CF2ClBr的火花等离子体降解

对用等离子体降解ＣＦ２ＣｌＢｒ进行了初步研究,产物主要用气相色谱分析。在ＣＦ２ＣｌＢｒ的强为２．６７×１０＾３Ｐａ时获得了９０％左右的解离率,主要降解产为ＣＦ３Ｃｌ,Ｂｒ２,ＣＦ４,ＣＦ２Ｃｌ２。另外,从热力学上对产物进行了解释,得出了产总是朝使体系更稳定的方向生成的结论。     

四川甘洛自勒沟泥石流运动特征及预测防治效果研究∗

甘洛县位于四川省西南部,所处区域高山峡谷地貌特征显著,地质构造运动强烈且为强震影响区,泥石流灾害频发。甘洛县自勒沟分别于 1987 年和 2019 年发生两次特大泥石流,大量泥石流堆积物顺沟而下,堵塞 245 国道和尼日河,并对沟口凉红水电站及尼日河河岸成昆铁路造成严重威胁。对此,基于现场调查资料和无人机航拍数据,利用 Massflow 数值模拟方法,对该沟泥石流运动特征进行分析以及治理措施防治效果进行预测。结果表明：若沟内现有物源再次爆发泥石流,最大泥深将达到 11.9 m,流速达到 11.7 m/s,流动强度达到 123.37 m² /s,堆积物一次冲出量为 11.18×10⁴ m³ ,堆积扇面积为 6.925×10⁴ m² 。根据预测结果,采用合理的工程措施进行治理后,最大泥深下降为 8.5 m,流速下降为 9.1 m/s,而流动强度可下降 52.7%,为 58.32 m² /s,堆积扇面积和一次冲出量分别为 1.406×10⁴ m² 和 2.75×10⁴ m³ ,分别下降 80% 和 75%。这表明,采用固源为主,拦挡、排导为辅的措施对自勒沟泥石流灾害进行治理,可取得较好治理效果,对保护沟口建筑及成昆铁路安全运营有重要意义。     

基于Newmark模型的地震诱发滑坡易发性分析方法的研究

以芦山地震诱发滑坡数据为研究对象,开展Newmark模型在区域性地震诱发滑坡空间易发性分析中的应用研究.首先采用网格形式进行数据处理,完成地形坡度、地震参数等数据的统一化,重点利用地层岩性数据对Newmark模型内参数开展区域定量化赋值,在此基础上根据Newmark模型及地震参数相关公式分别计算了安全系数、临界加速度和...     

离子色谱法测定废气中的甲酸和乙酸

阐述了离子色谱法测定废气中甲酸、乙酸含量的方法和步聚。甲酸、乙酸检出限分别为0.02mg/L和0.05mg/L,方法平均回收率分别为92%和95%。本方法分析速度快,所需样品量少,且无需复杂的前处理。     

文丘里喷嘴改进金锥滤筒脉喷清灰性能的数值模拟

针对除尘滤筒脉冲反吹清灰均匀性差、强度不足的缺点,构建了脉冲喷吹滤筒除尘器CFD数值模型,考察了文丘里喷嘴和金锥滤筒组合条件下的清灰性能.结果 表明,无论是文丘里喷嘴还是金锥滤筒的使用或二者组合使用,滤筒内喷吹压力均为底部大而上部小;文丘里喷嘴和金锥滤筒可单独或组合式优化喷吹性能;在喷吹高度为150～550 mm时,喷...     

淮北市土地集约利用研究

随着"中部崛起"战略的实施,淮北市必然加快发展的步伐,占用土地是不可避免的事实,土地供需矛盾更加突出.在对淮北市土地集约水平和土地集约利用潜力及影响土地集约利用因素分析的基础上,提出了集约用地的对策措施.通过这些对策措施,以期实现淮北市土地资源的合理有效配置,提高土地利用效率,使有限的土地资源供给能够满足经济社会持续发展的需要.     

