混凝沉淀法处理磷矿浮选废水试验研究

对于质量浓度高达268.5mg/L的磷矿浮选废水,在实验确定的最佳工艺条件下,出水磷酸盐质量浓度小于0.5mg/L,达到国家综合污水排放一级标准,磷的去除率高达99.85%;同时,磷矿浮选废水中CODcr和SS的去除率也达到了75.3%和81.2%.处理成本低,具有明显的经济效益和环境效益.     

有机磷降解酶的固定化及其工业化应用初探

采用一种新型的酶固定化方法,在大孔微球中对有机磷降解酶（OPHC2）固定化,制备固相载体化的交联酶聚集体固定化酶。对具有实际应用意义的参数：热稳定性、牢固度和连续反应批次进行了重点研究。结果表明,有机磷降解酶固定化酶的半衰期在70℃时比游离酶提高了2.1倍。固定化酶分别在37℃的摇床中经14 h高速振荡,以及在pH 8、37℃条件下循环反应49个批次降解甲基对硫磷后,均未发现固定化酶酶活力下降。在37℃,有机磷降解酶固定化酶柱以每小时3倍柱床体积的速率对甲基对硫磷农药乳油的稀释液（甲基对硫磷含量为216 mg/L）进行降解处理,系统连续工作156 h,甲基对硫磷的降解率保持在98.4%～99.9%。     

高校事故非线性灰色预测模型及应用研究

通过调查和分析表明,近几年来湖南省高校事故中学生非正常死亡由自杀、交通、溺水等7项因素组成,且统计数据信息偏少。笔者将影响湖南省高校事故学生非正常死亡人数的各项因素作为一个系统,应用系统灰预测理论建立高校事故系统灰预测模型;将原始建模数据序列经过方根变换和数值初始化处理后,适合于建模的要求,构造GM(1,N)与GM(1,1)的嵌套模型;通过建模事中和事后的检验,预测湖南省2007年高校事故学生非正常死亡人数,预测值与实际值相差较小,模型精度较高;高校事故非线性灰色预测模型,为高校事故预测提供了一种应用方法并有一定的指导意义。     

美国的环保政策及对环保产业发展的影响

美国的环保政策是一种经济发展政策 ,强调在提高美国工业竞争力和维护社会经济繁荣的基础上加强环境保护 ,强调通过环保技术的开发和应用实现具体的环保目标 ;措施上它强调灵活性、创新性、多样性和公众的自觉参与 ,创造了环保产业宽松和不断创新的环境。     

对单项污染评价中污染分界线问题的讨论

根据数理统计的原理,将环境质量标准,平均值,标准偏差以及样本容量综合进行考虑,提出了污染分界线的计算公式,并以表格形式给出了不同显著性水平下,不同的相对标准偏差和样本容量所对应的污染分界线,对污染分界线与样本容量及相对标准的偏差的关系进行了讨论,指出提高监测精度和适当增加监测数据个数,可以使污染分界线接近评价标准。     

2-(2-喹啉偶氮)-4-二乙氨基苯甲酸光度法测定镍的研究

合成了新试剂 2 -( 2 -喹啉偶氮 ) -4 -二乙氨基苯甲酸 ( QADEABA) ,并研究了其与镍的显色反应 ,在 p H=8.0的硼酸 -磷酸二氢钾缓冲介质中 ,吐温 -80存在下 ,QADEABA与镍反应生成 2∶ 1稳定络合物 ,λmax=5 90 nm ,ε=1 .1 8× 1 0 5L· mol-1· cm-1。镍含量在 0～ 0 .4 mg/ L内符合比耳定律 ,方法用于水样中镍含量的测定 ,结果令人满意     

Distribution and sources of mercury in soils from former industrialized urban areas of Beijing, China

