首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   3188篇
  免费   327篇
  国内免费   1040篇
安全科学   368篇
废物处理   142篇
环保管理   252篇
综合类   2057篇
基础理论   477篇
污染及防治   744篇
评价与监测   165篇
社会与环境   168篇
灾害及防治   182篇
  2024年   18篇
  2023年   85篇
  2022年   207篇
  2021年   208篇
  2020年   233篇
  2019年   156篇
  2018年   165篇
  2017年   184篇
  2016年   189篇
  2015年   242篇
  2014年   219篇
  2013年   330篇
  2012年   300篇
  2011年   307篇
  2010年   252篇
  2009年   197篇
  2008年   214篇
  2007年   188篇
  2006年   152篇
  2005年   138篇
  2004年   91篇
  2003年   79篇
  2002年   68篇
  2001年   46篇
  2000年   52篇
  1999年   47篇
  1998年   42篇
  1997年   35篇
  1996年   15篇
  1995年   27篇
  1994年   19篇
  1993年   14篇
  1992年   13篇
  1991年   7篇
  1990年   2篇
  1989年   4篇
  1988年   2篇
  1987年   2篇
  1986年   1篇
  1985年   1篇
  1983年   1篇
  1976年   1篇
  1975年   1篇
  1973年   1篇
排序方式: 共有4555条查询结果,搜索用时 15 毫秒
111.
Prevention and treatment of geological hazards is important for the sustainable development of human society. Surface geological hazards alone caused direct economic losses of ¥3.47 billion, with 768 deaths and 785 injuries in Guangdong Province, South China, from 1994 to 2005. The major factors causing geological hazards can be categorised into three types: geo-environmental, climatic-meteorological and human activity. Accompanied by rapid economic development and population growth, human activities can cause geological hazards that are as serious as those caused by natural factors. The authors propose some suggestions for prevention and treatment of geological hazards to achieve sustainable development on the Chinese coast.  相似文献   
112.
The dissipation routes of chlorpyrifos spiked in an Udic Ferrisol at the dosage of 400 ng g?1, which represents a residual level after an agricultural application, were studied in a laboratory, using the natural soil under three moisture regimes, sterilised, and organic matter-free soils in the dark at 20°C. The obtained results showed that higher soil moisture caused faster dissipation, and the abiotic and biotic contributions to the total dissipated amount of the applied chlorpyrifos in the soil accounted for 77.3–85.2% and 14.7–22.7%, respectively. In the sterilised soil, the contribution of organic matter to chlorpyrifos dissipation was noticed to account for 95% in the earlier two weeks, and was nearly equal to that of soil minerals two weeks after the incubation.  相似文献   
113.
采用UV+TiO2光催化氧化法处理印染废水生化出水,考察了反应时间、TiO2投加量以及初始pH对反应的影响,结果表明,TiO2投加量800 mg·L-1,反应时间8 h,反应pH为原水pH(6.5~8.0),在此操作条件下,ADMI7.6、DOC和COD的去除率分别为86%、20%及46%;选取两组反应条件,对其进出水采用XAD-8/XAD-4树脂联用技术,分析疏水酸、非酸疏水物质、弱疏水物质及亲水物质4类有机物的去除情况,结果表明,UV+TiO2光催化氧化处理工艺都能够长期有效去除印染废水生化出水中的弱疏水物质、疏水物质和非酸疏水物质引起的色度.  相似文献   
114.
采用还原铁粉处理印染废水生化出水,以ADMI7.6作为主要测试指标,考察铁粉投加量、反应时间以及进水pH对出水水质的影响,并研究在此过程中铁粉还原作用和混凝絮凝作用对整体效果的贡献比.结果表明,条件1:铁粉投加量=1.0 g.L-1,反应时间150 min,进水pH 2;条件2:铁粉投加量1.0 g.L-1,反应时间150 min,进水pH 3.条件1时,ADMI7.6去除率达到80%,但铁泥量大,酸碱消耗大,在此反应条件下,铁粉还原去除40%,混凝絮凝去除60%;条件2时,ADMI7.6去除率达到50%左右,产铁泥量小,经济合理;在此反应条件下,铁粉还原去除55%—63%左右,混凝絮凝去除37%—45%左右.经XAD8/XAD4树脂联用,分析疏水酸、非酸疏水物质、弱疏水物质及亲水物质4类有机物的去除情况表明,条件1时,能够高效去除非酸疏水物质,去除率为95%,对于疏水酸以及弱疏水物质也有一定的去除效果;条件2时,对4类有机物去除均有一定作用,但对于非酸疏水物质以及疏水酸的去除效果要略差于条件1.  相似文献   
115.
