The evolution of pollution profile and health risk assessment for three groups SVOCs pollutants along with Beijiang River,China

Three important groups of semi-volatile organic compounds (SVOCs), polycyclic aromatic hydrocarbons (PAHs), organic chlorinated pesticides (OCPs) and phthalate esters (PAEs), were produced by various human activities and entered the water body. In this study, the pollution profiles of three species including 16 PAHs, 20 OCPs and 15 PAEs in water along the Beijiang River, China were investigated. The concentrations of Σ₁₆PAHs in the dissolved and particulate phases were obtained as 69–1.5 × 10² ng L^?1 and 2.3 × 10³–8.6 × 10⁴ ng g^?1, respectively. The levels of Σ₂₀OCPs were 23–66 ng L^?1 (dissolved phase) and 19–1.7 × 10³ ng g^?1 (particulate phase). Nevertheless, higher levels of PAEs were found both in the dissolved and particulate phases due to abuse use of plastic products. Furthermore, non-cancer and cancer risks caused by these SVOCs through the ingestion absorption and dermal absorption were also assessed. There was no non-cancer risk existed through two kinds of exposure of them at current levels, whereas certain cancer risk existed through dermal absorption of PAHs in the particulate phase in some sampling sites. The results will show scientific insights into the evaluation of the status of combined pollution in river basins, and the determination of strategies for incident control and pollutant remediation.     

区域水环境系统脆弱性指标体系及综合决策模型研究

目前水环境系统脆弱性研究主要局限于水环境系统的单方面脆弱性研究,过于片面化,需要综合考虑水资源、水环境质量、旱涝灾害、社会经济以及生态环境等方面的脆弱性。根据水环境系统脆弱性是系统状态受到系统压力引起的敏感性以及系统状态对系统压力的适应性响应的观点,采用“压力-状态-响应”模式构建区域水环境系统脆弱性指标体系。区域水环境系统脆弱性研究中客观存在诸多不确定性,利用联系数描述上述不确定性过程中差异度系数在［-1,1］上取值仍存在不确定性,为此,构造三角模糊数刻画差异度系数取值的不确定性,给出三角模糊联系数的基本形式,取置信水平得出置信区间联系数,采用期望-方差排序法对置信区间联系数进行决策分析,建立基于三角模糊联系数的系统综合决策模型。此模型用于安徽省水环境系统脆弱性评价的结果表明,安徽省区域水环境系统脆弱等级介于［2.731 3.620］之间,脆弱性状况不容乐观,应采取相应措施改善区域水环境质量,降低区域水环境系统脆弱性,保障区域社会经济及生态环境的可持续发展     

密云水库上游河流底栖动物群落结构与水质评价

于2013年5月至10月对密云水库上游河流中大型底栖无脊椎动物(以下简称底栖动物)进行了采样调查。结果表明,采集到的底栖动物隶属于4门10纲16目45科,其中以节肢动物种类最多,占总数的80%,且水生昆虫占总数的67%,出现频率最高的是节肢动物门蜉蝣目蜉蝣科的昆虫,出现频率达87%;从分布来看,白河流域采集到的底栖动物种类最多、密度最高,而潮河流域采集到的底栖动物生物量最大;以底栖动物为指示生物的水质评价结果显示,密云水库上游河流中50%采样点的水质为Ⅰ级(清洁),其余50%为Ⅱ级(轻微污染),水质整体较好,与现场生境调查和水质监测的结果相吻合。     

微波消解-流动注射分光光度法测定土壤中的总磷

采用热效率高的微波消解系统对土壤中的总磷进行消解,建立了微波消解-流动注射分光光度法测定土壤中总磷的方法,该方法对比HJ632-2011碱熔-钼锑抗分光光度法具有快速、简便、节约试剂等特点。本文用两种分析方法对实际土壤样品及标准样品进行定量测定,所得结果表明微波消解法能快速测定大量土壤样品的总磷。     

公路项目竣工环境保护验收调查中的重点与难点

公路项目是生态影响类建设项目,本文以达渝高速公路三期工程(大竹城西至重庆段)竣工环境保护验收调查为例,以验收调查的技术路线、方法、工程建设对生态环境的影响及声环境的影响为重点进行调查,对在公路项目竣工环境保护验收调查中存在的问题和重点进行总结。     

安徽省旅游业转型升级对策研究

随着我国经济增长结构和产业增长方式调整转变,旅游业转型升级成为提高旅游业经济效益,实现旅游业可持续发展的必然要求。在全面分析安徽省旅游业转型升级背景的基础上,结合安徽省旅游业转型升级的优势条件与制约因素,提出安徽省旅游业在旅游产业结构、旅游产品、旅游企业、旅游市场、旅游人才等方面转型升级的路径与对策。     

The structure of the fire fighting foam surfactant Forafac®1157 and its biological and photolytic transformation products

