沸石滤料曝气生物滤池启动性能研究

沸石滤料曝气生物滤池 (ZBAF)对氨氮的去除包括生物硝化和离子交换两种作用。中试装置启动试验表明 ,初期对氨氮的去除以离子交换作用为主 ,末期以硝化作用为主 ,不能以氨氮总去除率达到稳定作为启动过程结束的标志 ,而应以氨氮硝化去除率达到稳定作为标志。沿程试验表明 ,硝化细菌对沸石的“生物再生功能” ,实质是已被沸石交换的氨氮被水中浓度较大的其他阳离子交换下来后 ,被硝化菌所利用的现象 ;沸石表面有生物膜时 ,仍具有交换氨氮能力     

The effect of low molecular weight chelators on iron chelation and free radical generation as studied by ESR measurement

The purpose of this work was to improve our current knowledge of the non-enzymatic mechanisms involved in brown rot fungal decay of wood, but also to improve our understanding of chelator-mediated reactions that may occur in other biological systems where low pH conditions may prevail. Several key steps (iron chelation and reduction) during early non-enzymatic wood decay processes have been studied by using electron spin resonance (ESR). It has been proposed that low molecular weight chelators as well as Fenton reagents are involved in brown rot decay, at least in early non-enzymatic stages. In this work, the binding between a catecholate model chelator and ferric iron was studied by ESR spectroscopy. The effects of the model chelator, Fenton reagents, as well as the reaction conditions on free radical generation were also studied using ESR spin-trapping techniques. The results indicate: (1) The relative quantity of the chelator-iron complex can be determined by measurement of the intensities of the characteristic g = 4.3 ESR signal. (2) The effects of the chelator:iron ratio, the pH, and other reaction parameters on the hydroxyl radical generation in a Fenton type system can be determined using ESR spin-trapping techniques. (3) Data support the hypothesis that superoxide radicals are involved in chelator-mediated Fenton processes.     

焦化厂生化出水电解脱色工艺及其机理的初步研究

针对焦化废水经萃取（蒸氨）脱酚和生化处理后的出水水质的特点，研究用铝板作为电极电解该废水的脱色效果，研究了废水pH、电解槽电压、时间等因素对其色度去除率的影响。结果表明，最佳工艺参数为：pH=4、电解槽电压=10V、时间=30min，此时色度去除率可达93．6％，COD的去除率也可以达到61．78％。采用GC—MS分析了电解前后废水中的有机物成分，探讨了形成高色度水质的原因、有机物的去除及脱色机理。     

脱硫石膏农业利用研究进展与展望

概述火电厂脱硫石膏定义、生产过程和性质.简述了脱离石膏的工业利用,详述了脱离石膏对酸性和碱性土壤改良的现状和机理,并展望了脱硫石膏促进滩涂土植被演替的前景.     

黄原酯棉回收废弃电子电路板中金的研究

废弃电子电路板经王水溶解后，在盐酸介质中，用自制的黄原酯棉吸附。用6mol/L HCl洗涤杂质后，5％Na2SO3洗脱Au，控制溶液的流速为1mL/min。洗脱液浓缩后，再用20％ Na2SO3沉淀得到99.59%Au。     

扁刺栲-华木荷群系次生林林下物种多样性分析

对四川中亚热带扁刺栲(Castanopsis platyacantha)—华木荷(Schima sinensis)群系人工杉木林、水杉林、日本落叶松林和天然次生林林下植物进行了群落调查和物种多样性分析。结果表明：(1)杉木林、水杉林、日本落叶松林和次生扁刺栲—华木荷林(20a)的物种丰富度分别为62，59，53和32；Simpson多样性指数分别为7．95，7．08，9．24和5．38；Shannon—Wiener多样性指数分别为3．67，3．3l，3．64和2．46。(2)人工林林下植物群落之间的群落系数和相似度系数分别为0．45～0．60和0．62～0．82；人工林林下植物群落与次生阔叶林林下植物群落之间的群落系数和相似度系数分别为0．19～0．53和0．55～0．77。(3)人工林林下物种多样性比次生林高的主要原因可能是风倒木和站干死木导致人工林乔木层郁闭度减小，增加了林下的光照，从而改蛮了林下的微生境。表6参19。     

Ecological compensation mechanism for urban green land and its application in Shanghai, China

Urban green land compensation plays an important role in county development, ecological environment management and many other fields. The concept, methods and principles of urban green land are introduced in this paper. According to the pay fee method, the value and ecological function of various types of urban green land were analyzed. The cost-benefit analysis method (CBAM) was used to estimate different external diseconomy benefits caused by green land loss. The authors applied CBAM to estimate such benefits in the case of Shanghai, China, and calculated the actual compensation value for green land. Results indicated that in 2002, the compensation value for the green land of Shanghai was RMB 8.58 × 10⁵ Yuan/hm².     

硫化氢气体快速检测方法研究

研究了快速监测硫化氢气体的新方法——硫化氢被动式检气管方法。该法是基于气体分子扩散(Fick)定律和化学吸收原理,将检气管内的海棉载体涂渍上对硫化氢有特效的显色剂(缓冲液G和醋酸铅)。测定时,硫化氢通过检气管端口扩散进入管内,在经过载体时,与载体上的显色剂发生反应,从而产生明显的颜色变化(浅黄色变成棕黑色)。检气管显色长度的平方与硫化氢质量浓度及采样时间的乘积在50~1500mg·m-3范围内成线性关系,从而快速监测环境中硫化氢的时间加权平均质量浓度。该检气管集采样与分析为一体,可快速测定硫化氢气体的质量浓度。与传统的采样分析方法比较,该检气管结构简单,操作方便,不受被测环境的空间大小、有无电源等影响;携带方便,利于外出测定和大面积布点测定。经过应用实验表明,该检气管具有较高的灵敏度,达到设计要求。     

黑柱石和水之间氢同位素平衡分馏的实验研究

在750-250℃温度范围内,对黑柱石-水之间的氢同位素平衡分馏进行了实验研究。研究中改进了氢同位素交换实验方法,从而保证了精度。研究结果表明,750-550℃温度范围内,黑柱石一水的分馏系数10~3lnα°_(黑柱石-水)=-30.51 10~6/T~2-59.86,550-350℃温度范围内,10~3lnα°_(黑柱石-水)与温度1/T~2间无依赖关系,其值为-105.0±0.7,.250℃时,交换率太低。文中讨论了黑柱石-水之间氢同位素分馏系数与温度、矿物晶体结构、矿物化学组成的关系及其地质意义。     

提高柴油质量减少汽车排气污染

柴油机车应用于道路运输具有许多优点，但环境保护要求减少排气污染、颗粒排放污染至关重要，为此，强化柴油燃料规格是其主要的驱动力。本文介绍了美国，西欧和亚太地区柴油质量现状和趋势，分析了我国柴油燃料质量及其改进意见。