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591.
592.
微酸多年卧孔菌产漆酶条件优化及其在染料脱色中的应用 总被引:4,自引:0,他引:4
微酸多年卧孔菌(Perenniporia subacida)产漆酶能力对生物漂白等研究具有重要意义.通过单因子和正交试验确定了微酸多年卧孔菌(菌株号:Dai 8224)的最适产酶条件:麦芽糖20 g/L,酵母浸粉5 g/L,pH 5.4,Cu2+2.0 mmol/L,培养温度24℃,转速160 r/min,接种量1.5%(V/V),此时酶活最高可达1.945 U/mL.单独使用微酸多年卧孔菌漆酶粗酶液对染料具有很好的脱色效果.该菌株对于50 mg/L杂环类染料中性红的脱色率可达98.3%,对偶氮染料刚果红的脱色率次之,为91.57%,对亚甲基蓝和铬天青的脱色率也都在80%以上.此外,其催化中性红脱色的最佳底物浓度为60 mg/L,脱色率达到99.42%,其中,生物降解作用占55.92%,菌体吸附作用占43.5%.结果表明该菌对多种染料脱色具有较大的应用潜力.图4表3参31 相似文献
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594.
为提高职业健康安全管理体系(OHSMS)绩效和职业健康安全绩效,根据OHSMS绩效评价的重要性,提出基于二元语义的OHSMS绩效评价模型。研究科学合理的评价指标体系,并运用层次分析法(AHP)和灰色关联分析法(GRA)确定主客观权重,再运用乘法集成法确定组合权重,作为评价指标的最终权重,运用二元语义的集结算子,计算OHSMS绩效评价指标的综合值,取得最终的评价结果。结果表明,基于二元语义的OHSMS绩效评价将专家经验与定量计算相结合,合理地处理许多因素的不确定性,通过确定不符合项和改进措施,持续改进OHSMS绩效。 相似文献
595.
Jian-jun Jiang Li Zhang Yi-qun Wang Yu-yuan Peng Kun Zhang Wen He 《Safety Science》2011,49(6):843-851
Monitoring process is an important part in a high safety digital main control room of nuclear power plant (NPP), it is the source extracted information and found abnormal information in time. As the human factors events arisen from monitoring process recently take place more and more frequent, the authors propose a reliability Markov model to effectively decrease these abnormal events. The model mainly analyzes next monitoring object probability in terms of current information and plant state. The authors divide digital human–machine interface into two parts that are referred as logical homogeneous Markov and logical heterogeneous Markov. For the former, a series of methods of probability evaluation are proposed, such as, Markov transition probability with condition, probability distributed function with human factors, system state and alarm; for the latter, the authors propose the calculation of probability of correlation degree between last time and next time and probability calculation methods with multi-father nodes. The methods can effectively estimate the transition probability from a monitoring component to next monitoring component at time t, can effectively analyze which information is more important in next monitoring process and effectively find more useful information in time t + 1, so that the human factors events in monitoring process can greatly be decreased. 相似文献
596.
本文简迷了皮肤防护器材--化学防护服(衣)化学防护性能试验与评价用标准物质的重要性,系统地概述了外军化学防护服(衣)化学防护性能试验与评价用标准物质的研究现状,并提出了我国化学防护服(衣)防护性能试验与评价用标准物质研制过程中应注意的一些问题. 相似文献
597.
臭氧已成为影响我国环境空气质量的重要污染物之一,准确解析环境臭氧及其前体物VOCs的关键源类及其贡献对于有效防控臭氧污染具有重要作用.因此,利用光化学年龄参数方法估算了青岛胶州市2021年1月1日至2月28日在线VOCs监测数据的初始浓度,矫正环境VOCs物种的光化学损耗;并利用正定矩阵因子分解(PMF)和臭氧生成潜势(OFP)模型进行了环境VOCs及其OFP来源解析研究,以期为青岛市环境臭氧污染的防控提供数据支撑.结果表明,研究期间青岛市环境ρ(TVOCs)和OFP的平均值分别为65.9μg·m-3和176.7μg·m-3;其中丙烷浓度(12.4μg·m-3)和占比(18.9%)最高,而间/对-二甲苯的OFP(24.6μg·m-3)及占比(13.9%)最高.研究期间TVOCs的初始浓度为153.1μg·m-3,其光化学损耗率达到63.8%.烯烃是光化学损耗率(92.1%)最高的VOCs物种,其中异戊二烯的光化学损耗率达到98.6%,明显高于其它VOCs物种.基于初始浓度的来源... 相似文献
598.