For several decades, perfluorooctane sulfonate (PFOS) has widely been used as a fluorinated surfactant in aqueous film forming foams used as hydrocarbon fuel fire extinguishers. Due to concerns regarding its environmental persistence and toxicological effects, PFOS has recently been replaced by novel fluorinated surfactants such as Forafac®1157, developed by the DuPont company. The major component of Forafac®1157 is a 6:2 fluorotelomer sulfonamide alkylbetaine (6:2 FTAB), and a link between the trade name and the exact chemical structure is presented here to the scientific community for the first time. In the present work, the structure of the 6:2 FTAB was elucidated by ¹H, ¹³C and ¹⁹F nuclear magnetic resonance spectroscopy and high-resolution mass spectrometry. Moreover, its major metabolites from blue mussel (Mytilus edulis) and turbot (Scophthalmus maximus) and its photolytic transformation products were identified. Contrary to what has earlier been observed for PFOS, the 6:2 FTAB was extensively metabolized by blue mussel and turbot exposed to Forafac®1157. The major metabolite was a deacetylated betaine species, from which mono- and di-demethylated metabolites also were formed. Another abundant metabolite was the 6:2 fluorotelomer sulfonamide. In another experiment, Forafac®1157 was subjected to UV-light induced photolysis. The experimental conditions aimed to simulate Arctic conditions and the deacetylated species was again the primary transformation product of 6:2 FTAB. A 6:2 fluorotelomer sulfonamide was also formed along with a non-identified transformation product. The environmental presence of most of the metabolites and transformation products was qualitatively demonstrated by analysis of soil samples taken in close proximity to an airport fire training facility.     

Evidence for the inhibitory effects of silver nanoparticles on the activities of soil exoenzymes

Silver nanoparticles (AgNPs) are well known to have antimicrobial ability, but very little is known about the effect of AgNPs on soil exoenzyme activities, which reflect the potential of a soil to support biochemical processes. This study provides evidence of the inhibitory effects of AgNPs on the activities of soil exoenzymes. Six exoenzymes related to nutrient cycles (urease, acid phosphatase, arylsulfatase, β-glucosidase) and the overall microbial activity (dehydrogenase, fluorescein diacetate hydrolase) were tested in soils treated with AgNPs (1, 10, 100 and 1000 μg g(-1)) and silver ion (0.035, 0.175, 0.525, 1 and 1.5 μg g(-1)). AgNPs were capable of inhibiting the activities of all the exoenzymes tested in this study. Especially, the urease and dehydrogenase activities were significantly related to the presence of AgNPs. The effects of silver ions dissolved from the AgNPs were not significant, indicating the adverse effects caused by AgNPs themselves. This study suggested that AgNPs negatively affect soil exoenzyme activities, with the urease activity especially sensitive to AgNPs.     

聚环氧琥珀酸萃取锰泥残渣中铬的研究

聚环氧琥珀酸(PESA)是一种具有无磷及非氮结构、环境友好型水溶性聚合物,且具有螯合多价金属阳离子的性能和可生物降解性的特征,选取其作为锰泥残渣中铬的螯合萃取剂,研究了不同pH、螯合萃取剂剂量、搅拌时间下PESA对铬的萃取率。结果表明:(1)最佳萃取条件为pH=4、PESA剂量30mg/g、搅拌时间60min;在最佳萃取条件下,铬的萃取率可达95%。(2)从结构上看,PESA是由醚基和羧基基团组成的高分子聚合物,羧基基团是与金属离子作用的主要官能团,它对Ca2+、Mg2+、Zn2+、Cr(Ⅲ)、Cr(Ⅵ)和Pb2+等有较强的螯合能力;从溶液的配位角度看,PESA与金属有较强的结合能力。因此,PESA对锰泥残渣中的铬有萃取作用。     

垃圾渗滤液发酵产氢和产甲烷特性研究

以实际垃圾渗滤液作为厌氧发酵基质,研究了初始pH为7.0、中温(37℃)条件下的发酵产氢、产甲烷特性。结果表明,利用垃圾渗滤液作为基质发酵产氢或甲烷时,氢气的最大累积产量为24.33mL(以每克COD计,下同),甲烷的最大累积产量为91.59mL,产氢发酵在初期存在明显的迟滞期,但是产甲烷发酵不存在明显迟滞期;产氢发酵的液相末端产物中含有大量的挥发性有机酸和乙醇,乙醇、乙酸、丁酸质量浓度分别为487.23、1 175.21、1 225.78mg/L,相比产氢发酵,产甲烷发酵的液相末端产物中乙醇、乙酸、丁酸质量浓度均较低,分别为256.38、106.73、107.42mg/L;产甲烷发酵的最终pH是6.32,接近中性,而产氢发酵的最终pH为4.21,呈明显酸性;产甲烷发酵对COD的去除率(41.78%)高于产氢发酵对COD的去除率(32.14%),可能是产氢发酵液相末端产物中的乙酸能被产甲烷菌利用,而被进一步降解。