Trace metals solubility in rainwater: evaluation of rainwater quality at a watershed area, Istanbul

In this study, 79 bulk precipitation samples were collected at two sampling sites near Büyükçekmece Lake, one of the important drinking water sources of Istanbul, for the period of October 2001 to July 2002. The study comprised the determination of trace and toxic metals concentrations in rain water. The concentrations of the metals in this study were found to be higher than those reported by other researchers around the world. The solubility of toxic metals was found in the order of Cd > Cu > V > Zn > Ni > Pb > Cr. Solubility of metals under acidic conditions (pH < 5.5) was approximately five times higher than those under neutral conditions with Cd as the most soluble metal (50% soluble). Statistical evaluations including seasonal variations, crustal enrichment factors, and correlation matrix were discussed to identify the possible sources of these pollutants. The study revealed that anthropogenic elements were highly enriched especially for Cd > Cu > Pb which were found to be highly enriched. Significant portion of Cu and Pb could be increased by the effect of local sources like cement industry in the area; however, the rest of the investigated trace metals could be brought to the sampling site by long-range transport to the Büyükçekmece Lake watershed area.     

Cover Image

The cover image is based on the Original Article Noninvasive prenatal paternity testing by means of SNP-based targeted sequencing by Jacqueline Chor Wing Tam et al., https://doi.org/10.1002/pd.5595 .

     

An online air pollution forecasting system using neural networks

In this work, an online air pollution forecasting system for Greater Istanbul Area is developed. The system predicts three air pollution indicator (SO(2), PM(10) and CO) levels for the next three days (+1, +2, and +3 days) using neural networks. AirPolTool, a user-friendly website (http://airpol.fatih.edu.tr), publishes +1, +2, and +3 days predictions of air pollutants updated twice a day. Experiments presented in this paper show that quite accurate predictions of air pollutant indicator levels are possible with a simple neural network. It is shown that further optimizations of the model can be achieved using different input parameters and different experimental setups. Firstly, +1, +2, and +3 days' pollution levels are predicted independently using same training data, then +2 and +3 days are predicted cumulatively using previously days predicted values. Better prediction results are obtained in the cumulative method. Secondly, the size of training data base used in the model is optimized. The best modeling performance with minimum error rate is achieved using 3-15 past days in the training data set. Finally, the effect of the day of week as an input parameter is investigated. Better forecasts with higher accuracy are observed using the day of week as an input parameter.     

Allozyme polymorphisms and heavy metal levels in the green-lipped mussel Perna viridis (Linnaeus) collected from contaminated and uncontaminated sites in Malaysia

It has been widely reported that heavy metal contamination in coastal waters can modify the allozyme profiles of marine organisms. Previous studies have recorded elevated metal concentrations in sediments and mussel tissues off Peninsular Malaysia. In the present study, horizontal starch gel electrophoresis was carried out to estimate the levels of allelic variation of the green-lipped mussel, Perna viridis, collected from one contaminated and three relatively uncontaminated sites off Peninsular Malaysia. Fourteen polymorphic loci were observed. In addition, the concentrations of cadmium, copper, lead, mercury and zinc were determined in the sediments and in the soft tissues of the mussels. Mussels from contaminated site, evidenced by high metal pollution indices (MPI) of the sediment and the mussel tissues, showed the highest percentage of polymorphic loci (78.6%), while those collected from the uncontaminated sites had lower MPI of the sediment and mussel tissue, and exhibited lower percentages of polymorphic loci (35.7-57.1%). The population from the contaminated site showed the highest excess of heterozygosity (0.289) when compared to that of the populations from the three uncontaminated sites (0.108-0.149). Allozyme frequencies at the phosphoglucomutase (PGM; E.C. 2.7.5.1) locus also differed between the contaminated and uncontaminated populations. Previous studies have shown that exposure to heavy metals can select or counter-select for particular alleles at this locus. The present results suggest that allozyme polymorphism in P. viridis is a potential biomonitoring tool for heavy metal contamination but further validation is required.     

Waste Management in the European Union: National Self-Sufficiency and Harmonization at the Expense of Economic Efficiency?

