Geochemistry,mining and the environment

This paper reviews literature on the sources of lead-zinc mining pollution, and specifically deals with the water and air pollution aspects of these operations. Problems associated with mining and the environment are also discussed. The problems are geochemical in nature but also economic, social, political and legal. Individuals doing research in these boundary conditions are poorly publicised and rarely recognised outside of their own narrow industry.The paper notes that it is possible to have both an economical mining operation and a clean environment. The New Lead Belt region of Southern Missouri, the world's largest lead-mining region lies underneath a national forest with a pure, pristine, undisturbed ecosystem having high recreational value to the nearby cities. By early cooperation between governmental scientists, mining industry, environmental scientists and engineers of the University of Missouri and other universities it was possible to develop this deposit and at the same time keep the pristine nature of the surrounding forest without spending a single day in court or litigation. Problems did arise, but problem-solving sessions dealt with them, not lawyers.     

New insights on the systematics,palaeoecology and palaeobiology of a plesiosaurian with soft tissue preservation from the Toarcian of Holzmaden,Germany

The Posidonienschiefer Formation (Toarcian) of Holzmaden, Baden-Württemberg in southwestern Germany has yielded several excellently preserved plesiosaurian specimens and received considerable research attention. The plesiosaurians found within these deposits are always significantly outnumbered by ichthyosaurs, and close examination of these rare specimens is crucial to a better understanding of the diversity and palaeoecology of Plesiosauria in this very peculiar ecosystem. The plesiosaurian specimen SMNS 51945 found in this area is a juvenile individual consisting of a partial, crushed skull and an exquisitely preserved post-cranial skeleton. Its anatomical characters seem to differ from the long-necked plesiosauroids Microcleidus brachypterygius and Seeleyosaurus guilelmiimperatoris that are the most abundant taxa within the plesiosaurian assemblage. The post-cranial skeleton preserves very likely soft tissues composed of buff-coloured and dark-coloured structures around the vertebral column and hindlimb of the animal. A network of buff-coloured fibres located posterior to the hindlimb most likely represents phosphatised collagen fibres as already found in some ichthyosaur specimens, confirming that wing area in plesiosaurians was much larger than that suggested by skeletal remains alone. The specimen also contains gastroliths (sand-sized grains mainly composed of quartz) in the stomach cavity suggesting the animal spent at least some of its time in shallow coastal waters, tens or hundreds of kilometres from the final place of burial.     

Describing Damage to Stream Modification Projects in Constrained Settings

Complex relationships between stream functions and processes make evaluation of stream modification projects difficult. Informed by vague objectives and minimal monitoring data, post‐construction project evaluations can often be a subjective attribution of success or failure. This article provides a simple framework to rapidly describe the degree of damage in stream modification projects performed in constrained settings. Based on widely accepted evaluations of physical habitat quality and stream stability, the damage states framework describes a continuum of damage in multiple categories that relate natural stream functions to the often desired state of static equilibrium. Given that channel form is closely related to stream function, it follows that changes to the channel form result in changes in function. The damage states focus on damage to flow hydraulics, sediment transport and channel equilibrium, hydraulic, and geomorphic parameters that describe basic stream functioning and support higher level functions in the modified channel. The damage states can be used in decision making as a systematic method to determine the need for repair and design adjustments.     

Development of a biotic ligand model (BLM) predicting nickel toxicity to barley (Hordeum vulgare)

A biotic ligand model (BLM) was developed to predict nickel toxicity, affecting root growth of barley (Hordeum vulgare), in nutrient solutions. The extent to which Ca(2+), Mg(2+), Na(+), K(+) ions and pH each influenced nickel toxicity was determined. Higher activities of Mg(2+) linearly increased the 4d EC50 Ni (2+) , while Ca(2+), Na(+), K(+) and H(+) activities did not significantly influence Ni(2+) toxicity. Stability constants for the binding of Ni(2+) and Mg(2+) to the biotic ligand were obtained: logK(NiBL)=5.27 and logK(MgBL)=3.47. Further, it was calculated that on average 57% of the biotic ligand sites needed to be occupied by nickel to induce 50% root growth inhibition. Auto-validation of the BLM indicated that predicted EC50s differed from the observed EC50s by a factor of less than 2, indicating that the BLM concept may also be used to predict metal toxicity to terrestrial plants.