditions at each site: (1) control, (2) N (NO₃‐N), (3) P (PO₄‐P), and (4) N + P (NO₃‐N + PO₄‐P). Chlorophyll a response was measured on 10 replicate substrates per treatment, after 15 days of in situ exposure. Chlorophyll a values did not approach what have been defined as nuisance levels (i.e., 100‐200 mg/m²), even in response to nutrient enrichment in sunny conditions. For Georgia coastal plain streams, algal periphyton growth appears to be primarily light limited and can be secondarily nutrient limited (most commonly by P or N + P combined) in light gaps and/or open areas receiving sunlight.     

OPTIMAL RESERVOIR MANAGEMENT AND CROP PLANNING UNDER DETERMINISTIC AND STOCHASTIC INFLOWS1

ABSTRACT: This study analyzes planning under deterministic and stochastic inflows for the Mayurakshi project in India. Models are developed to indicate the optimal storage of reservoir water, the transfer of water to the producing regions, and the spillage of water from the reservoir, if needed. A deterministic programming model was first formulated to represent the existing situation. A chance-constrained model then was constructed to evaluate potential violations of the deterministic model. Both models were quantified for the command area. Data were collected from surveys of the area and from government agencies. Both the deterministic and change-constrained models suggest a more intensive cropping program in the region. Both emphasize more dependence on rabi and less on kharif crops. The chance-constrained especially suggests use of more water in the rabi season. Important chances in cropping programs and labor use take place under the chance-constrained model.