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111.
Membrane based treatment processes are very effective in removing salt from wastewater, but are hindered by calcium scale deposit formation. This study investigates the feasibility of removing calcium from treated sewage wastewater using accelerated seeded precipitation. The rate of calcium removal was measured during bench scale batch mode seeded precipitation experiments at pH 9.5 using various quantities of calcium carbonate as seed material. The results indicate that accelerated seeded precipitation may be a feasible option for the decrease of calcium in reverse osmosis concentrate streams during the desalination of treated sewage wastewater for irrigation purposes, promising decreased incidence of scaling and the option to control the sodium adsorption ratio and nutritional properties of the desalted water. It was found that accelerated seeded precipitation of calcium from treated sewage wastewater was largely ineffective if carried out without pre-treatment of the wastewater. Evidence was presented that suggests that phosphate may be a major interfering substance for the seeded precipitation of calcium from this type of wastewater. A pH adjustment to 9.5 followed by a 1-h equilibration period was found to be an effective pre-treatment for the removal of interferences. Calcium carbonate seed addition at 10 g l−1 to wastewater that had been pre-treated in this way was found to result in calcium precipitation from supersaturated level at 60 mg l−1 to saturated level at 5 mg l−1. Approximately 90% reduction of the calcium level occurred 5 min after seed addition. A further 10% reduction was achieved 30 min after seed addition. 相似文献
112.
Control of hazardous organic micropollutants is a challenging water quality issue. Dissolved humic organic matter (DOM) isolated from oxyhumolite coal mined in Bohemia was investigated as a complexation agent to remove polycyclic aromatic hydrocarbons (PAHs) and functionalized phenols from water by a two-stage process involving complexation and flocculation. After the formation of humic-contaminant complexes, ferric salts were added resulting in the precipitation and flocculation of the DOM and the associated pollutants. Flocculation experiments with ferric ion coagulants indicated that precipitation of oxyhumolite DOM together with the complexed contaminants occurred at lower ferric ion concentrations than with the reference DOM in acidic environments (pH approximately 3.5). The complexation-flocculation removal rates for non-reactive PAHs characterized by small localization energies of pi-electrons correlated well with the complexation constants. On the other hand, the combined complexation-flocculation removal rates for activated PAHs including trans-stilbene, anthracene and 9-methyl anthracene, as well as functionalized polar phenols, were higher than predicted from the complexation coefficients. Methodological studies revealed for the first time that the ferric ion coagulant contributed to enhanced removal rates, most probably due to ferric ion-catalyzed pollutant degradation resulting in oxidized products. 相似文献
113.
Peter Brooker 《Safety Science》2010,48(7):831-844
SESAR, the ‘Single European Sky Air traffic Research’ program, envisages radical changes for European Air Traffic Management (ATM). It integrates and implements new technologies and information processing. This paper examines the safety decision-making in the implementation of SESAR projects. SESAR poses new safety problems because it adopts new paradigms for ATM safety – what lessons are there from environmental, nuclear and defense modeling? These disciplines have also had to confront the limitations of modeling the rates of rare and damaging – even catastrophic – events. A major conceptual change in SESAR is that of automated separation assurance systems. Some existing responsibilities transfer from the controller – either to the pilot or to computer systems – in a progressively phased approach. The major problem for SESAR safety validation is that mixed equipage/operations within a common airspace potentially generate new and different safety issues regarding the validation of safety predictions. A potential way forward uses high-fidelity Human In The Loop Simulations (HITLS) to generate confidence in the resilience of the ATM system. The focus changes from proving safety, i.e. through traditional kinds of validation processes, to extensive resilience testing using these simulations. The aim would be to test how resilient the system is to seeded errors, penetration testing, and crash/stress testing. This would be a high cost process because of the large investments required and the need for long sequences of testing. However, these demanding processes can provide ‘justified belief’ to the decision-maker that the changed ATM system is acceptably safe. 相似文献
114.
115.
Peter M. Haas 《中国人口.资源与环境(英文版)》2017,15(3):186-188
<正>1.Introduction And now we have Parxit.On 1 June 2017,President Trump issued the highly unpopular announcement that the United States will withdraw from the 2015 Paris Agreement on Climate Change.In this brief piece,I will try to explain the reasons for this nearly unprecedented act of foreign policy folly(Ronald Reagan did pull out of the Law of the Sea 相似文献
116.
117.
Günter Gunkel Florian Selge Jonas Keitel Debora Lima Silvana Calado Maria Sobral Maricela Rodriguez Elena Matta Reinhard Hinkelmann Peter Casper Michael Hupfer 《Regional Environmental Change》2018,18(7):1913-1925
Reservoirs have a wide variety of uses that have led to frequent conflicts over ecological conservation and contamination, especially as land management has intensified. Oligotrophication must be implemented in numerous tropical reservoirs that experience advanced eutrophication to maintain aquatic ecosystem functions. To quantify impacts on ecosystem functions and to develop an adaptive management policy, multiple studies have been conducted on the Itaparica Reservoir, São Francisco River, in the semi-arid north-eastern region of Brazil. Here, we add to that existing body of knowledge through investigating how nutrient accumulation is affected by water exchange between the main river flow and Icó-Mandantes Bay. Operational water-level fluctuations in the reservoir create large desiccated littoral areas that release high amounts of nutrients when they are rewetted. In particular, water-level variation promotes proliferation of Egeria densa, a noxious weed, thus elevating trophic levels of the Itaparica Reservoir and Icó-Mandantes Bay. Analysis with a P efficiency model determined 25 μg P L?1 to be the critical concentration and further indicated that the critical load in both bodies of water have been exceeded. Moreover, intensive fish aquaculture using net cages has led to further overtaxing of the reservoir. We conclude that an effective ecological reservoir management policy must involve oligotrophication, harvesting of noxious water weeds for use as soil amendment in agriculture or biogas production, “blue” aquaculture, and limiting hydroelectric power production based on current water availability. 相似文献
118.