为研究沉积物中十溴联苯醚(BDE-209)的生物有效性,将淡水生态系统中常见的底栖动物中华圆田螺(Cipangopaludina cahayensis)暴露于商品DE-83(主要包含92%的BDE-209、6%的BDE-206、1.5%的BDE-207和0.5%的BDE-208)染毒的沉积物,进行60 d养殖实验。根据暴露期间中华圆田螺体内PBDEs含量与同系物组成的变化,探讨了田螺对DE-83的富集动力学、积累常数以及可能发生的生物转化。实验结果显示,DE-83主要同系物均能够被中华圆田螺积累,但是生物有效性非常低,BDE-209、BDE-207和BDE-206的吸收速率常数(ks)为0.029~0.042 d-1,BDE-207 > BDE-206 > BDE-209。依据动力学参数推算的生物-沉积物积累因子(BSAF)非常低,分别为0.05(BDE-209)和0.02(BDE-206和BDE-207)。暴露20 d后,中华圆田螺体内有低溴代同系物检出,其含量随暴露时间延长而增加,说明BDE-209在中华圆田螺体内发生了生物转化。  相似文献   
116.
以壳聚糖(CTS)、聚乙烯吡咯烷酮(PVP)、活性炭(C)为基材,Cu(Ⅱ)为印迹离子,制备了CTS/PVP共混印迹球[Cu(Ⅱ)-IICP]和CTS/PVP/C共混印迹球[Cu(Ⅱ)-IICPC].以Cu(Ⅱ)的吸附量作为评价指标,对两种共混印迹球的制备条件进行了优化.研究结果表明,当CTS/PVP的质量比为6∶4,活性炭质量分数为0.6%,Cu(Ⅱ)模板剂质量分数为0.05%,所制备的两种共混印迹球吸附性能较佳,且对Cu(Ⅱ)有较好的选择吸附性.物理吸附分析结果表明,与未印迹相比印迹材料的比表面积明显增大.FTIR谱图分析,Cu(Ⅱ)模板主要与CTS和PVP中的—NH2和—OH发生了配位作用.XRD谱图分析结果表明,CTS与PVP、C、Cu(Ⅱ)之间发生了相互作用,改变了CTS原有的晶体结构,使其结晶度降低.  相似文献   
117.
作物根际沉积碳输入而引起的根际激发效应,对农田土壤碳排放通量和碳平衡起到关键的调控作用.在稻田生态系统中,由于频繁的干湿交替,土壤CO2 和CH4 排放以及根际激发效应明显有别于其他自然生态系统.因此,明确稻田生态系统干湿交替过程中水稻根际激发效应的方向与强度,对于减缓稻田温室气体排放具有重要意义.本研究采用13C-C...  相似文献   
118.
The junction area of Yunnan, Guizhou, and Sichuan provinces is the heaviest coal-burning endemic fluorosis zones in China. To better understand the pathogenicity of endemic fluorosis in this area, 87 coal samples from the late Permian outcrop or semi-outcrop coal seams were collected in eight counties of the junction area of Yunnan, Guizhou, and Sichuan provinces. The total fluorine and sulfate content, etc. in the coal was determined using combustion-hydrolysis/fluoride-ion-selective electrode method and ion chromatography, respectively. The results show that the total fluorine concentrations in the samples ranged from 44 to 382 µg g?1, with an average of 127 µg g?1. The average pH of the coals is 5.03 (1.86–8.62), and the sulfate content varied from 249 to 64,706 µg g?1 (average 7127 µg g?1). In addition, the coals were medium- and high-sulfur coals, with sulfur mass fraction ranging from 0.08 to 13.41%. By heating the outcrop coals, HF release from the coal was verified quantitatively without exception, while simulated combustion directly confirmed the release of sulfuric acid (H2SO4). The acid in coal may be in the form of acidic sulfate (\({\text{HSO}}_{4}^{ - }\)/H2SO4) because of a positive relationship between pH and \(p\left( {{\text{SO}}_{4}^{2 - } } \right)\) in the acidic coal. The possible reaction mechanism would be that a chemical reaction between the acid (H2SO4 or \({\text{HSO}}_{4}^{ - }\)) and fluorine in the coal occurred, thereby producing hydrogen fluoride (HF), which would be the chemical form of fluorine released from coal under relatively mild conditions. The unique chemical and physical property of HF may bring new insight into the pathogenic mechanism of coal-burning endemic fluorosis. The phenomenon of coal-burning fluorosis is not limited to the study area, but is common in southwest China and elsewhere. Further investigation is needed to determine whether other endemic fluorosis areas are affected by this phenomenon.  相似文献   
119.
