全文获取类型
收费全文 | 1198篇 |
免费 | 147篇 |
国内免费 | 363篇 |
专业分类
安全科学 | 154篇 |
废物处理 | 59篇 |
环保管理 | 92篇 |
综合类 | 793篇 |
基础理论 | 183篇 |
污染及防治 | 238篇 |
评价与监测 | 64篇 |
社会与环境 | 74篇 |
灾害及防治 | 51篇 |
出版年
2024年 | 4篇 |
2023年 | 28篇 |
2022年 | 92篇 |
2021年 | 77篇 |
2020年 | 84篇 |
2019年 | 64篇 |
2018年 | 76篇 |
2017年 | 67篇 |
2016年 | 64篇 |
2015年 | 89篇 |
2014年 | 74篇 |
2013年 | 101篇 |
2012年 | 118篇 |
2011年 | 107篇 |
2010年 | 92篇 |
2009年 | 88篇 |
2008年 | 81篇 |
2007年 | 82篇 |
2006年 | 58篇 |
2005年 | 42篇 |
2004年 | 33篇 |
2003年 | 25篇 |
2002年 | 36篇 |
2001年 | 28篇 |
2000年 | 10篇 |
1999年 | 14篇 |
1998年 | 12篇 |
1997年 | 18篇 |
1996年 | 8篇 |
1995年 | 6篇 |
1994年 | 3篇 |
1993年 | 3篇 |
1992年 | 5篇 |
1991年 | 5篇 |
1989年 | 2篇 |
1988年 | 5篇 |
1987年 | 2篇 |
1984年 | 1篇 |
1982年 | 2篇 |
1973年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有1708条查询结果,搜索用时 421 毫秒
341.
342.
343.
本文报导了大气颗粒物中多环芳烃的一种测定方法和结果。颗粒物预处理方法是:超声萃取,抽滤,减压蒸发浓缩,硅胶柱净化,再浓缩,定容溶解。用高效液相色谱法分离和鉴定。对西南石油学院5个功能区冬季大气颗粒物中的苯并(a)芘等9种多环芳烃的分布状况进行了实测,苯并(a)芘平均含量为26ng/m~3,为国外一些大城市冬季值的三倍,为国内一些大城市冬季污染值的二分之一。 相似文献
344.
345.
氯代芳烃催化氢转移脱氯的研究 总被引:12,自引:0,他引:12
本文以甲酸钠为氢源,对聚乙烯吡咯烷酮锚定的PdCl2催化氯代芳烃脱氯进行了研究,考察了反应条件对反应的影响,研究了脱氯的选择性。结果表明;该方法具有卓越的脱氯选择性,催化剂用量少,反应条件温和,操作简便。本文并对其脱氯反应机理进行了初步探讨。 相似文献
346.
本文阐述了北亚热带过渡区十个土壤剖面的成土条件和基本性质,应用模糊聚类对土壤的五项诊断指标进行了分析,并与发生分类和诊断分类相比较.在中国土壤系统分类中提出建立淋溶土纲和始成土纲的基础上,探讨了供试土壤的分类地位。其中01-04号剖面属于典型铁质湿润淋溶上亚类;05—07和09号剖面归为铁质粘磐半干润淋溶土亚类;08号剖面为典型半干润淡色始成上亚类,10号剖面为典型淡色滞水淋溶士亚类。 相似文献
347.
Concentrations and accumulation profiles of PCDDs/DFs and coplanar-PCBs (co-PCBs) in aquatic biota (e.g., plankton, shellfish, benthic invertebrate, and fish) and sediment from Tokyo Bay were examined to elucidate the relationship between bioaccumulation and trophic level in the food web as determined by the stable nitrogen isotope analysis. Bioaccumulation patterns of PCDDs/DFs and co-PCBs varied greatly among congeners. Accumulation patterns of PCDDs/DFs and co-PCBs are not solely explained by their physicochemical properties. Biota-sediment accumulation factors (BSAFs) for co-PCBs in biota from Tokyo Bay were significantly greater than those of PCDDs/DFs. Furthermore, the slopes of the plots of delta15N and BSAF values and water solubility of 2,3,7,8-substituted PCDDs/DFs and co-PCBs were highly correlated. The results of our study would provide the valuable information to understand the accumulation properties of PCDDs/DFs and co-PCBs that can be used as a scientific basis to determine the sediment quality criteria of PCDDs/DFs and co-PCBs. 相似文献
348.
