全文获取类型
收费全文 | 1919篇 |
免费 | 220篇 |
国内免费 | 583篇 |
专业分类
安全科学 | 283篇 |
废物处理 | 66篇 |
环保管理 | 165篇 |
综合类 | 1275篇 |
基础理论 | 250篇 |
污染及防治 | 319篇 |
评价与监测 | 117篇 |
社会与环境 | 94篇 |
灾害及防治 | 153篇 |
出版年
2024年 | 16篇 |
2023年 | 34篇 |
2022年 | 111篇 |
2021年 | 150篇 |
2020年 | 109篇 |
2019年 | 92篇 |
2018年 | 83篇 |
2017年 | 98篇 |
2016年 | 101篇 |
2015年 | 144篇 |
2014年 | 140篇 |
2013年 | 154篇 |
2012年 | 177篇 |
2011年 | 173篇 |
2010年 | 154篇 |
2009年 | 131篇 |
2008年 | 156篇 |
2007年 | 132篇 |
2006年 | 125篇 |
2005年 | 94篇 |
2004年 | 59篇 |
2003年 | 47篇 |
2002年 | 41篇 |
2001年 | 49篇 |
2000年 | 31篇 |
1999年 | 28篇 |
1998年 | 18篇 |
1997年 | 18篇 |
1996年 | 13篇 |
1995年 | 8篇 |
1994年 | 9篇 |
1993年 | 7篇 |
1992年 | 6篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有2722条查询结果,搜索用时 359 毫秒
91.
根据一真实火灾调查报告设定了真实大空间建筑物开口情况和材料燃烧性能参数,建立了FDS(Fire Dy-namics Simulator)物理模型。计算了火灾释热速率以及着火大空间烟气的温度场和一氧化碳浓度场的变化。研究结果表明:火灾短时间发生轰燃,随后发生回燃。轰燃是导致大量人员死亡的1个重要原因;回燃没有引起各点烟气的温度和一氧化碳浓度显著的提高,但对各点烟气的温度和一氧化碳浓度的保持起到较大作用。 相似文献
92.
93.
Ou LT Thomas JE Allen LH Vu JC Dickson DW 《Journal of environmental science and health. Part. B》2008,43(5):376-381
The purpose of this study was to conduct a field study at a Florida field site on surface emissions and subsurface distribution of cis-and trans-1,3-dichloropropene (1,3-D) and chloropicrin (CP) in raised beds injected with Telone C35 with four replications. A total of 16 beds were applied with Telone C35 by chisel injection and covered with four different plastic films, 4 beds for each film. Each bed was installed with five 20-cm long soil pore air probes and a surface air collection pan at arbitrarily locations along the length of each bed for sampling soil pore air and surface air, respectively, for analysis of the three biologically active compounds, cis- and trans-1,3-D and CP. We found that average concentrations of the three compounds at 20-cm depth among the beds covered with four different plastic films generally were not statistically different. Among the four beds covered with the same plastic film, average concentrations of the three compounds were statistically different only in the four metallic PE covered beds at 5 and 24 hours after injection. Volatilization rates of the three compounds among the beds covered with four different plastic films, with the exception of CP at 48 hours after injection, were not statistically different. It appeared that initial upward diffusion and volatilization flux were influenced by solar radiation. Initial subsurface concentrations of the three compounds and volatilization flux, especially cis-1,3-D, were greater in the beds on the east side of the field than that in the beds on the west side of the field. Whether or not difference in initial subsurface concentrations of the compounds between east side beds and west side beds may influence fumigant efficacy remains to be determined. 相似文献
94.
Co3O4/介孔分子筛催化剂对苯催化完全氧化的研究 总被引:2,自引:0,他引:2
分别以介孔分子筛MCM-41、MCM-48、SBA-15为载体,采用等体积浸渍法制备了氧化钴/介孔分子筛催化剂,利用N2吸附、X射线衍射、程序升温还原等技术对催化剂进行了表征,考察了Co3O4的负载量及载体的孔结构对催化剂完全催化氧化苯的性能的影响。结果表明,Co3O4的负载量为20%时,催化剂的催化活性最好;载体的孔径和催化剂的可还原性能是影响催化活性的主要因素,催化剂活性顺序为Co3O4 /SBA-15> Co3O4 /MCM41> Co3O4 /MCM-48。 相似文献
95.
96.
