Changes in mussel Mytilus galloprovincialis protein profile as a reaction of water pollution

In the present report the changes in mussels Mytilus galloprovincialis protein profile, as a reaction of water pollution, is presented. The antioxidant capacity was determined by the efficacy to scavenge the derived radical in mussel samples using the Trolox Equivalent Antioxidant Capacity (TEAC) assay. The highest percentage of inhibition was estimated in protein mussels from the dirty area (DM) in comparison with the clean samples (CM). The amounts of both zinc and copper determined by atomic spectroscopy were significantly higher in the protein mussels from the dirty than from the clean areas (P<0.05). Fourier Transform Infrared (FT-IR) spectroscopy and fluorescence revealed specific qualitative changes in secondary and tertiary structures of mussel proteins from the dirty area by the shift in the amides I and II positions and fluorescence intensity. Estimated temperature and enthalpy of denaturation in the protein mussels well correlated with fluorescence and spectroscopic measurements and showed the changes influenced by water pollution.     

Vulnerability of Water Systems to the Effects of Climate Change and Urbanization: A Comparison of Phoenix, Arizona and Portland, Oregon (USA)

The coupled processes of climate change and urbanization pose challenges for water resource management in cities worldwide. Comparing the vulnerabilities of water systems in Phoenix, Arizona and Portland, Oregon, this paper examines (1) exposures to these stressors, (2) sensitivities to the associated impacts, and (3) adaptive capacities for responding to realized or anticipated impacts. Based on a case study and survey-based approach, common points of vulnerability include: rising exposures to drier, warmer summers, and suburban growth; increasing sensitivities based on demand hardening; and limited capacities due to institutional and pro-growth pressures. Yet each region also exhibits unique vulnerabilities. Comparatively, Portland shows: amplified exposures to seasonal climatic extremes, heightened sensitivity based on less diversified municipal water sources and policies that favor more trees and other irrigated vegetation, and diminished adaptive capacities because of limited attention to demand management and climate planning for water resources. Phoenix exhibits elevated exposure from rapid growth, heightened sensitivities due to high water demands and widespread increases in residential and commercial uses, and limited adaptive capacities due to weak land use planning and “smart growth” strategies. Unique points of vulnerability suggest pathways for adapting to urban-environmental change, whether through water management or land planning. Greater coordination between the land and water sectors would substantially reduce vulnerabilities in the study regions and beyond.     

Walking when intoxicated: An investigation of the factors which influence individuals’ drink walking intentions

Annually, in Australia, 10-15% of all road-related fatalities involve pedestrians. Of those pedestrians fatally injured, approximately 45% were walking while intoxicated or ‘drink walking’. Drink walking is increasing in prevalence and younger persons may be especially prone to engage in this behaviour and, thus, are at heightened risk of being injured or killed. Presently, limited research is available regarding the factors which influence individuals to drink walk. This study explored young people’s (17-25 years) intentions to drink walk, using an extended Theory of Planned Behaviour (TPB). Participants (N = 215), completed a self-report questionnaire which assessed the standard TPB constructs (attitude, subjective norm, perceived behavioural control) as well as the extended constructs of risk perception, anticipated regret, and past behaviour. It was hypothesised that the standard TPB constructs would significantly predict individuals’ reported intentions to drink walk and that the additional constructs would predict intentions over and above the TPB constructs. The TPB variables significantly predicted 63.2% of the variance in individuals’ reported intentions to drink walk, and the additional variables, combined, explained a further 6.1% of the variance. Of the additional constructs, anticipated regret and past behaviour, but not risk perception, were significant predictors of drink walking intentions. As one of the first studies to provide a theoretically-based investigation of factors influencing individuals’ drink walking intentions, the current study’s findings have potentially significant implications for understanding young people’s decisions to drink walk and the design of future countermeasures to ultimately reduce this behaviour.     

Characterization of Cr ion exchange with hydrotalcite

Experiments were performed to characterize the removal of chromium from water with uncalcined hydrotalcite, a clay mineral ion exchange media. The process was characterized as a function of pH, temperature, contact time, and both Cr and hydrotalcite concentrations. A Freundlich isotherm, used to describe adsorption equilibria, was used as a model and Freundlich constants were determined. The kinetics of the ion exchange reaction were also modeled using a pseudo-first order reaction rate. Finally, an equilibrium stage process was modeled with sequential batch separations to determine if hydrotalcite ion exchange could reduce aqueous Cr levels to below the EPA limit of 0.1mgl(-1). It was shown that the process is highly pH dependent, only yielding significant removals at pH levels between 2.0 and 2.1. While hydrotalcite concentration, Cr concentration, and time did effect the ion exchange, temperature was not found to be a factor. Under optimal conditions, maximum removals of greater than 95% were achieved. Finally, sequential batch tests performed on initial Cr solutions ranging from 5mgl(-1) to 40mgl(-1), demonstrated that the water could be purified to a level that was not statistically different than the EPA limit, thus demonstrating the applicability of hydrotalcite ion exchange.     

