不同区域城市空气O3和PM2.5累积速率时序模型

利用2017—2018年全国7个区域10个典型城市环境空气O₃和PM_2.5浓度数据，统计污染物累积速率，进而采用回归方法拟合污染物浓度及其累积速率的时间序列模型，分析不同区域污染物时序变化特征差异。结果表明：不同区域O₃浓度时序曲线拟合程度总体高于PM_2.5，石家庄O₃拟合程度最高，西安PM_2.5拟合程度最高。以07：00、14：00分别作为O₃、PM_2.5模拟起点是24 h中的最优模型。不同城市夏季O₃小时浓度时序变化曲线均为单峰形态，O₃浓度及累积速率峰值出现时间可能由城市所处经度决定，太原O₃累积最快，西安O₃消解最快。各城市间冬季PM_2.5小时浓度及其累积速率时序变化曲线形态差异较大，沈阳PM_2.5累积和消解均最快。与浓度相比，城市环境空气O₃和PM_2.5累积速率与光照、扩散条件等有更好的时间相关性。     

海河下游水体中DO与NH_3-N、COD_(Mn)相关关系探讨

本文应用近年来海河下游监测数据对ＤＯ与ＮＨ３Ｎ和ＣＯＤＭｎ进行一元线性回归，得到两回归方程：ＮＨ３Ｎ＝－１２８ＤＯ＋１０５４；ＣＯＤＭｎ＝－１１３ＤＯ＋１６９２。并经相关系数和回归系数显著性检验，表明在９９９％的置信水平下ＤＯ与ＮＨ３Ｎ和ＣＯＤＭｎ线性相关均极其显著     

连续采样与五日法采样效果及费用的对比分析

通过对连续采样与五日法采样五种方法监测结果及所需费用的比较，得出连续采样方法监测结果更具有代表性，合理性，一次性投资大，但运行费用并不高的结论。     

Development of an ombrotrophic peat bog (low ash) reference material for the determination of elemental concentrations

Given the increasing interest in using peat bogs as archives of atmospheric metal deposition, the lack of validated sample preparation methods and suitable certified reference materials has hindered not only the quality assurance of the generated analytical data but also the interpretation and comparison of peat core metal profiles from different laboratories in the international community. Reference materials play an important role in the evaluation of the accuracy of analytical results and are essential parts of good laboratory practice. An ombrotrophic peat bog reference material has been developed by 14 laboratories from nine countries in an inter-laboratory comparison between February and October 2002. The material has been characterised for both acid-extractable and total concentrations of a range of elements, including Al, As, Ca, Cd, Cr, Cu, Fe, Hg, Mg, Mn, Na, Ni, P, Pb, Ti, V and Zn. The steps involved in the production of the reference material (i.e. collection and preparation, homogeneity and stability studies, and certification) are described in detail.     

辽河流域浑河沈阳段地表水重点控制有机污染物的筛选

采用美国环保局工业环境实验室提出的化学物质的“潜在危害指数法”,对辽河流域浑河沈阳段地表水和底质中检出的有机污染物的潜在危害进行了排序,参考国内外有毒化学品优先控制名单的筛选原则和方法,结合本流域的实际情况,制定出重点控制有机污染物的评分标准,提出辽河流域浑河沈阳段重点控制有机污染物名单。考虑到个别有机污染物在水中的浓度很低,但在底质中相对含量较高,所以将底质的检测结果也纳入评分标准。     

4类噪声标准适用区最佳监测时间研究

以1年的实测数据为分析样本,分别采用误差理论分析及数理统计分析方法,在保证一定精确度前提下确定出反映4类标准适用区噪声水平的最佳监测时间。     

离子交换树脂光度法测定微量铁的研究

研究了以阳离子交换树脂为显色载体，利用直接吸附在树脂上有色络合物－Fe(II)邻二氮菲的吸光度，借以检测水和火腿肠中铁的新方法，本法具有比原子吸收法更高的灵敏度，稳定性和选择性，并对成络及树脂吸附条件作了较详细研究。     

我国污染源在线监测现状及建议

文章在对国内重点城市污染源在线监测调查研究的基础上 ,分析总结了国内污染源在线监测的经验和教训 ,提出了推进污染源在线监测的建议     

Modeling the spatial pattern of farmland using GIS and multiple logistic regression: a case study of Maotiao River Basin, Guizhou Province, China

Land use change is an important topic in the field of global environmental change and sustainable development. Land use change modeling has attracted substantial attention because it helps researchers understand the mechanisms of land use change and assists regulatory bodies in formulating relevant policies. Maotiao River Basin is located in the province of Guizhou, China, which has a developed agricultural industry in the karst mountain areas. This paper selected biophysical and social–economic factors as independent variables, and constructed a multiple logistic regression of farmland spatial distribution probability by random sampling. Then, by using GIS technology and integrating the 2000 data, this study predicted the farmland spatial pattern. When the predicted map was compared with the actual farmland map for 2000, we noted that 71% of the simulation is in accordance with the 2000 farmland pattern. The result satisfactorily proves the reasonability and applicability of our model.     

Performance evaluation of a sorbent tube sampling method using short path thermal desorption for volatile organic compounds

Air sampling, using sorbents, thermal desorption and gas chromatography, is a versatile method for identifying and quantifying trace levels of volatile organic compounds (VOCs). Thermal desorption can provide high sensitivity, appropropriate choices of sorbents and method parameters can accommodate a wide range of compounds and high humidity, and automated short-path systems can minimize artifacts, losses and carry-over effects. This study evaluates the performance of a short-path thermal desorption method for 77 VOCs using laboratory and field tests and a dual sorbent system (Tenax GR, Carbosieve SIII). Laboratory tests showed that the method requirements for ambient air sampling were easily achieved for most compounds, e.g., using the average and standard deviation across target compounds, blank emissions were < or = 0.3 ng per sorbent tube for all target compounds except benzene, toluene and phenol; the method detection limit was 0.05 +/- 0.08 ppb, reproducibility was 12 +/- 6%, linearity, as the relative standard deviation of relative response factors, was 16 +/- 9%, desorption efficiency was 99 +/- 28%, samples stored for 1-6 weeks had recoveries of 87 +/- 9%, and high humidity samples had recoveries of 102 +/- 12%. Due to sorbent, column and detector characteristics, performance was somewhat poorer for phenol groups, ketones, and nitrogen containing compounds. The laboratory results were confirmed in an analysis of replicate samples collected in two field studies that sampled ambient air along roadways and indoor air in a large office building. Replicates collected under field conditions demonstrated good agreement except for very low concentrations or large (> 41 volume) samples of high humidity air. Overall, the method provides excellent performance and satisfactory throughput for many applications.