清罐油泥资源化综合利用技术应用

采用清罐含油污泥资源化综合利用技术,处理后的含油污泥经检测其灰渣重金属含量均小于我国GB 15618-1995《土壤环境质量标准》和GB 4284-84《农用污泥中污染物控制标准》,灰渣浸出液达到GB5085.3-2007《危险废物鉴别标准浸出毒性鉴别》二级标准、燃烧后产生的废气和烟尘达到GB 13271-2001《锅炉大气污染物排放标准》。解决了清罐油泥处理难的问题,同时符合国家推行清洁生产,大力发展循环经济的要求,使生产过程中的废物减量化、资源化、无害化,减小了油泥排污费用,具有显著环境效益和社会效益。     

鱼粉行业恶臭污染物产生与成分分析探讨

针对目前鱼粉行业废气污染严重、排放量大、成分复杂的特性和测定难度较大、监测准确度较低等实际情况,采用实际监测数据,利用傅立叶红外光谱分析仪,有针对性地对鱼粉生产过程中及采取治理措施后恶臭污染物的排放进行了现场连续监测,得到了全面的监测数据。     

Comparison of adsorption models in reservoir simulation of enhanced coalbed methane recovery and CO2 sequestration in coal

Coalbed methane is an important resource of energy. Meanwhile CO₂ sequestration in coal is a potential management option for greenhouse gas emissions. An attractive aspect to this process is that CO₂ is adsorbed to the coal, reducing the risk of CO₂ migration to the surface. Another aspect to this is that the injected CO₂ could displace adsorbed methane leading to enhanced coalbed methane recovery. Therefore, in order to understand gas migration within the reservoir, mixed-gas adsorption models are required. Moreover, coal reservoir permeability will be significantly affected by adsorption-induced coal swelling during CO₂ injection. Coal swelling is directly related to reservoir pressure and gas content which is calculated by adsorption models in reservoir simulation. Various models have been studied to describe the pure- and mixed-gas adsorption on coal. Nevertheless, only the Langmuir and Extended Langmuir models are usually applied in coal reservoir simulations. This paper presents simulation work using several approaches to representing gas adsorption, implemented into the coal seam gas reservoir simulator SIMED II. The adsorption models are the Extended Langmuir model (ELM), the Ideal Adsorbed Solution (IAS) model and the Two-Dimensional Equation of State (2D EOS). The simulations based on one Australian and one American coal sample demonstrated that (1) the Ideal Adsorbed Solution model, in conjunction with Langmuir model as single-component isotherm, shows similar simulation results as the ELM for both coals, with the IAS model representing the experimental adsorption data more accurately than the ELM for one coal and identically with the ELM for the other coal; (2) simulation results using the 2D EOS, however, are significantly different to the ELM or IAS model for both coal samples. The magnitude of the difference is also dependent on coal swelling and the well operating conditions, such as injection pressure.     

Cu2+-Mn2+-H2O2体系催化氧化降解罗丹明B

研究了Cu2＋-Mn2＋-H2O2体系催化氧化降解染料罗丹明B的效果。实验结果表明,Cu2＋-Mn2＋-H2O2体系的罗丹明B降解率比H2O2体系、Mn2＋-H2O2体系和Cu2＋-H2O2体系有显著提高,反应120rain后罗丹明B降解率接近100％。对于Cu2＋-Mn2＋-H2O2体系,最佳罗丹明B降解条件：溶液pH为5,反应温度为45℃,质量浓度为10mg／L的罗丹明B溶液体积100mL,浓度为0．01mol／L的硫酸铜溶液加入量5．0mL,浓度为0．01moVL的硫酸锰溶液加入量3．0mL,体积分数为30％的H2O2溶液加入量1．5mL。在此条件下罗丹明B降解的反应速率常数最大,为0．04228min-1,其拟合相关系数为0．99912。罗丹明B降解符合一级动力学模型。