Hans J. M. van Grinsven Jan D. van Dam Jan Peter Lesschen Marloes H. G. Timmers Gerard L. Velthof Luis Lassaletta 《Regional Environmental Change》2018,18(8):2403-2415
This paper tests the hypothesis that relocation of pig production within the EU27 can reduce the external costs of nitrogen (N) pollution. The external cost of pollution by ammonia and nitrate from agriculture in the European Union (EU27) in 2008 was estimated at 61–215 billion € (0.5 to 1.8% of the GDP). Per capita it ranged from more than 1000 € in north-west EU27 to 50 € in Romania. The average contribution of pig production was 15%. Using provincial data (224 NUTS2 regions in EU27), the potential reduction of external N cost by relocation of pig production was estimated at 14 billion € (10% of the total). Regions most eligible for decreasing the pig stock were in western Germany, Flemish region, Denmark, the Netherlands and Bretagne, while Romania is most eligible for increasing pig production. Relocating 20 million pigs (13% of the total EU stock) decreased average external costs per capita from 900 to 785 € in the 13 NUTS2 regions where pigs were removed and increased from 69 to 107 € in 11 regions receiving pigs. A second alternative configuration of pig production was targeted at reducing exceedance of critical N deposition and closing regional nutrient cycles. This configuration relocates pigs within Germany and France, for example from Bretagne to Northern France and from Weser-Ems to Oberbayern. However, total external cost increases due to an increase of health impacts, unless when combined with implementation of best N management practices. Relocation of the pig industry in the EU27 will meet many socio-economic barriers and realisation requires new policy incentives. 相似文献
119.
Franziska?Pfister Peter?BacciniEmail author 《Environment, Development and Sustainability》2005,7(3):337-361
Food production has to be increased in a sustainable way to meet the future global demand. A key position is attributed to
developing countries. A deepened understanding of their agricultural regions with specific resource endowments and constraints
is therefore crucial. In this study we propose a methodology based on material flux analysis (MFA) to assess the resource
potentials and limitations of a Nicaraguan agricultural region. We focus on current regional and farm resource management
and explore them under two scenarios. Indicators are nitrogen and the degrees of self-sufficiency (DSS) for energy, and the
staples maize and beans. As data is scarce, most information is based on interviews with farmers of four categories and key
persons, and on literature.
The results show that nitrogen management does not differ considerably among categories. Nitrogen is mined mostly from staple
plots. Self-sufficiency for beans is given in an average year. Yet, landless and small farmers neither produce enough maize
for autoconsumption, nor are they self-sufficient for firewood. Energy supply is also the core problem of the region, since
the DSS is 70%. Soil nitrogen
stocks last at most for three more generations. Analyses with the scenario technique show that: (a) Unlimited population growth
has serious consequences in the near future e.g. severe shortage of energy and food. (b) Alternative farming systems are possible,
but they require reducing the population by a factor 2, and thus the creation of jobs in a Hinterland.
Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue. 相似文献
120.
The distribution of major and trace elements was systematically investigated by use of energy dispersive X-ray fluorescence spectrometry (EDXRF) on a former horticultural soil. The purpose of the study was to combine mapping of soil element concentration levels with multivariate statistics for characterisation of soil metal pollution in relation to previous and present land use. A 1-ha study site was chosen from a former horticulture where a previous preliminary survey indicated increased concentration levels of toxic elements. The soil was sampled from the top 20 cm of the soil surface in a 10 x 10-m grid-like pattern covering the 1-ha study area. In addition, three soil profiles were studied. The elemental composition of the soil samples was investigated by EDXRF while the composition of aqueous soil extracts was determined by total reflection X-ray fluorescence spectrometry (TXRF). Based on mapping and multivariate statistically analysis of the data obtained by EDXRF, most elements were found in almost constant concentration levels in the top soil throughout the investigated site. However, the contents of the toxic elements Zn, Cu, As, and Pb were found to vary significantly within the area. Hence, the samples with high accumulations of As also contained relatively high amounts of Zn, Cu, and Pb, which indicates that toxic-element-containing pesticides have been applied to the soil surface in the area of the former green houses at the study site. The Pb/As mass ratio in the soil indicates that PbHAsO3 was the preferential lead arsenate used for pest management at the investigated site, while Cu as Bordeaux liquid (CuSO4) and Zn were applied to minimize the leaf damaging effect from the former compounds. Calculations indicated that As annually was applied to the soil in the former greenhouses in doses up to 4 kg As/ha while Pb had been annually applied in doses up to 12 kg Pb/ha. The enrichment of Zn, Cu, As and Pb was greatest in the top 20 cm of the soil and no anthropogenic enrichment of these elements occurred below a depth of 50 cm, indicating that the toxic elements are rather immobile in this soil. The results of this investigation suggest that EDXRF used in combination with multivariate statistics is a strong tool for multi-element mapping of elemental contents, sources and mobility in the terrestrial environment. 相似文献