Yuanhang Zhang Yuesi Wang Xin Jin Zirui Liu Gehui Wang Guiqian Tang Keding Lu Bo Hu Shanshan Wang Guohui Li Xinqin An Chao Wang Qihou Hu Lingyan He Fenfen Zhang 《环境科学学报(英文版)》2023,123(1):350-366
Atmospheric oxidizing capacity (AOC) is an essential driving force of troposphere chemistry and self-cleaning, but the definition of AOC and its quantitative representation remain uncertain. Driven by national demand for air pollution control in recent years, Chinese scholars have carried out studies on theories of atmospheric chemistry and have made considerable progress in AOC research. This paper will give a brief review of these developments. First, AOC indexes were established that represent apparent atmospheric oxidizing ability (AOIe) and potential atmospheric oxidizing ability (AOIp) based on aspects of macrothermodynamics and microdynamics, respectively. A closed study refined the quantitative contributions of heterogeneous chemistry to AOC in Beijing, and these AOC methods were further applied in Beijing-Tianjin-Hebei and key areas across the country. In addition, the detection of ground or vertical profiles for atmospheric OH·, HO2·, NO3· radicals and reservoir molecules can now be obtained with domestic instruments in diverse environments. Moreover, laboratory smoke chamber simulations revealed heterogeneous processes involving reactions of O3 and NO2, which are typical oxidants in the surface/interface atmosphere, and the evolutionary and budgetary implications of atmospheric oxidants reacting under multispecies, multiphase and multi-interface conditions were obtained. Finally, based on the GRAPES-CUACE adjoint model improved by Chinese scholars, simulations of key substances affecting atmospheric oxidation and secondary organic and inorganic aerosol formation have been optimized. Normalized numerical simulations of AOIe and AOIp were performed, and regional coordination of AOC was adjusted. An optimized plan for controlling O3 and PM2.5 was analyzed by scenario simulation. 相似文献
599.
红色旅游资源是革命精神的核心载体,其保护和旅游利用面临着破碎化、片段化、静态化等问题,亟需开展整合开发研究。以中央苏区核心区为例,基于文化生态学理论,采用GIS空间分析方法和修正的引力模型,研究红色旅游资源空间格局和文化生态变迁,在此基础上提出整合开发的策略,结论如下:(1)红色旅游资源点空间上呈现局部聚集特征,赣南苏区形成章贡区、瑞金市、于都县“金三角”分布格局,闽西苏区则形成新罗区、永定区、上杭县、连城县“银菱形”分布格局;(2)闽西和赣南苏区各重大事件红色旅游资源点在空间上8.9~106.6 km的范围内,形成带状或面状的文化生态基底,并呈现一致向服务业主导型转变的发展态势;(3)红色旅游资源网络联系方向与服务业主导型文化生态方向错位发展,这是赣南和闽西红色旅游资源内部网络联系度较强,跨区域网络联系度较弱的重要原因。在此基础上,遵循红色旅游资源文化生态空间一体化、文化生态演变全域化、文化生态发展动态化的原则,提出空间集聚区优先整合开发、高发展指数红色旅游资源跨省域优先整合开发、跨主导类型关键节点优先整合开发三个整合开发对策,以期促进中央苏区红色旅游高质量发展。 相似文献
600.
Jin Xie Xiao-Dong Niu Jiao-Jiao Xie Kai-Qiang He Meng-Dan Shi Su-Juan Yu Chun-Gang Yuan Jing-Fu Liu 《环境科学学报(英文版)》2021,33(10):1-7
The distribution and chemical speciation of arsenic (As) in different sized atmospheric particulate matters (PMs), including total suspended particles (TSP), PM10, and PM2.5, collected from Baoding, China were analyzed. The average total mass concentrations of As in TSP, PM10, and PM2.5 were 31.5, 35.3, and 54.1 µg/g, respectively, with an order of PM2.5 >PM 10 > TSP, revealing that As is prone to accumulate on fine particles. Due to the divergent toxicities of different As species, speciation analysis of As in PMs is further conducted. Most of previous studies mainly focused on inorganic arsenite (iAsIII), inorganic arsenate (iAsV), monomethylarsonate (MMA), and dimethylarsinate (DMA) in PMs, while the identification and sensitive quantification of trimethylarsine oxide (TMAO) were rarely reported. In this study, a high-performance liquid chromatography coupled to inductively coupled plasma mass spectrometry system was optimized for As speciation including TMAO in PMs. An anion exchange column was used to separate MMA, DMA and iAsV, while a cation exchange column to separate TMAO and iAsIII. Results showed that iAsV was the dominate component in all the samples, corresponding to a portion of 79.2% ± 9.3% of the total extractable species, while iAsIII, TMAO and DMA made up the remaining 21%. Our study demonstrated that iAsIII accounted for about 14.4% ± 11.4% of the total extracted species, with an average concentration of 1.7 ± 1.6 ng/m3. It is worth noting that TMAO was widely present in the samples (84 out of 97 samples), which supported the assumption that TMAO was ubiquitous in atmospheric particles. 相似文献