火焰原子吸收法测定水中铁的不确定度评定

测量不确定度是表征合理地赋予被测量值的分散性,与测量结果相联系的参数,通过火焰原子吸收分光光度法对水中铁的不确定度进行评定,确定铁测量不确定度的来源主要为工作曲线拟合、消解过程、重复测定和分析仪器,最主要来源是工作曲线,其他测量因素引起的分量较小,可以不予考虑。通过合理选择不确定度分量,优化评定过程,减少评定环节,达到对不确定度合理评定的目的。     

The impact of different voltage application modes on biodegradation of chloramphenicol and shift of microbial community structure

● Presented coupled system enhanced biodegradation of antibiotic chloramphenicol. ● HRT and electrical stimulation modes were key influencing factors. ● Electrical stimulation had little effect on the chloramphenicol metabolic pathway. ● Microbial community structure varied with the voltage application mode. Exoelectrogenic biofilms have received considerable attention for their ability to enhance electron transfer between contaminants and electrodes in bioelectrochemical systems. In this study, we constructed anaerobic-aerobic-coupled upflow bioelectrochemical reactors (AO-UBERs) with different voltage application modes, voltages and hydraulic retention times (HRTs). In addition, we evaluated their capacity to remove chloramphenicol (CAP). AO-UBER can effectively mineralize CAP and its metabolites through electrical stimulation when an appropriate voltage is applied. The CAP removal efficiencies were ~81.1%±6.1% (intermittent voltage application mode) and 75.2%±4.6% (continuous voltage application mode) under 0.5 V supply voltage, which were ~21.5% and 15.6% greater than those in the control system without voltage applied, respectively. The removal efficiency is mainly attributed to the anaerobic chamber. High-throughput sequencing combined with catabolic pathway analysis indicated that electrical stimulation selectively enriched Megasphaera, Janthinobacterium, Pseudomonas, Emticicia, Zoogloea, Cloacibacterium and Cetobacterium, which are capable of denitrification, dechlorination and benzene ring cleavage, respectively. This study shows that under the intermittent voltage application mode, AO-UBERs are highly promising for treating antibiotic-contaminated wastewater.     

Impact of waste of COVID-19 protective equipment on the environment,animals and human health: a review

Environmental Chemistry Letters - During the Corona Virus Disease 2019 (COVID-19) pandemic, protective equipment, such as masks, gloves and shields, has become mandatory to prevent person-to-person...     

Quantifying ecosystem service mismatches for land use planning: spatial-temporal characteristics and novel approach—a case study in Jiangsu Province,China

Environmental Science and Pollution Research - Land use and land cover changes associated with urbanization have had a significant influence on ecosystem services (ESs), but previous studies have...     

OMEGA算法在导弹振动工程中的应用

目的研究位移、速度和加速度谱之间的转换关系,给出三者功率谱密度之间的转换公式,进而用于导弹运输振动环境的设计。同时,研究加速度信号转换为振动位移的方法,并应用于导弹舱内单机设备安全间隙的设计。方法利用OMEGA算法,首先将加速度传感器测得的加速度时域信号转换成加速度频域信号,随后将加速度谱转换成位移谱,并计算位移谱中每个谱线对应的幅值、相位和圆频率,最后将各位移分量简单叠加得到振动位移的时间历程。结果采用该方法计算了高速公路上导弹的运输振动位移功率谱,并得到垂向、横向和纵向的峰-峰位移分别为3.32,0.46,2.14 mm。同时,计算了飞行环境下导弹舱内单机设备的振动位移,与所测得位移在幅值上相当,时域曲线形态一致。结论该方法能够很好地应用于导弹振动工程设计。     

Characterization of phosphorus species and modeling for its organic forms in eutrophic shallow lake sediments,North China

Variations of phosphorus （P） and its species in surface sediment of Baiyangdian Lake, a eutrophic shallow lake located in North China, were investigated through combination of field survey and numerical calculation based on cluster analysis. P fractionation was performed by a sequential extraction scheme, categorized as loosely bound P （NH4Cl-P）, reductant soluble P （BD-P）, metallic oxide bound P （NaOH-P）, calcium bound P （HCl-P） and organic P （Org-P）. P concentrations exhibited regional similarities and a total of four sub-areas were identified in which the same rank was HCl-P 〉 Org-P 〉 BD-P ,=NaOH-P 〉NH4Cl-E NH4Cl-P, BD-P and Org-P were found to contribute to P enrichment in overlying water column. Specifically, labile Org-P acted as a potential pool with a greater contribution in aerobic layer compared to anaerobic layer. A hysteresis （lag = 4 months） existed when labile Org-P concentration was negatively correlated with aerobic layer thickness. In view of magnitude of identified P contributors in sub-areas, higher potential of P release was present in Fuhe River and Tang River estuary areas. On the basis of calibration and verification, the mathematical model with parameter settings applied in this study was improved to serve as a tool for limnology management and eutrophic control.     