The feasibility of using Phragmites australis-JS45 system in removing nitrobenzene from sediments was conducted. However, it was observed that nitrobenzene degraded rapidly and was removed completely within 20 days in native sediments, raising the possibility that indigenous microorganisms may play important roles in nitrobenzene degradation. Consequently, this study aimed to verify this possibility and investigate the potential nitrobenzene degraders among indigenous microorganisms in sediments. The abundance of inoculated strain JS45 and indigenous bacteria in sediments was quantified using real-time polymerase chain reaction. Furthermore, community structure of the indigenous bacteria was analyzed through high throughput sequencing based on Illumina MiSeq platform. The results showed that indigenous bacteria in native sediments were abundant, approximately 1014 CFU/g dry weight, which is about six orders of magnitude higher than that in fertile soils. In addition, the levels of indigenous Proteobacteria (Acinetobacter, Comamonadaceae_ uncultured, Pseudomonas, and Thauera) and Firmicutes (Clostridium, Sporacetigenium, Fusibacter, Youngiibacter, and Trichococcus) increased significantly during nitrobenzene removal. Their quantities sharply decreased after nitrobenzene was removed completely, except for Pseudomonas and Thauera. Based on the results, it can be concluded that indigenous microorganisms including Proteobacteria and Firmicutes can have great potential for removing nitrobenzene from sediments. Although P. australis - JS45 system was set up in an attempt to eliminate nitrobenzene from sediments, and the system did not meet the expectation. The findings still provide valuable information on enhancing nitrobenzene removal by optimizing the sediment conditions for better growth of indigenous Proteobacteria and Firmicutes.
  相似文献   
120.
To explore the role of endophytic fungi in the decomposition of litter, the endophytic fungi Penicillium sp. strain CG2 (A), Fusarium flavum strain AY13 (B), and Talaromyces strain AJ14 (C) of Cunninghamia lanceolata were added to experimental pots in different forms (mycelium, sterilized fermentation broth, single fungus, and mixed fungi), and a control treatment (CK) was set up (no fungi added). At 10, 30, 60, 90, and 120 days after litter decomposition, a study on the decomposition dynamics of C. lanceolata litter under different treatments was performed. The results showed that the rate of leaf mass loss was the highest in the sterilized fermentation broth treatment A after 120 days, and that there was a significant difference (P < 0.05) between the mycelium treatment AC and the control treatment after 60 days (23.97% higher than the control group). On day 60, the litter carbon content from the mycelium treatment A was significantly different from that of the control (P < 0.05), showing a 16.74% lower value, whereas the litter carbon content of the mycelium treatment B was 21.13% lower than that of the control after 90 days. The nitrogen content of the litters of most mycelium and sterilized fermentation broth treatments was increased compared to that of the control group; there was significant difference (P < 0.05) between the sterilized fermentation broth treatment A and the control (P < 0.05), with a 17.05% higher value than that of the control. Similar to nitrogen, the litter phosphorus content also increased; there was a statistically significant difference between the mycelium treatment A and the control group, with treatment A showing a 46.67% higher value than the control group. The potassium content was 28% lower than that of the control group under the sterilized fermentation broth treatment C, a result that was significantly different from that of the control group (P < 0.05). After treatment for 90 days, the ratio of carbon to nitrogen was the lowest under the treatments with the mycelium A and the mycelium B, with values 25.54% and 25.11% lower than that of the control group, respectively, and a statistically significant difference from that of the control group (P < 0.05). The ratio of carbon to phosphorus was the lowest under the treatment with mycelium A after 60 days, and the result was significantly different from that of the control (P < 0.05), with a 43.05% lower value than the control. Thus, the three endophytic fungi had different effects on the mass loss rate and nutrient content of the litter. The Penicillium sp. strain CG2 (A) had statistically significant effects on the mass loss and nutrient content of leaf litter, which was within the range of fungi fertilizer reference values for the breeding of C. lanceolata. © 2018 Science Press. All rights reserved.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号