地理空间信息网格安全问题研究 总被引:1,自引:0,他引:1
计算机网络足地理空间信息网格的载体,二者之间有着密切的联系,其关联性主要表现在互连互通、基于协议、交互接口和虚拟组织几个方面.计算机网络遇到的安全威胁,地理空间信息网格也同样会遇到.此外,地理空间信息网格还要面对自身特征带来的诸如攻击核心设施、导致整体瘫痪,或破坏局部计算等各种安全威胁.针对这些问题,基于用户、通信网络、应用程序和网格资源四个环节,研究设计了地理空间信息网格安全体系结构,并论述了各模块的功能和相互之间的关系,以及整体协同运行程序. 相似文献
97.
Yao Z Wang Q He K Huo H Ma Y Zhang Q 《Journal of the Air & Waste Management Association (1995)》2007,57(11):1379-1386
On-board emission measurements were performed on 49 light-duty gasoline vehicles in seven cities of China. Vehicle-specific power mode distribution and emission characteristics were analyzed based on the data collected. The results of our study show that there were significant differences in different types of roads. The emission factors and fuel consumption rates on arterial roads and residential roads were approximately 1.4-2 times those on freeways. The carbon monoxide, hydrocarbon, and nitrogen oxides emission factors of Euro II vehicles were on average 86.2, 88.2, and 64.5% lower than those of carburetor vehicles, respectively. The new vehicle emission standards implemented in China had played an important role in reducing individual vehicle emissions. More comprehensive measures need to be considered to reduce the total amount of emissions from vehicles. 相似文献
98.
为全面了解北京城市湿地的现状及近年来的动态变化情况,利用高分辨率卫星遥感数据,综合运用GIS技术与景观生态学方法,定量分析了北京市6环内的湿地空间格局。结果表明,北京6环内城市湿地以河流湿地和湖库湿地为主;2016—2018年间湿地面积有所下降,2年间减少了126.58 hm2,主要转化为草地,少量转化为建设用地和林地;由于城市外围的开发建设强度较大,5-6环湿地被侵占面积相对较大,而4环内湿地面积的波动较小;2016—2018年,北京城市湿地的斑块密度增加,平均斑块面积有所减小,表明湿地斑块随时间变化呈破碎化的趋势,且从城市中心向城市边缘,湿地斑块的破碎化程度增强。 相似文献
99.
通过水热合成法和液相沉积法制备g-C_3N_4/C@Bi_2MoO_6复合光催化剂,并采用X射线衍射、扫描电子显微镜、氮气吸脱附、紫外-可见漫反射等技术对其进行表征。研究了可见光下g-C_3N_4/C@Bi_2MoO_6催化降解罗丹明B(Rh B)的影响因素,并对其光催化反应机理进行初步探讨。实验结果表明:g-C_3N_4掺杂量为60%(w)时g-C_3N_4/C@Bi_2MoO_6的光催化活性最高;在60%g-C_3N_4/C@Bi_2MoO_6的投加量为1.00 g/L、初始Rh B质量浓度为2.50 mg/L、可见光照射150 min的条件下,Rh B的降解率达到97.90%;在g-C_3N_4/C@Bi_2MoO_6光催化降解体系中,h~+和·O_2~-是主要活性物种。 相似文献
100.
Chang Liu Jianlin Luo Xiaona Li Qiang Gao Jianzhang Li 《Journal of Polymers and the Environment》2018,26(1):158-165
The effects of three compounded curing agents on the properties and performance of the urea-formaldehyde (UF) resin were investigated in this study. The compounded curing agents were prepared by mixing ammonium chloride with hexamethylenetetramine, citric acid, and oxalic acid respectively at a ratio of 1:1, named N-H, N–CA, and N–OA, respectively. The curing process, crystallinity, and physical properties were measured, and the three-ply plywood was fabricated to measure its prepress strength, wet shear strength, and formaldehyde emission. Results showed that the compounded curing agents N–CA and N–OA enhanced the initial viscosity, crosslinking density and thermal stability of UF resin. Additionally, the prepress strength of the plywood bonded by UF resin with N–CA and N–OA increased by 82 and 111% respectively compared to the UF resin with NH4Cl, and the wet shear strength increased by 14 and 16%, the formaldehyde emission decreased by 19 and 42% respectively. However, owing to the short pot-life of these curing agent limited their storage time, the curing agents N–CA and N–OA should be applied to fabricate plywood in winter for obtaining a better bond strength and a lower formaldehyde emission. While the UF resin with N–HT showed a suitable pot-life, so it could be applied to fabricate plywood in summer for long time storage and avoiding procuring problem. 相似文献