/ Since 1975, the European Union (EU) has developed an impressive body of waste management legislation, although, according to the principle of subsidiarity, responsibilities belong to the most local level at which the tasks can be carried out effectively. Using economic theory, this paper examines several factors that influence the efficient distribution of regulatory authority among the EU and the member states. We specifically analyze the role of harmonization that, in our opinion, will often lead to an overcentralization. Within this context, a second issue is becoming more important, as ongoing discussions show. If no consensus can be reached about harmonization, should member states be allowed to stop cross-border shipments of waste, or should the EU strive for a common market for waste? We take the position that most objections against waste shipments are not convincing, especially if the member states implement minimum standards for landfills and waste processing facilities and common information and control systems. Competition between different national regulations within adequate constraints that, e.g., control transboundary externalities leads to more efficient waste management structures in Europe than national self-sufficiency or centralized decision-making at the EU level. KEY WORDS: Waste management; European Union; Subsidiarity; Institutional competition; Harmonization; Cross-border shipments of waste     

Aeolian contributions of trace metals to marine sediments of Kuwait

Concentrations of silver, cadmium, chromium, iron, manganese, nickel, lead, vanadium, and zinc were determined in dust fallout samples from eight inland locations in Kuwait. Results were used to calculate enrichment factors for metals relative to their abundance in the continental crust using Fe as the conservative element. Five metals (Cu, Cr, Mn, Ni, and V) showed enrichment factors that were approximately unity (1.3–4.7). Higher enrichment factors for the rest (24–421) suggested an anthropogenic contribution for Ag, Cd, Pb, and Zn. However, all metals in dust fallout (except Pb and Zn) showed a degree of enrichment relative to unpolluted marine sediments that was approximately unity, suggesting a substantial aeolian contribution to trace metals in marine surface sediments. Higher enrichments for Pb and Zn probably reflect a larger input from local pollution sources. This is particularly true for lead, the enrichment of which showed a stronger association with the distribution of urban population. Probable contributions of aeolian transport to a band of elevated lead concentrations in marine surface sediments are discussed.     

Gaseous and particulate polycyclic aromatic hydrocarbons (PAHs) emissions from commercial restaurants in Hong Kong

Commercial cooking emissions are important air pollution sources in a heavily urbanized city. Exhaust samples were collected in six representative commercial kitchens including Chinese restaurants, Western restaurants, and Western fast-food restaurants in Hong Kong during peak lunch hours. Both gaseous and particulate emissions were evaluated. Eight gaseous and twenty-two particulate polycyclic aromatic hydrocarbons (PAHs) were quantified in this study. In the gaseous phase, naphthalene (67-89%) was the most abundant PAH in all of the exhaust samples. The contribution of acenaphthylene in the gaseous phase was significantly higher in emissions from the Chinese restaurants, whereas fluorene was higher in emissions from the Western cooking style restaurants (i.e., Western restaurants and Western fast-food restaurants). Pyrene is the most abundant particulate PAH in the Chinese restaurants (14-49%) while its contribution was much lower in the Western cooking style restaurants (10-22%). Controlled cooking conditions were monitored in a staff canteen to compare the emissions from several different local cooking styles, including deep frying, steaming, and mixed cooking styles (combination of steaming and frying). Deep frying produced the highest amount of total gaseous PAHs, 6 times higher than the steaming. However, steaming produced the highest particulate emissions. The estimated annual gaseous PAH emissions for the Chinese restaurants, Western restaurants, and Western fast-food restaurants were 255, 173, and 20.2 t y(-1) whereas 252, 1.9, and 0.4 t y(-1) were estimated for particulate phase PAH emissions. The study provides useful information and estimates for PAH emissions from commercial cooking exhaust in Hong Kong.     

Computed tomographic reconstruction of a fetus with the dysgnathia complex (agnathia-otocephaly)

The dysgnathia complex (agnathia-otocephaly) (AO) is a lethal malformation that consists of congenital absence of the lower jaw with union or close approximation of the lower ears on the front of the neck, microstomia, and hypoglossia. We present a novel case of agnathia-otocephaly with associated organomegaly and the use of postmortem 3-D computed tomographic rendering. Copyright © 2006 John Wiley & Sons, Ltd.