北京冬季大气中多溴联苯醚的污染水平和分布特征

2010年11月至2011年2月利用聚氨酯泡沫(PUF)大气被动采样技术采集了北京市海淀、朝阳、丰台、石景山、昌平、大兴、通州等区域的大气样品,采用高分辨气相色谱/高分辨质谱联用法(HRGC/HRMS)分析了其中13种多溴联苯醚(PBDEs)同族体的污染浓度和分布特征.结果表明,北京大气中PBDEs总含量(Σ13PBDEs)为0.97~41.1pg/m3,平均值为7.85pg/m3.在区域分布规律方面呈现东南地区的采样点污染物浓度明显高于西北地区,工业地区和人口密集的商业地区明显高于郊区和背景对照区的分布特征.     

改性壳聚糖混凝去除太湖藻研究

对太湖不同区域的水使用改性壳聚糖做混凝除藻实验。对于泵取水,投加量0.7 mg/L时,藻去除率可达89.6%,对于岸边高浓藻水,投加量4 mg/L,0.5 h内藻去除率即可达为85.77%。改性壳聚糖复配黏土可解决岸边高浓藻絮体的上浮问题,黏土投加0.8 g/L絮体可完全下沉,除藻率fe从85.77%提升到94.35%。但复配黏土造成UV254去除率下降。改性壳聚糖复配0.3 g/L PDMDAAC改性粉煤灰投加或复配0.4 g/L改性沸石时,絮体也可完全下沉,除藻率都可提升到98%以上。同时,两种药剂都加强了系统对有机物的去除,UV254去除率从56.94%提升到72%以上。     

不同气候生态条件下水稻品种产量、功能性成分含量及稳定性

培育高γ-氨基丁酸和抗性淀粉的水稻品种,并明确其适宜的生态条件是水稻功能性育种和栽培的重要环节之一.选用云南和浙江近期育成的水稻Oryza sativa L.粳籼品种(系)21个,按粳籼品种(系)分组后分别在云南粳籼稻区10个点种植,比较研究不同生态条件其产量、γ-氨基丁酸和抗性淀粉含量变异及稳定性.结果表明:供试11个粳稻品种(系)产量的平均值为8 485.0kg/hm2,变化幅度为4 129.8～10 159.2 kg/hm2,其中以HIPjl最低.10个籼稻品种(系)产量变化范围在380.1～7 995.6 kg/hm2,其中以W229最低.滇农S-1/毫梅、滇农S-1/滇靖8号、功米6号、文稻1号/IR36和RS21属于高产而稳定性较好的品种.粳稻平均GABA的含量在108.7～157.1 mg·kg-1之间,平均值为128.9 mg·kg-1;其抗性淀粉含量在0.48%～0.73%之间,平均值为0.62%.籼稻品种的平均GABA含量在86.1～186.9 mg·kg-1之间,平均值为133.04 mg·kg-1,变异系数范围为2.33%～19.75%;其平均抗性淀粉含量为0.18%～2.52%,平均值为0.85%.其中滇农S-1/毫梅、功米6号、银光、HIPil和文稻2号/IR36属于高GABA而稳定性较好的品种.滇农S-1/毫梅、65-36/云粳136、功米6号、RS21和滇屯502/双籼稻属于高RS而稳定性较好的品种.不同气候生态条件下参试品种的GABA和RS的变异,籼稻大于粳稻.     

Analysis of the phenolic compounds in root exudates produced by a subalpine coniferous species as responses to experimental warming and nitrogen fertilisation

In terrestrial ecosystems, plant root exudates clearly play a crucial role in the belowground ecosystem. However, there have been few reports on root exudates from field-grown plants or mature trees in situ, especially when exposed to experimental warming. In this study, we adopted and modified a culture-based cuvette system developed especially for root exudation collection in the field to collect soluble root exudates of a subalpine coniferous species, Abies faxoniana, under experimental warming and nitrogen fertilisation treatments. We then analysed the chemical composition and relative abundance of root exudates using gas chromatography-mass spectrometry (GC-MS). The major chemical constituents of root exudates were phenols and their derivatives of all the different treatments, such as 2,6-di-tert-butyl-4-methylphenol. Experimental warming had significant effects on the relative contents of major compounds and an increase effect on the total phenolic acid compounds. By contrast, there were small significant effects of N fertilisation on root exudation and no significant effects of the warming×N fertilisation interaction. Meanwhile, warming also markedly increased soil polyphenol oxidase activity and it may be soil ecological adjustment response to changes of root exudation under global climate warming.