Aquatic macrophytes potential for the simultaneous removal of heavy metals (Buenos Aires, Argentina)

Heavy metal removal from water has been approached by using different technologies. Phytotechnologies, with an increasing development during the last two decades, involve using plants for metal removal. Three autochthonous floating macrophytes, common in pampean shallow lakes (Argentina), Pista stratiotes, Spirodela intermedia and Lemna minor were used in laboratory experiences for the simultaneously removal of several heavy metals (Fe, Cu, Zn, Mn, Cr and Pb) resulting from anthropogenic activity, in order to simulate a naturally polluted environment. The experiences were performed for different concentrations of metals along 15 days. High metal removal percentages were obtained for the 3 species and metals. L. minor did not survive the conditions of the experiment. High correlation between the final water and the macrophytes metal concentration was obtained, deviations were due to PbCrO(4) precipitation. The rate of metal uptake was dependent on the metal concentration for the 3 species studied.     

Microbial Removal of Arsenic

Bangladesh is currently the subject of the world's largest mass arsenic poisoning in history. Groundwater throughout Bangladesh and West Bengal is contaminated with naturally occurring arsenic from the alluvial and deltaic sediments that form the region's aquifers. It has been estimated that 75 million people are at risk of developing health effects associated with the ingestion of arsenic. This project focuses on the use of microorganisms such as bacteria and algae to remove arsenic from water. Arsenic in the arsenite form was used in the studies. Experiments were conducted with a common alga and wastewater bacteria. A common green algae Scenedesmus abundans was used for determining arsenic uptake in batch experiments. Results of the experiments indicated that the algae biosorption could be modeled by the conventional Langmuir isotherm model. Algae morphology studies indicated that the algae cells were impacted due to the presence of arsenic as evidenced by clumping or loss of cell clusters. The wastewater bacteria also were capable of high percent of arsenic removal. Results indicate that microbial uptake of arsenic may be a viable method of pretreatment of arsenic contaminated water. However algae and sludge disposal would pose a problem and will have to be dealt with accordingly.     

Evaluating the Risk of Potential Acid Sulfate Soils and Habitat Modification for Mosquito Control (Runneling) in Coastal Salt Marshes: Comparing Methods and Managing the Risk

Coastal environments in Australia are under development pressures. Human settlement encroaches on disease vector salt marsh mosquito breeding areas that are underlain by potential acid sulfate soils (PASS). Altering the hydrology by runneling solves the mosquito problem but may lead to acid sulfate problems. Appropriate analytical tools can assess the risk to the environment. The objective of the research was to compare three methods of assessing PASS. The study area was a low-lying intertidal subtropical salt marsh that was being considered for runneling. The results indicated that using field pH and field peroxide pH (and the relationship between these), and also the peroxide oxidation-combined acidity and sulfate (POCAS) test, appeared to overestimate the potential acidity. This was because the source of acidity in the intertidal salt marsh includes a large organic content, which is not a major environmental concern. The chromium-reducible sulfur test, which is not affected by organic content, was found to provide the most appropriate assessment, and is recommended for use in highly organic salt marshes.     

Learning through public involvement in environmental assessment hearings

This research examined the opportunities for critical education available to participants of a federal environmental assessment (EA) that includes hearings. The Sable Gas Panel Review, an assessment of a natural gas project situated in the Maritimes, was undertaken between 1996 and 1997. This study documented what participants learned through their experiences and how that learning was facilitated. Primary data collection emphasized the use of semi-structured interviews to record the experientially based observations of panel participants. Primary data were supported by a review of material submitted by hearing participants for consideration by the panel, and complemented with literature related to EA, environmental education, and transformational learning theories. Evidence was considered in terms of assessment-specific operational definitions, developed from Shor (1993) [Education is politics: Paulo Freire's Critical Pedagogy. In: McLaren, P., Leonard, P. (Eds.), Paulo Freire : A critical Encounter, Routledge, New York, pp. 25-35] ten indicators of critical education. The study revealed that participants of the Sable Gas panel review had an opportunity to engage in critical education. While it is important to acknowledge that the panel did not set out to engage participants in a 'critical educational' experience, each of the 10 operational definitions of critical education used in the study were addressed to varying degrees through activities undertaken by the panel secretariat. Results illustrate the types of educational opportunities, such as a class on how to participate in a quasi-judicial hearing, and the importance of participant-led research that can arise out of the panel review process. The findings of this research contribute to the evolving literature regarding the role of critical education in EA and environmental management. Understanding the existing scope of critical education within a panel review provides the foundation for identifying opportunities for expanding the capacity of the existing EA process to facilitate learning by participants.     

Vertical distribution of aliphatic and aromatic hydrocarbons in mussels from the Amposta offshore oil production platform (Western Mediterranean)

The qualitative distributions of aliphatic hydrocarbons in mussels adhered to the legs of an oil production platform (Amposta, Western Mediterranean) have evidenced local (diesel oil) and chronic inputs (middle East crude oils) as the main pollutant sources in the area. Quantitative data have shown that aromatic hydrocarbons are selectively accumulated with the age of mussels and are more evenly distributed through the water column. Background concentrations of petrogenic aliphatic hydrocarbons in mussels living in the vicinity of oil platforms have been established in the range of 25–40 ug/g dry weight.