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61.
Improved techniques are needed to monitor toxic aminophenols in industrial wastewater. Microchip capillary electrophoresis
(CE)-electrochemical detection (ECD) can be used to develop miniaturized system providing on-site monitoring. Here, a dual-channel
microchip CE-ECD has been applied for the monitoring of aminophenols. The effect of conductance and capacitance between a
working electrode and a reference electrode has been studied to minimize the noise that was generated in the amperometric
detection. A mixture of aminophenols dissolved in a running buffer has been monitored. A separation efficiency with a plate
number of 4770 and a high linear concentration dependence from 100 nM to 1 mM have been achieved for p-aminophenol. As a result, the analysis system has been applied for the monitoring of the pollutants with low detection limits
of p-aminophenol (14.6 nM), o-aminophenol (10.6 nM) and m-aminophenol (15.3 nM). Here, we show that a wastewater sample from a natural gas refinery can be monitored using the microchip
CE-ECD system. 相似文献
62.
JaeYoon Lee SungJun Park Cheonghoon Lee Kyuseon Cho Yong Seok Jeong Young-Mog Kim Kwon-Sam Park Jong Duck Choi Yongsik Sin GwangPyo Ko 《Food and environmental virology》2020,12(3):240-249
Human and animal feces are important sources of various types of microbial contamination in water. Especially, enteric viruses, the major agents of waterbo 相似文献
63.
Lim CY Yoo YH Sidharthan M Ma CW Bang IC Kim JM Lee KS Park NS Shin HW 《Journal of environmental biology / Academy of Environmental Biology, India》2006,27(3):461-466
In copper based antifouling (AF) paints Cu (I) oxide was largely used as booster biocide. In this study effect of Cu (I) oxide on two marine microalgae, Tetraselmis suecica and Dunaliella tertiolecta was demonstrated. EC50 (96 hr) concentrations estimated for T. suecica and D. tertiolecta were 1.3 mg l(-1) and 1.34 mg l(-1), respectively. Copper (I) oxide induced changes in growth, chlorophyll, carbohydrate and protein contents were observed in T. suecica and D. tertiolecta. At low concentration of 0.0625 mg l(-1), 3-26% and 1-16% growth stimulation was observed in T. suecica and T. tertiolecta respectively. Increasing Cu (I) oxide concentrations proportionately decreased the carbohydrate and protein contents. This study clearly indicates the toxicity of excessive Cu (I) oxide on growth and biochemical compositions of T. suecica and D. tertiolecta. 相似文献
64.
65.
de Jong JT Boye M Schoemann VF Nolting RF de Baar HJ 《Journal of environmental monitoring : JEM》2000,2(5):496-502
An overview is presented of sampling techniques and flow injection analysis (FIA) methods for low concentrations of Fe, Mn and Al in filtered seawater. On the basis of sampling procedures, filtration techniques, accuracy, blanks, detection limits, intercalibration results and oceanographic consistency, the feasibility of these FIA methods was evaluated. It was found that these metals could be measured on board with a minimum risk of contamination and with good accuracy even at low subnanomolar levels (<0.5 nM). Results for reference seawater were in the case of Fe-FIA and Mn-FIA in excellent agreement with the certified values. Data from samples analyzed by Fe-FIA and by cathodic stripping voltametry (CSV) compared well, as did Mn-FIA and GFAAS. All three methods gave results that were mostly in good agreement with data from the same ocean regions published by other research groups. Two different types of surface water sampling were also tested and compared, namely conventional hand filling of a sample bottle from a rubber dinghy away from the ship, and underway pumping of seawater using a 'tow fish'. The latter method gave the best results. Also, conventional membrane filtration and cartridge filtration for large volume filtration were compared using Fe and Al data from water column samples. Good agreement was found for both filter types, although for defining dissolved metal species the latter filter type was preferred. 相似文献
66.
67.
Airborne particulate matter (PM) concentrations were measured in Iksan, a suburban area in South Korea during April, 2003.
PM2.5 (particles with an aerodynamic diameter less than 2.5 μm) and PM10 (particles with an aerodynamic diameter less than 10 μm) samples were collected, and the chemical characteristics of particles
were examined for diurnal patterns, yellow dust/rainfall influences, and scavenging effects. Average concentrations of PM2.5 and PM10 mass measured were 37.3 ± 16.2 μg m−3 and 60.8 ± 29.5 μg m−3, respectively. The sum of ionic chemical species concentrations for PM2.5 and PM10 was 16.9 ± 7.3 and 23.1 ± 10.1 μg/m3, respectively. A significant reduction in PM mass concentrations during rainfall days was observed for coarse mode (PM2.5 − 10) particles, but less reduction was found for fine (PM2.5) mass concentration. SO4
2−, NH4
+, and K+ predominated in fine particulate mode, NO3
− and Cl− predominated in fine particle mode and coarse particle mode, but Na+, Mg2+, and Ca2+ mostly existed in coarse mode. The high concentration of ammonium due to local emissions and long-range transport neutralized
sulfate and nitrate to ammonium sulfate and ammonium nitrate, which were major forms of airborne PM in Iksan. Average mass
concentrations of PM10 in daytime and at night were 57.6 and 70.0 μg m−3, and those of PM2.5 were 35.4 and 42.5 μg m−3, respectively. NO3
− and Cl− in both PM2.5 and PM10 were about double at night than in the daytime, while the rest of the chemical species were equal or a little higher at night
than in the daytime. The results suggest the formation of ammonium nitrate and chloride when high ammonia concentration and
low air temperature are allowed. Backward air trajectory analyses showed that air masses arriving at the site during yellow
dust period were transported from arid Chinese regions, which resulted in high concentrations of airborne PM mass concentrations.
