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761.
Michael R. Burkart Philip W. Gassman Thomas B. Moorman Piyash Singh 《Journal of the American Water Resources Association》1999,35(5):1089-1100
Data from seven Management Systems Evaluation Areas (MSEA) were used to test the sensitivity of a leaching model, Pesticide Root Zone Model-2, to a variety of hydrologic settings in the Midwest. Atrazine leaching was simulated because it was prevalent in the MSEA studies and is frequently detected in the region's groundwater. Short-term simulations used site specific soil and chemical parameters. Generalized simulations used data avail. able from regional soil databases and standardized variables. Accurate short-term simulations were precluded by lack of antecedent atrazine concentrations in the soil profile and water, suggesting that simulations using data for less than five years underestimate atrazine leaching. The seven sites were ranked in order of atrazine detection frequency (concentration > 0.2 μg L-1) in soil water at 2 m depth in simulations. The rank order of the sites based on long-term simulations were similar to the ranks of sites based on atrazine detection frequency from groundwater monitoring. Simulations with Map Unit Use File (MUUF) soils data were more highly correlated with ranks of observed atrazine detection frequencies than were short-term simulations using site-specific soil data. Simulations using the MIJUIF data for soil parameters were sufficiently similarity to observed atrazine detection to allow the credible use of regional soils data for simulating leaching with PRZM-2 in a variety of Midwest soil and hydrologic conditions. This is encouraging for regional modeling efforts because soil parameters are among the most critical for operating PRZM-2 and many other leaching models. 相似文献
762.
Inexpensive near-infrared diode lasers are now being used to enable high sensitivity, real time monitoring of gases both in open path measurements of urban air quality and in industrial environments for stack gas emission monitoring. Individual species are detected in a highly selective manner via overtone and combination bands of their vibrational spectra. Operating at room temperature and with simple optical components they can be made into portable instruments, ideal for field measurements. Combined with optical fibres they can be used for accessing remote and possibly dangerous locations. This paper presents current progress on the development of such a system illustrating recent results on ammonia monitoring at 1540 nm and acetylene at 780 nm. Sensitivities of the order of parts per million and below have been attained. Advantages and disadvantages of this approach to air pollution monitoring will be described. Pressure broadening results are also given for the 2v1 band of ammonia. 相似文献
763.
Long-term trends in nitrous oxide emissions, soil nitrogen, and crop yields of till and no-till cropping systems 总被引:3,自引:0,他引:3
No-till cropping can increase soil C stocks and aggregation but patterns of long-term changes in N2O emissions, soil N availability, and crop yields still need to be resolved. We measured soil C accumulation, aggregation, soil water, N2O emissions, soil inorganic N, and crop yields in till and no-till corn-soybean-wheat rotations between 1989 and 2002 in southwestern Michigan and investigated whether tillage effects varied over time or by crop. Mean annual NO3- concentrations in no-till were significantly less than in conventional till in three of six corn years and during one year of wheat production. Yields were similar in each system for all 14 years but three, during which yields were higher in no-till, indicating that lower soil NO3- concentrations did not result in lower yields. Carbon accumulated in no-till soils at a rate of 26 g C m(-2) yr(-1) over 12 years at the 0- to 5-cm soil depth. Average nitrous oxide emissions were similar in till (3.27 +/- 0.52 g N ha d(-1)) and no-till (3.63 +/- 0.53 g N ha d(-1)) systems and were sufficient to offset 56 to 61% of the reduction in CO2 equivalents associated with no-till C sequestration. After controlling for rotation and environmental effects by normalizing treatment differences between till and no-till systems we found no significant trends in soil N, N2O emissions, or yields through time. In our sandy loam soils, no-till cropping enhances C storage, aggregation, and associated environmental processes with no significant ecological or yield tradeoffs. 相似文献
764.
Alan E. Fryar Stephen A. Macko William F. Mullican III Katherine D. Romanak Philip C. Bennett 《Journal of contaminant hydrology》2000,40(4)
In arid and semi-arid environments, artificial recharge or reuse of wastewater may be desirable for water conservation, but NO3− contamination of underlying aquifers can result. On the semi-arid Southern High Plains (USA), industrial wastewater, sewage, and feedlot runoff have been retained in dozens of playas, depressions that focus recharge to the regionally important High Plains (Ogallala) aquifer. Analyses of ground water, playa-basin core extracts, and soil gas in an 860-km2 area of Texas suggest that reduction during recharge limits NO3− loading to ground water. Tritium and Cl− concentrations in ground water corroborate prior findings of focused recharge through playas and ditches. Typical δ15N values in ground water (>12.5‰) and correlations between δ15N and ln CNO−3–N suggest denitrification, but O2 concentrations ≥3.24 mg l−1 indicate that NO3− reduction in ground water is unlikely. The presence of denitrifying and NO3−-respiring bacteria in cores, typical soil–gas δ15N values <0‰, and decreases in NO3−–N/Cl− and SO42−/Cl− ratios with depth in cores suggest that reduction occurs in the upper vadose zone beneath playas. Reduction may occur beneath flooded playas or within anaerobic microsites beneath dry playas. However, NO3−–N concentrations in ground water can still exceed drinking-water standards, as observed in the vicinity of one playa that received wastewater. Therefore, continued ground-water monitoring in the vicinity of other such basins is warranted. 相似文献
765.
