Stability analysis of alkaline nitrobenzene-containing wastewater by a catalyzed Fe-Cu treatment process

Iron and copper bimetallic system (catalyzed Fe-Cu process) is a promising technology for alkaline nitrobenzene-containing wastewater treatment. However, little is currently known about the changes of treatment efficiency with time going. This research investigated the long-term performance of the catalyzed Fe-Cu process to reduce nitrobenzene (NB) in alkaline wastewater. In addition, the changes of the metal surfaces morphologies and matters before and after the reaction were analyzed by scanning electron microscopy (SEM) in conjunction with energy-dispersion spectroscopy (EDS) and X-ray diffraction spectroscopy (XRD). The results showed that the surface properties of copper almost remained unchanged after weeks of operation, which spelled its strong chemical stability and resistance to poisoning. Moreover, the results indicated that there were two reasons for the treatment efficiency decreasing with time. One was the gradual iron element consumption due to corrosion. The other was iron reactivity weakened due to the precipitates accumulation on the surfaces that were mainly Fe₃O₄ and FeCO. __________ Translated from Environmental Pollution & Control, 2006, 28(10): 783–785 [译自: 环境污染与防治]     

臭氧控制膜污染的研究进展

本文对臭氧在控制膜污染方面的研究现状进行了综述,重点放在臭氧用于膜冲洗和臭氧用于过滤液预处理这两个方面;指明了在一定的条件下,臭氧可以有效地减缓、降低膜污染;臭氧控制膜污染的作用主要通过臭氧降解造成膜污染的有机物质来实现.此外,还介绍了一些臭氧与膜联用的开发应用情况.     

模糊数学法在环境质量评价中的应用 --以天津滨海新区为例

模糊评价能有效的解决评价标准边界模糊和监测误差对评价结果的影响,具有一定的科学性、合理性.运用模糊数学法对天津滨海新区环境质量各因素进行定级评价,将各因素评价结果采用公式计数法进行二级赋权,较为客观评价了总体环境质量级别,为综合治理提供科学依据.     

发达农村生活垃圾特性调查及治理技术探讨

为了了解我国发达地区农村垃圾特征,以丹阳市群楼村为研究对象,通过现场调查和问卷调查的方式分析了群楼村的垃圾特性,并对群楼村垃圾的集运方式、处理措施以及当地居民对垃圾的认识进行了调查。表明群楼村的垃圾已经具有城市垃圾的特征,但垃圾配套处理措施及居民意识远远没有达到要求。根据调查的结果探讨了适合群楼村以及发达地区农村生活垃圾集运方式与管理模式。     

纳米TiO_2-CS微球光催化降解亚甲基兰的研究

将用化学方法改性后的纳米TiO2与壳聚糖(CS)共混,通过反相悬浮、交联制备了纳米TiO2-CS微球光催化剂,以亚甲基兰为对象,紫外灯为光源,研究了亚甲基兰的初始浓度、光照时间、不同pH值、纳米TiO2的含量、催化剂用量对亚甲基兰光降解率的影响。结果表明:纳米TiO2-CS微球能显著地降解亚甲基兰,且易于回收、能重复使用,为其实际应用提供了有价值的参数。     

无排泥条件下HRT对膜生物反应器硝化性能的影响及其生物群落结构分析

以无机氨氮废水(NH+4 N,500mg·L-1)为处理对象,在不排泥条件下逐渐缩短膜生物反应器的水力停留时间(HRT,30h～5h),连续运行260d.在反应器内的氨氮容积负荷和污泥负荷分别为1 2kg·(d·L)-1和2 13kg·kg-1·d-1时,氨氮去除率达98 2%以上.当HRT减少至7h时开始出现NH+4 N和NO-2 N的积累.尽管反应器内MLSS随着运行时间的延长在逐步上升,氨氧化菌(AOB)和亚硝酸氧化菌(NOB)的数量分别从HRT10h和15h起开始下降.16SrDNA聚合酶链式反应结合变性梯度凝胶电泳(PCR DGGE)的分析发现反应器内生物多样性随着运行时间的延长而增加,测序结果表明进行氨氧化作用的主要是亚硝化单胞菌属(Nitrosomonassp.),进行亚硝酸氧化的主要是硝化螺菌属(Nitrospirasp.).尽管反应器只进行无机氨氮配水,仍存在大量的异养菌,估计其生长是以胞外分泌产物和细胞裂解产物为基质.     

一种新型复合式生物流化反应器混合特性的研究

对新型蜂窝状断面复合生物流化反应器进行了液体循环速率和水力停留时间分布曲线的测定，实验表明新型反应器具有抗冲击负荷强，接近CSTR反应器的特点，反应器随气量增大、载体投加量减少和进水量减少而更近似于CSTR反应器，通过理论分析，证明了影响液体循环速率的参数主要有气体流量(气含率)、反应器沿程和局部阻力系数以及Ad/Ar，并且得出液体循环速率与反应器高度的0．5次方成正比。     

人工湿地处理皂素废水生产性试验研究

黄姜是生产“药用黄金”——皂素的主要原材料，生产过程中会产生大量的工业废水。皂素废水是一种难降解、污染物浓度高的酸性废水，目前还没有成功应用于工程实际的废水处理工艺。本文主要采用人工湿地处理经两相厌氧工艺一好氧工艺组合工艺处理之后的废水，以满足达标排放的要求。经过4个月试验研究得出如下结论：人工湿地COD平均去除率为47．79％，氨氮平均去除率为75．64％，总磷平均去除率为88．82％。水平潜流型人工湿地作为皂素废水深度处理工艺是可行的。     

Present status and changes of the phytoplankton community after invasion of Neosalanx taihuensis since 1982 in a deep oligotrophic plateau lake, Lake Fuxian in the subtropical China

Phytoplankton assemblages in the subtrophical oligotrophic Lake Fuxian, the second deepest lake in China, were investigated monthly from September 2002 to August 2003. A total of 113 species belonging to seven phyla were identified, among them, a filamentous green alga, Mougeotia sp., dominated almost throughout the study period and comprised most of the total phytoplankton biomass.Mougeotia sp. has made a substantial development during the past decades: it was absent in 1957, only occasionally present in 1983,increased substantially in 1993, and became predominant in 2002--2003. It is likely that natural invasion of the Taihu Lake noodlefish (Neosalanx taihuensis) has led to a change of dominant herbivorous zooplankton from small to large calanoid, which has increased grazing pressure on small edible algae, and thus has indirectly favored the development of the inedible filamentous Mougeotia sp.     

微波/化学氧化/混凝协同处理垃圾渗滤液研究

针对难处理垃圾渗滤液,详细研究了微波/Fenton化学氧化/混凝工艺及其之间的协同作用。结果表明,该法能有效处理高浓度垃圾渗滤液,在H2O2和Fe2+用量分别为3.0g.L-1和0.12g.L-1,混凝剂PMSi用量为40mg.L-1,微波功率800W,共辐射2m in的最佳条件下,浊度、色度和CODCr去除率分别高达98.02%、97.33%和89.91%。