Koh CH Kim GB Maruya KA Anderson JW Jones JM Kang SG 《Environmental pollution (Barking, Essex : 1987)》2001,111(3):437-445
Polycyclic aromatic hydrocarbons (PAHs) and induction of the P450 reporter gene system (RGS) for 6- and 16-h exposure periods were determined in organic extracts of Ulsan Bay (South Korea) sediments to assess the utility of this bioassay as a screening tool for PAH contamination. The sum of the concentrations of 23 individual PAHs in 30 sediment samples (sigma PAH) based on GC-MS analysis ranged from 0.05 to 6.1 micrograms/g dry wt. P450 RGS fold induction ranged from 4.0 to 320 micrograms/g based on benzo[a]pyrene toxic equivalents (BaPEq). P450 RGS BaPEq and the 'chemical BaPEq', defined as the sum of the products of individual PAH concentrations and pre-determined toxic equivalency factors, exhibited very strong positive correlations with sigma PAH (r2 > 0.90; P < 0.001). Fold induction did not increase (and in some cases decreased) after the optimal incubation period (6 h) for PAHs, indicating that other compounds known to induce the P450 RGS (e.g. chlorinated organics) were not present at levels effecting significant induction. This was supported by GC-ECD analysis where non-ortho and mono-ortho polychlorinated biphenyls (PCBs) known to be strong P450 RGS inducers were found to be at very low or non-detectable levels in samples with the highest P450 RGS responses. The profound difference in PAH profiles for the two most contaminated sites suggested that this assay is especially sensitive for selected PAHs with greater than four rings. Combined with previous results, the P450 RGS shows promise as a useful screening tool for predicting deleterious biological effects resulting from CYP1A1-inducing, sediment-associated chemicals, particularly high molecular weight PAHs. 相似文献
349.
This paper describes the use of photo-fenton process for color removal from textile wastewater stream. The wastewater sample to be treated was simulated by using colorless polyvinyl alcohol (PVA) and reactive dyestuff of R94H. As a result, the hydroxyl radical (HO*) oxidation can effectively remove color, but the chemical oxygen demand (COD) was removed in a slight degree. The color removal is markedly related with the amount of HO* formed. The optimum pH for both the OH* formation and color removal occurs at pH 3-5. Up to 96% of color can be removed within 30 min under the studied conditions. Due to the photoreduction of ferric ion into ferrous ion, color resurgence was observed after 30 min. The ferrous dosage and UV power affect the color removal in a positive way, however, the marginal benefit is less significant in the higher range of both. PVA as the major background COD of a textile wastewater stream inhibits the color removal insignificantly as its concentration increases. 相似文献
350.
So-Ryong Chae Hyeong-Seok Jeong Jae-Lim Lim Seok-Tae Kang Hang-Sik Shin Byeong-Cheon Paik Jong-Ho Youn 《Water environment research》2004,76(3):272-279
A four-stage biological nutrient removal (BNR) process was operated to investigate the effect of anaerobically fermented leachate of food waste (AFLFW) as an external carbon source on nutrient removal from domestic wastewater having a low carbon-to-nitrogen ratio. The BNR system that was supplemented with AFLFW showed a good performance at a sludge retention time (SRT) of 30 days, despite low temperature. With this wastewater, average removal efficiencies of soluble chemical oxygen demand (COD), total nitrogen (T-N), and total phosphorus (T-P) were 88 to 93%, 70 to 74%, and 63 to 68%, respectively. In this study, several kinds of poly-hydroxyalkanoates (PHAs) were observed in cells. These included 24% poly-3-hydroxybutyrate (PHB), 41% poly-3-hydroxyvalerate (PHV), 18% poly-3-hydroxyhexanoate (PHH), 10% poly-3-hydroxyoctanoate (PHO), 5% poly-3-hydroxydecanoate (PHD). and 2% poly-3-hydroxydodecanoate (PHDD), indicating that microorganisms could store various PHAs through the different metabolic pathways. However, breakdown of the enhanced biological phosphorus removal (EBPR) mechanism was observed when SRT increased from 30 to 50 days for the enhancement of nitrification. To study the effect of SRT on EBPR, a sequencing batch reactor (SBR) system that was supplied with glucose was operated at various SRTs of 5, 10, and 15 days. Nitrification and denitrification efficiencies increased as SRT increased. However, the content of intracellular materials such as PHAs, glycogen. and poly-P in cells decreased. From these results, it was concluded that SRT should be carefully controlled to increase nitrification activity and to maintain biological phosphorus removal activity in the BNR process. 相似文献