Over the last three decades, China’s coal industry has achieved dramatic increases in coal production, both in absolute terms and relative to the world as a whole. This achievement is due largely to its coal policies. Yet facing increasing pressures of environmental sustainability and market transition, the Chinese government was forced to make deep reforms and adjustments to regulate the coal industry effectively. This paper presents an historical overview of China’s coal economic policies, paying particular attention to the current reform policy of closing mines and restricting the yield for the small coal mines (SCMs) in the context of economic theories and methods. We argue that the SCM closure policy would not likely be efficiently enforced if a feasible market mechanism were not built up. The failure of closure policy is due largely to problems of property rights, coal pricing, ownership, and objectives. 相似文献
766.
Philip M. Fearnside 《The Environmentalist》1988,8(4):281-300
Summary The land uses that now predominate in Brazil's Amazon Region are unlikely to produce sustainable yields. They also tend to close off potentially sustainable alternative uses. Cattle pasture — either productive or abandoned — now occupies most deforested land. Small farmers plant pasture after using the land for a year or two under annual crops, while large cattle ranches plant pasture directly after clearing. The principal motive for planting pasture is often its low cost and high effectiveness as a means of securing speculative land claims — not beef production.Pasture and cattle yields are low and, after use for about a decade, the planted grasses are out-competed by secondary forest species or inedible grasses. Depletion of available phosphorus in the soil is a major cause of yield decline; Brazil's relatively modest phosphorus deposits, virtually all of which are outside of Amazonia, make fertiliser use not feasible for the vast areas now rapidly being converted to pasture. Converting a substantial portion of Amazonia to pasture would have potential climatic effects. Areas that can be planted in annual and perennial crops are restrained by world markets, as well as by soil quality and Brazil's limited stocks of the inputs needed for intensive agriculture.Recent initiatives for agricultural-ecological in Brazil's Amaoznian states could be a first step toward more rational land use. Immediate measures are needed to slow deforestation, to discourage unsustainable uses and to make sustainable alternatives profitable.Professor Philip Fearnside is currently Research Professor in the Department of Ecology at the National Institute for Research in the Amazon. The paper has been modified from an earlier version presented at the International Symposium on Alternatives to Deforestation held in Belém, Pará, Brazil in January 1988. 相似文献
767.
768.
Effective Population Size in Winter-Run Chinook Salmon 总被引:1,自引:0,他引:1
Winter-run chinook salmon from the Sacramento River, California, is federally listed as endangered. Since 1989 there has been aprogram to augment the natural population by capturing adults, artificially spawning them, raising tine young and releasing the smolt. Here we estimate the effective population size of these captive-raised fish, the natural run, and the combination of both groups over the three-year period from 1991 to 1993. We find that the most appropriate estimate of the effective population size of the captive-raised progeny is a variance estimate of effective population size standardized so that the number of released smolts returning to spawn was the same as the number of spawners used to produce the smolts originally. We have generated 10,000 random samples to simulate returns from these released progeny. The estimates of the effective population sizes in 1991, 1992, and 1993 were only 7.02, 19.07, and 7.74, respectively. We then determined limits on the effective population size of the natural run based on 0.1 and 0.333 of the run-size estimates. Using estimates of the captive proportion of the run, the minimum estimates of the effective population size of the overall run for the three years were 21.9, 127.3, and 39.0, and the maximum estimates were 61.6, 401.0, and 108.7. It does not appear that the hatchery program has reduced the overall effective population size. The run sizes in each year are extremely low, however, and it is possible that fish will be lost from this run in one of the years in the immediate future, making reestablishment of a healthy run even more difficult. 相似文献
769.
770.
This paper presents a procedure for estimating the distribution of ionic material in the NH3-HNO3-H2SO4-NaCl system and applies this procedure in a particular case. The data used were measurements of HNO3, NH3, NO
3
–
, SO
4
–
, NH
4
+
Cl– and Na+ performed during February 1989 – February 1990 in a central Athens street with high traffic density. According to the procedure, ions combine in the following manner: Na+ combines preferentially with SO
4
–
, then with NO
3
–
, followed by NH
4
+
with the remaining SO
4
–
and then with the remaining NO
3
–
to form bisulphates, sulphates and nitrates. The combination procedure showed that the main constituents of the NH3-HNO3-H2SO4-NaCl system are primarily (NH4)2SO4 and, to a lesser extent, NH4NO3 and NH4HSO4, with mean and maximum concentrations, during morning hours, (NH4)2SO4: 14.5 (max 46.8), NH4NO3: 2.97 (max 23) and NH4HSO4: 1.78 (max 40.6) µg m–3. Lower concentations of Na2SO4, NaHSO4, NaNO3 and NH4Cl and very low concentrations of H2SO4 are also present, depending on the availability of NaCl. It became apparent from the ionic distribution that there is sufficient NH3 to neutralize the H2SO4 and HNO3. It was also shown that a significant fraction of the HNO3, especially on days with high pollution, occurs as aqueous NO
3
–
. A number of empirical equations have been proposed, which enable the approximate estimation of the constituents of the NH3-HNO3-H2SO4-NaCl system from air pollution monitoring data and meteorological parameters. 相似文献