硫酸渣制备高纯度硫酸亚铁

以高铁硫酸渣为原料,采用酸浸一还原-除杂-结晶-重结晶-干燥工艺,合成高纯度硫酸亚铁.通过反应温度、反应时闻对硫酸渣中铁的浸出率的影响,以及结晶温度、干燥温度,干燥时间、于燥时间对硫酸亚铁产品纯度的影响做分析实验,得出最佳酸浸条件:硫酸渣与硫酸的固液比为1:3,硫酸质量分数为20%-25%,反应温度为80℃,反应时间为6 h,搅拌强度为200 r/min;最佳结晶精制条件:结晶溶液pH值1:3,温度为60℃,温度海60℃;除杂最佳条件:pH值约为4.5;冷却结晶温度控制在20℃,结晶秣过程为30℃于燥6 h.     

发展循环经济 开辟航空业新纪元

随着人们环保意识的逐渐增强,航空业所造成的环境和噪声污染已经越来越成为令人关注的重大问题.从5个方面介绍了发达国家航空业发展循环经济的经验,指出我国作为发展中国家,要正视与发达国家的差距,借鉴国外先进经验,转变观念、大胆创新,大力发展循环经济,开辟我国航空业的新纪元.     

成都市土壤天然放射性核素的外照射水平估算研究

利用IED22000A便携式微机多道能谱仪对成都市区土壤的天然放射性核素进行了直接就地测量,估算出天然环境放射性核素^238U、^232Th、^40K的比活度范围分别为10.37～77．19Bq／kg、17,85～225．74Bq／kg、284．83～892．67Bq／kg;外照射指数范围为0．16—0．8;离地面1m高的空气吸收剂量率均值为83．23nGy／h;1外照射年有效剂量当量为0．34～0．70mSv;等效镭浓度的变化范围是59．06-386．45Bq／kg,均值为164．15Bq／kg。各项指标均在容许范围之内,因而成都市属于外照射水平的安全区域,人居环境不受影响。     

北京蟹岛集团发展循环经济调查

通过对民营企业北京蟹岛集团的实地调查,对其以“低消耗、低排放、低污染、高效益”为经营方针,以“生态、环保、可持续”为经营理念,成功实现“资源－消费－再利用”的循环经济增长模式进行详细介绍。并通过蟹岛集团自身的发展证明：循环经济不仅可以改变传统“资源－效益—废弃物”的线性增长模式,还可以促进企业的发展,为企业带来可观的经济效益。     

Removal of arsenic(III,V) by a granular Mn-oxide-doped Al oxide adsorbent: surface characterization and performance

In order to remove arsenic (As) from contaminated water, granular Mn-oxide-doped Al oxide (GMAO) was fabricated using the compression method with the addition of organic binder. The analysis results of XRD, SEM, and BET indicated that GMAO was microporous with a large specific surface area of 54.26 m^2/g, and it was formed through the aggregation of massive Al/Mn oxide nanoparticles with an amorphous pattern. EDX, mapping, FTIR, and XPS results showed the uniform distribution of Al/Mn elements and numerous hydroxyl groups on the adsorbent surface. Compression tests indicated a satisfactory mechanical strength of GMAO. Batch adsorption results showed that As(V) adsorption achieved equilibrium faster than As(III), whereas the maximum adsorption capacity of As(III) estimated from the Langmuir isotherm at 25 °C (48.52 mg/g) was greater than that of As(V) (37.94 mg/g). The As removal efficiency could be maintained in a wide pH range of 3~8. The presence of phosphate posed a significant adverse effect on As adsorption due to the competition mechanisms. In contrast, Ca²⁺ and Mg²⁺ could favor As adsorption via cation-bridge involvement. A regeneration method was developed by using sodium hydroxide solution for As elution from saturated adsorbents, which permitted GMAO to keep over 75% of its As adsorption capacity even after five adsorption–regeneration cycles. Column experiments showed that the breakthrough volumes for the treatment of As(III)-spiked and As(V)-spiked water (As concentration = 100 μg/L) were 2224 and 1952, respectively. Overall, GMAO is a potential adsorbent for effectively removing As from As-contaminated groundwater in filter application.

     

基于信息熵的省域内能源消费总量分配研究

能源消费总量控制是保障能源安全,积极应对气候变暖的重要手段;省域内能源消费量的合理分配,是落实国家能源消费总量控制的有效措施。提出能源消费总量分配应以公平为主、考虑区域发展权益的同时兼顾效率的原则,秉承“定基数,分增量”的思想,构建了基于信息熵的多因子混合加权分配模型,对目标年能源消费增量进行分配;选择了10个指标从经济水平、能耗水平、发展现状、产业结构及城市发展定位5个方面描述各地区的节能潜力及控制能耗量的责任,拟对能源消费总量在省内各市区的分配进行探索性研究。并以安徽省为例,对安徽省2015年能源消费总量分配到各市区进行了实证分析。结果显示,2015年安徽省17个市区能耗分配量增长率范围为1193%~5045%,能耗增幅的分配结果整体上受各市区人均GDP和人均能源消费量水平所支配,受单位工业增加值能耗和城市化率所调控     

XAFS study of starch-stabilized magnetite nanoparticles and surface speciation of arsenate

It has been shown that starch can effectively stabilize nanoscale magnetite particles, and starch-stabilized magnetite nanoparticles (SMNP) are promising for in situ remediation of arsenic-contaminated soils. However, a molecular level understanding has been lacking. Here, we carried out XAFS studies to bridge this knowledge gap. Fe K-edge XAFS spectra indicated that the Fe-O and Fe-Fe coordination numbers of SMNP were lower than those for bare magnetite particles, and these coordination numbers decreased with increasing starch concentration. The decrease in the average coordination number at elevated stabilizer concentration was attributed to the increase in the surface-to-volume ratio. Arsenic K-edge XAFS spectra indicated that adsorbed arsenate on SMNP consisted primarily of binuclear bidentate (BB) complexes and monodentate mononuclear (MM) complexes. More BB complexes (energetically more favorable) were observed at higher starch concentrations, indicating that SMNP not only offered greater adsorption surface area, but also stronger adsorption affinity toward arsenate.     

利用西湖淤泥进行低成本有机型基质栽培试验

以西湖淤泥为主要原料，配以砻糠灰、干鸡粪、菜籽饼等，组配低成本有机型基质，旨在合理开发利用西湖淤泥。处理Ⅰ(西湖淤泥 砻糠灰 干鸡粪)与处理Ⅱ(西湖淤泥 砻糠灰 菜籽饼)均有良好的理化性质，其孔隙度、有机质含量及N、P、K含量适宜樱桃番茄的生长。处理Ⅰ樱桃番茄早期营养生长及前期产量、总产量等方面与对照(泥炭 珍珠岩 泡沫粒)无显著性差异，果实中Vc含量显著高于对照。处理Ⅱ早期营养生长不如对照，但前期产量、总产量与对照无显著性差异，干物质、Vc含量与糖度显著高于对照。处理Ⅰ、处理Ⅱ的成本约为对照的1／2左右。