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11.
Ji Hu Jianmin Wang Shuxia Liu Zhechao Zhang Haifeng Zhang Xiaoxia Cai Jianming Pan Jingjing Liu 《环境科学学报(英文版)》2018,30(4):208-215
TiO_2 nanoparticles(NPs) could adversely impact aquatic ecosystems. However, the aggregation of these NPs could attenuate this effect. In this work, the biological effects of TiO_2 NPs on a marine microalgae Isochrysis galbana were investigated. The aggregation kinetics of TiO_2 NPs under different conditions was also investigated to determine and understand these effects. Results showed that, though TiO_2 NPs had no obvious impact on the size and reproducibility of algal cells under testing conditions, they caused a negative effect on algal chlorophyll, which led to a reduction in photosynthesis. Furthermore, fast aggregation of TiO_2 NPs occurred under all conditions, especially at the pH close to the p Hzpc. Increasing ionic strength and NP concentration also enhanced the aggregation rate.The aggregation and the following sedimentation of TiO_2 NPs reduced their adverse effects on I. galbana. 相似文献
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Adsorption of zinc on manganite(γ-MnOOH): particle concentration effect and adsorption reversibility
The adsorption and desorption processes of Zn(Ⅱ) on τ-MnOOH as a function of particle concentrations (Cp) were studied. An obvious Cp effect was observed in this adsorption system. The degree of adsorption hysteresis increased greatly with the increasing of Cp, indicating that the extent of the real metastable-equilibrium states deviating from the ideal equilibrium state was enhanced with the increasing of Cp. The Cp-reversibility relationship confirmed the metastable-equilibrium adsorption (MEA) inequality (Pan, 1998a), which was the core formulation of the MEA theory. Because the MEA inequality was based on the basic hypothesis of MEA theory that adsorption densitιy ι is not a state variable, the Cp-reversibility relationship gave indirect evidence to the basic hypothesis of MEA theory. 相似文献
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对多环芳烃(PAHS)4种理化参数(K;W、Sw。X Vv。)与 LCO的相关关系进行了研究,建立了 4种一元线性回归方程。结果表明,4种参数的相关系数分别为:0.刀66、08083、09488、0.9570,经r检验,后两种属高度显著相关.用所建立的一元线性回归方程对7种PAHS的LC。进行估算,估算值与实测值相比,平均相对误差分别为58.84%、32.23%、1761%、198%,用l和V*.H对LClj进行估算的估算精度也较高。经比较,提出用(。估算P*比对麦穗鱼*CO的新方法。 相似文献
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本研究对兰州市不同污染区(石油化工为主、燃煤、商业及农村)在不同季节时的大气飘尘,作了对比采样.飘尘样品用溶剂抽提法提取后,用化学萃取法分离为五个有机物馏分.用毛细色谱-质谱-计算机联用系统进行了定性分析,并用毛细管色谱法进行了部分定量分析.用Ames试验(用TA1537、TA98和TA100三株菌.加与不加S-1)对其致突变活性进行了研究.并对有机致突变物在不同污染区、不同季节的变化规律及其来源进行了初步探讨. 相似文献
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HydrolyticdynamicsofpesticideN'-(2,4-dimethylphenyl)-N-methylformamidineinaquaticsolution¥MoHanhong;YangKewu;AnFengchun;LiuYe... 相似文献
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Given the key role of biogenic volatile organic compounds(VOCs) to tropospheric chemistry and regional air quality, it is important to generate accurateVOCs emission inventories. However, only a less fraction of plant species, in temperate grassland of Inner Mongolia, has been characterized by quantitative measurements. A taxonomic methodology, which assigns VOCs measurements to unmeasured species, is an applicable and inexpensive alternation for extensive VOCs emission survey, although data are needed for additional plant families and genera to further validate the taxonomic approach in grassland vegetation. In this experiment, VOCs emission rates of 178 plant species were measured with a portable photoionization detector( PID). The results showed the most of genera and some families have consistent feature of their VOCs emission, especially for isoprene, and provide the basic premise of taxonomic methodology to develop VOCs emission inventories for temperate grassland. Then, the taxonomic methodology was introduced into assigning emission rate to other 96 species, which no measured emission rates available here. A systematical emission inventory of temperate grassland vegetation in Inner Mongolia was provided and further evidence that taxonomy relationship can serve as a useful guide for generalizing the emissions behavior of many, but not all, plant families and genera to grassland vegetation. 相似文献
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有机阴离子可以和长碳链的季胺盐阳离子结合生成可溶于高介电常数有机溶剂的离子对.在此溶剂中,它可以和某些卤代烃发生复分解反应,生成季铵盐阳离子的卤化物及有机阴离子的相应烷基化物,故称离子对烷基化反应.此反应条件温和,转化率高,被广泛地应用于酸性及其它含活泼氢的有机化合物的烷基衍生物合成中.在这类有机物的分析中也得到应用.但尚未见应用于农药及其降解物残留分析中的报道. 2,4-D,2,4,5-T是典型的酸性有机农药,广泛用作农田除草剂.在二者的残留分析中,通常用CH_2N_2、BF_3CH_3OH、(CH_3)_2SO_4将它们烷基化,然后用气相色谱加以分析.近几年也有人用多卤素取代醇的BCl_3络合物或五氟苄基溴化物同Na_2CO_3作为 相似文献
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河南省黄河湿地生态旅游资源的开发与保护研究 总被引:1,自引:0,他引:1
河南黄河湿地旅游资源丰富,有各具特色的湿地景观、复杂多样的生物景观、丰富的地文景观、悠久的历史人文景观和工程园林景观等多种景观类型;但目前存在着开发利用程度较低,市场营销不够、景点开发质量不高,旅游设备简陋、基础设施落后,景点少、点热面冷,人才缺乏、经营管理水平低等众多问题;最后从旅游功能分区、旅游开发、旅游管理、旅游线路设计、旅游环境监测、区域旅游联合、加大宣传力度等方面提出了河南黄河湿地生态旅游资源开发的对策. 相似文献