In the meantime, air mass trajectories during a rainfall period were mostly from the Pacific Ocean or the East China Sea,
along with a relatively low PM concentration. 相似文献
68.
Antecedents and consequences of satisfaction with work–family balance: A moderating role of perceived insider status 下载免费PDF全文
This study developed a moderated mediation model to investigate how family‐supportive paid leave and supervision affect employees' satisfaction with work–family balance and in turn their affective organizational commitment and supervisor‐directed organizational citizenship behavior depending on their perceived insider status in the organization. Our analysis of data collected from 118 employee–supervisor dyads in Korean organizations revealed that satisfaction with work–family balance mediated the linkages from family‐supportive supervision to affective organizational commitment and supervisor‐directed organizational citizenship behavior, and the linkage from family‐supportive paid leave to affective organizational commitment. Results further showed that the entire mediational process for family‐supportive supervision was more pronounced for those who perceived themselves to be an insider of their organizations, while the same pattern was not found for the meditational process related to family‐supportive paid leave. Our findings provide theoretical implications for work–family balance research and offer practical suggestions to make employees satisfied with work–family balance. 相似文献
69.
Ab Grootjans Rohani Shahrudin Annelies van de Craats Annemieke Kooijman Gerard Oostermeijer Jörg Petersen Donovan Amatirsat Chantal Bland Pieter Stuyfzand 《Journal of Coastal Conservation》2017,21(5):631-641
The present study aims at assessing the life span of populations of the orchid L. loeselii during successional in dune slacks on the Wadden Sea islands. An inventory of Liparis loeselii populations was carried out on 6 islands, while the population structure was assessed in more detail on the island of Texel. The occurrence of the orchid was related to soil factors and hydrological conditions. Groundwater levels were measured in a dune area with natural dune slack formation. The groundwater composition was analyses and the freshwater lenses were modelled. Various scenarios were investigated, including sea level rise and sand nourishment. The window of opportunity for L. loeselii to colonize a new slack is relatively narrow. Under favorable management, the population can survive c. 20 years. Soil pH was positively correlated with the occurrence of L. loeselii populations, while a high organic matter content was negatively correlated. Sites with large populations of L. loeselii, were situated in young dune slacks, that functioned as flow-through lakes and has top soilsinfluenced by anoxic calcareous groundwater. Modelling showed that the freshwater lens would decrease due to sea level rise, while artificial sand nourishment could counteract this effect. The populations of the Hors area on Texel, the Netherlands, can survive for several decades due to continuous formation of new slacks. Discharge of calcareous groundwater is essential to keep the pH on a high level. The hydrological systems that supply dune slack with groundwater are relatively small and are vulnerable for changes in sea level rise. 相似文献
70.
Development of a SWAT Patch for Better Estimation of Sediment Yield in Steep Sloping Watersheds1 总被引:1,自引:0,他引:1
Jong‐Gun Kim Younshik Park Dongsun Yoo Nam‐Won Kim Bernard A. Engel Seong‐joon Kim Ki‐Sung Kim Kyoung Jae Lim 《Journal of the American Water Resources Association》2009,45(4):963-972
Abstract: The watershed scale Soil and Water Assessment Tool (SWAT) model divides watersheds into smaller subwatersheds for simulation of rainfall‐runoff and sediment loading at the field level and routing through stream networks. Typically, the SWAT model first needs to be calibrated and validated for accurate estimation through adjustment of sensitive input parameters (i.e., Curve Number values, USLE P, slope and slope‐length, and so on). However, in some instances, SWAT‐simulated results are greatly affected by the watershed delineation and Digital Elevation Models (DEM) cell size. In this study, the SWAT ArcView GIS Patch II was developed for steep sloping watersheds, and its performance was evaluated for various threshold values and DEM cell size scenarios when delineating subwatersheds using the SWAT model. The SWAT ArcView GIS Patch II was developed using the ArcView GIS Avenue program and Spatial Analyst libraries. The SWAT ArcView GIS Patch II improves upon the SWAT ArcView GIS Patch I because it reflects the topographic factor in calculating the field slope‐length of Hydrologic Response Units in the SWAT model. The simulated sediment value for 321 subwatersheds (watershed delineation threshold value of 25 ha) is greater than that for 43 subwatersheds (watershed delineation threshold value of 200 ha) by 201% without applying the SWAT ArcView GIS Patch II. However, when the SWAT ArcView GIS Patch II was applied, the difference in simulated sediment yield decreases for the same scenario (i.e., difference in simulated sediment with 321 subwatersheds and 43 subwatersheds) was 12%. The simulated sediment value for DEM cell size of 50 m is greater than that for DEM cell size of 10 m by 19.8% without the SWAT ArcView GIS Patch II. However, the difference becomes smaller (3.4% difference) between 50 and 10 m with the SWAT ArcView GIS Patch II for the DEM scenarios. As shown in this study, the SWAT ArcView GIS Patch II can reduce differences in simulated sediment values for various watershed delineation and DEM cell size scenarios. Without the SWAT ArcView GIS Patch II, variations in the SWAT‐simulated results using various watershed delineation and DEM cell size scenarios could be greater than those from input parameter calibration. Thus, the results obtained in this study show that the SWAT ArcView GIS Patch II should be used when simulating hydrology and sediment yield for steep sloping watersheds (especially if average slope of the subwatershed is >25%) for more accurate simulation of hydrology and sediment using the SWAT model. The SWAT ArcView GIS Patch II is available at http://www.EnvSys.co.kr/~swat for free download. 相似文献