Fifty-seven typical surface soils and 108 deeper soils were collected from five former industrial sites in Beijing and concentrations of total Hg (SigmaHg) as well as pH, total carbon (TC), total nitrogen (TN), total sulfur, and dissolved organic carbon concentrations determined. The mean concentration of SigmaHg in surface soils was significantly greater than background concentrations in the vicinity of Beijing. Forty-eight percent of the samples exceeded the "critical" concentration of 1.0 mg Hg/kg, dry weight in soils, which has been established by the Chinese government. At depths of 0-80 cm in the soil, profile concentrations of SigmaHg also exceeded the background value. There were significant correlations between concentrations of SigmaHg, TC, and TN in the industrial soils. The greater concentration of SigmaHg in most soils could have been due in part to combustion of coal and leakage from industrial processes.     

Concentrations of sulphur and heavy metals in needles and rooting soils of Masson pine (Pinus massoniana L.) trees growing along an urban–rural gradient in Guangzhou, China

Current (C) and previous year (C + 1) needles and soils (organic horizon, 0-10 cm and 10-20 cm mineral depth) of Masson pine (Pinus massoniana L.) trees were sampled at four forested sites (Huang Pu industrial district, HP; South China Botanical Garden, BG; Mao Feng Mt., MF; and Nan Kun Mt., NK) in Guangzhou along a urban-rural gradient and analyzed for sulfur (S) and heavy metals (Cu, Zn, Ni, Cd, Cr and Pb) concentrations. Needle concentrations of all the elements were significantly higher at industrial HP than at other three sites, except for Cu and Pb which were highest at the traffic site (BG). The C + 1 needles generally had higher Cu, Cd, Pb, Zn, Cr than the C needles while the opposite was for Ni and S. Total and available Cd, Pb, Zn in soils peaked at the urban sites (HP and BG) and decreased at suburban MF and rural NK. Heavy metals were generally higher in the organic soils than in the mineral soils at all sites. Zinc and Pb at all sites, and Cd, S and Cu at the urban sites (HP and BG) in soils or pine needles were above or near their respective natural background levels, implying that threats resulted from these toxic elements occurred on local particularly urban forests, but did not for Cr and Ni due to their presence below their background values. Our results demonstrated that elements concentrations in needles and soils had reflected the variability of pollutants and the environmental quality change along the urban-rural transect, and were efficient as biomonitors to assess the influence of anthropogenic activities along the urbanization course on forest health.     

Regional differences and sources of organochlorine pesticides in soils surrounding chemical industrial parks

Concentrations of organochlorine pesticides (OCPs; dichlorodiphenyltrichloroethanes (DDTs), hexachlorocyclohexanes (HCHs), hexachlorobenzene (HCB)) were investigated in 105 soil samples collected in vicinity of the chemical industrial parks in Tianjin, China. OCP concentrations significantly varied in the study area, high HCH and DDT levels were found close to the chemical industrial parks. The intensity of agricultural activity and distance from the potential OCP emitters have important influences on the OCP residue distributions. Principal component analysis indicates that HCH pollution is a mix of historical technical HCH and current lindane pollution and DDT pollution input is only due to technical DDT sources. The significant correlations of OCP compounds reveal that HCHs, DDTs and HCB could have some similar sources of origin.     

柴油在土壤中迁移的试验模拟研究

通过土柱模拟试验研究了0#柴油在不同类型的土壤(壤土、砂土)中分别以连续和间歇方式入渗的渗流特征.结果表明:柴油在壤土中的入渗速率小于砂土;相同类型的土壤中,连续入渗的速率大于间歇入渗;柴油饱和溶液入渗条件下,绝大部分的柴油集中在深度小于25 cm的土层里,只有在连续入渗砂土情况下,大量的柴油迁移到了35 cm深度的土层;柴油以无水液流态(NAPL)间歇入渗条件下,壤土和砂土中各土层的柴油质量比与土层深度服从相应的负指数关系.通过对比静态吸附的结果,发现迁移过程中存在吸附、截留和生物降解作用等.