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431.
A simple, sensitive, convenient and low cost spectrofluorometric technique for determination of quinalphos is described. Quinalphos is decomposed with sodium ethoxide. Resultant sodium diethyl thiophosphate (Na-DETP) is extracted with a cationic fluorescein as ion pair complex into 1-chloro-2-nitrobenzene. The fluorescence of the ion pair, fluorescein-DETP is measured at 530 nm after excitation at 490 nm. This technique is applicable for the determination of quinalphos in water, food grains and vegetable samples up to ng level with Amberlite XAD-4. 相似文献
432.
Mehaffey MH Nash MS Wade TG Ebert DW Jones KB Rager A 《Environmental monitoring and assessment》2005,107(1-3):29-44
The Catskill/Delaware reservoirs supply 90% of New York City’s drinking water. The City has implemented a series of watershed protection measures, including land acquisition, aimed at preserving water quality in the Catskill/Delaware watersheds. The objective of this study was to examine how relationships between landscape and surface water measurements change between years. Thirty-two drainage areas delineated from surface water sample points (total nitrogen, total phosphorus, and fecal coliform bacteria concentrations) were used in step-wise regression analyses to test landscape and surface-water quality relationships. Two measurements of land use, percent agriculture and percent urban development, were positively related to water quality and consistently present in all regression models. Together these two land uses explained 25 to 75% of the regression model variation. However, the contribution of agriculture to water quality condition showed a decreasing trend with time as overall agricultural land cover decreased. Results from this study demonstrate that relationships between land cover and surface water concentrations of total nitrogen, total phosphorus, and fecal coliform bacteria counts over a large area can be evaluated using a relatively simple geographic information system method. Land managers may find this method useful for targeting resources in relation to a particular water quality concern, focusing best management efforts, and maximizing benefits to water quality with minimal costs.The United States Environmental Protection Agency through its Office of Research and Development funded and managed the research described here. It has been subjected to Agency’s administrative review and approved for publication as an EPA document. 相似文献
433.
The increasing use of the landscape by humans has led to important diminutions of natural surfaces. The remaining patches
of wild habitat are small and isolated from each other among a matrix of inhospitable land-uses. This habitat fragmentation,
by disabling population movements and stopping their spread to new habitats, is a major threat to the survival of numerous
plant and animal species. We developed a general model, adaptable for specific species, capable of identifying suitable habitat
patches within fragmented landscapes and investigating the capacity of populations to move between these patches. This approach
combines GIS analysis of a landscape, with spatial dynamic modeling. Suitable habitat is identified using a threshold area
to perimeter ratio. Potential movement pathways of species between habitat patches are modeled using a cellular automaton.
Habitat connectivity is estimated by overlaying habitat patches with movement pathways. The maximum potential population is
calculated within and between connected habitat patches and potential risk of inbreeding within meta-populations is considered.
The model was tested on a sample map and applied to scenario maps of predicted land-use change in the Peoria Tri-county region
(IL). It (1) showed area of natural area alone was insufficient to estimate the consequences on animal populations; (2) underscored
the necessity to use approaches investigating the effect of land-use change spatially through the landscape and the importance
of considering species-specific life history characteristics; and (3) highlighted the model's potential utility as an indicator
of species likelihood to be affected negatively by land-use scenarios and therefore requiring detailed investigation. 相似文献
434.
Bhanarkar AD Srivastava A Joseph AE Kumar R 《Environmental monitoring and assessment》2005,109(1-3):73-80
Air pollution in the workplace environment due to industrial operation have been found to cause serious occupational health
hazard. Similarly, heat stress is still most neglected occupational hazard in the tropical and subtropical countries like
India. The hot climate augments the heat exposure close to sources like furnaces. In this study an attempt is made to assess
air pollution and heat exposure levels to workers in the workplace environment in glass manufacturing unit located in the
State of Gujarat, India. Samples for workplace air quality were collected for SPM, SO2, NO2 and CO2 at eight locations. Results of workplace air quality showed 8-hourly average concentrations of SPM: 165–9118 μg/m3, SO2: 6–9 μg/m3 and NO2: 5–42 μg/m3, which were below the threshold limit values of workplace environment. The level of CO2 in workplace air of the plant was found to be in the range 827–2886 μg/m3, which was below TLV but much higher than the normal concentration for CO2 in the air (585 mg/m3). Indoor heat exposure was studied near the furnace and at various locations in an industrial complex for glass manufacturing.
The heat exposure parameters including the air temperature, the wet bulb temperature, and the globe parameters were measured.
The Wet Bulb Globe Temperature (WBGT), an indicator of heat, exceeded ACGIH TLVs limits most of the time at all the locations
in workplace areas. The recommended duration of work and rest have also been estimated. 相似文献
435.
Wiersma YF 《Environmental monitoring and assessment》2005,100(1-3):1-9
Environmental benchmarks are widely used in Canadian environmental assessment as a standard against which to monitor air or water quality in response to human activities in the environment. Recent work in Canada has developed the concept of ecological benchmarks as a complement to environmental benchmarks. However, implementation of ecological benchmarks may be challenging. This paper presents an analogy between ecological benchmarks and the more commonly used environmental benchmarks, as an attempt to increase understanding and use of ecological benchmarks in resource management, assessment, and monitoring. Ecological benchmarks, and their corresponding indicators, will be challenging to identify and use. However, through the use of the principles of adaptive management, effective ecological indicators and benchmarks can be established. Although it is essential that ecological benchmarks are site-specific, the analogy and general principles outlined here are applicable to assessment and monitoring in any part of the world. 相似文献
436.
A modular approach to Integrated Assessment modeling 总被引:1,自引:0,他引:1
In this paper, we present a new approach to model coupling that probably forms the methodological basis of a new generation of Integrated Assessment models. This approach respects the knowledge and expertise that is embodied in existing models and encourages their gradual evolution. Modularity is the guiding principle. Our approach is distinguished by the way modules are coupled which is based on an interplay of a job control module, a numerical coupling module, and a couple of stand-alone functional modules. The numerical coupling module - the core component - serves to treat the feedbacks between the functional modules. A first implemented example that couples an economic and a climate module by means of a two-phase meta-optimization is presented here. The algorithm and mathematical structure behind are discussed as well as important features such as convergence behavior and reliability. 相似文献
437.
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440.
Summary As stated at the beginning of this paper conclusions reached thus far cannot be discussed in this paper. However, a great deal of information is available for examination.EPA displayed its ability to coordinate widely separated laboratories, both Federal and private, into a smooth working team in a very short period of time. A very comprehensive study plan was also developed and implemented quickly. EPA was fortunate to have already had GCA under contract when the emergency arose. In no small part the success of the field effort was due to the managerial and technical abilities of the GCA team.Within a period of 6 weeks a plan was developed, a prime contractor retained, subcontractors hired, and field activities begun. Within a period of 3 months in excess of 8600 field samples were collected and over 12,000 field and QC samples were analyzed. During this same period 2 major data systems were developed, debugged, and placed into operation.In short this EPA project was probably the most comprehensive multimedia field project ever attempted by EPA and certainly the data is being subjected to the most strenuous quality control measures ever imposed by this Agency. The entire program is presently under peer review and the results are being prepared for publication by EPA Headquarters.Note. Originally intended to be published as part of the special issue on Exposure Monitoring: An International Workshop (Las Vegas, Nevada, October 19–22, 1981). 相似文献