浅谈龙江县人为水土流失的防治对策

本文分析了龙江县水土流失的成因及危害,并提出了机关的防治对策,对今后的水土保养、合理开发有一定的借鉴作用.     

引水工程前后西湖流场的数值模拟研究

采用Delft 3D水动力学计算模型,对西湖西进工程前后的流场进行了模拟,计算结果与实测资料较为吻合,模型真实可靠.各种工况下的流场模拟结果表明在不考虑风场的情况下,各进出水口的流量和位置决定了西湖的流场结构,而流场结构决定了水体的推移扩散规律.总体上,南湖水体推移扩散效果最好,西里湖、外湖和岳湖次之,北里湖最差,基本不能被置换.西湖水体的置换效果主要取决于可被置换区域的面积和引水量,而可被置换区域大小主要取决于流场结构.因此,在引水量不变的前提下,优化西湖水体置换效果的根本途径就是调整进出水口位置和流量大小,以改变流场结构.     

风景区中影视拍摄的环境规制研究

影视剧组在风景区的拍摄活动,往往造成风景区的环境破坏。文章首先对风景区中影视拍摄所造成的破坏类型进行分析,然后从相关责任主体方面探讨造成该问题的原因,最后根据环境规制发展的趋势,提出风景区中影视拍摄的规制对策：政府部门的强制性规制和影视剧组的自愿性规制两者相结合。     

硝化抑制剂的加量对生化需氧量值影响的探讨

BOD作为衡量水体受有机污染程度的重要指标,其反映的可生化降解性是其他参数无法替代的。在5日生化培养时间内,硝化作用的耗氧量取决于是否存在足够数量的能进行此种氧化作用的微生物,许多二级生化处理的出水和受污染较久的水体中,往往含有大量硝化微生物,因此测定这种水样时应抑制其硝化反应。通过对特定水体硝化抑制剂添加与否及加量多少对BOD5测定结果的影响,分析并探讨抑制特定水体硝化过程的最佳条件。在严格质量控制的基础上,对特定行业和环境水体的实际样品进行硝化抑制剂添加与否和加量及时间培养曲线等对比实验,通过所得到的比对数据以化学需氧量值与BOD5之间关系为基准,对硝化抑制剂的加量进行了探究。     

Enantioselective separation and zebrafish embryo toxicity of insecticide beta-cypermethrin

Enantioselectivity of chiral pollutants is receiving growing concern due to the difference in toxicology and environment fate between enantiomers.In this study,enantiomers of insecticide beta-cypermethrin (beta-CP) were separated on selected chiral column by HPLC,and the toxicity of enantiomers was evaluated using the zebrafish embryo-larval assays.The enantiomers of beta-CP were baseline separated on Chiralcel OD and Chiralpak AD columns and detected by circular dichroism (CD) at 236 nm.Better separation could be achieved at lower temperature (e.g.,20°C) and with lower levels of polar modifiers.Pure enantiomers were obtained on Chiralcel OD.The CD spectra of enantiomers were recorded.By comparing the elution order with a previous similar study,the absolute configuration of beta-CP enantiomers was determined.The individual enantiomers were used in zebrafish embryo test,and the results showed that beta-CP enantioselectively induced yolk sac edema,pericardial edema and crooked body.The 1R-cis-αS and 1R-trans-αS enantiomers showed strong developmental toxicities at concentration of 0.1 mg/L,while the 1S-cis-αR and 1S-trans-αR induced no malformations at higher concentration (e.g.,0.3 mg/L).The results suggest that the enantioselective toxicological effects of beta-CP should be considered when evaluating its ecotoxicological effects.     

鼎鑫煤化有限公司焦化废水处理工程实践

介绍了河北涉县鼎鑫煤化有限公司的焦化废水处理工程,详细论述了该工程所采用的"隔油+气浮+生化处理+脱色混凝"处理工艺,分析了DO、pH及温度等因素对运行效果的影响,并对该工程运行后的综合效益进行了分析.运行结果显示:系统出水的COD、SS、NH3-N、挥发酚、氰化物、硫化物、石油类质量浓度分别为140,100,20,0...     

土壤修复与重金属回收中的超临界二氧化碳萃取技术

针对应用于污染土壤修复、重金属回收以及核废料处理领域的超临界二氧化碳萃取技术,重点阐述了该技术的国内外研究进展和最新动向,分析了超临界二氧化碳萃取用于上述领域与传统工艺相比的技术优势,并指出了今后应该着力解决的关键问题。     

Formation and cytotoxicity of a new disinfection by-product (DBP) phenazine by chloramination of water containing diphenylamine

Disinfection by-products (DBPs) in drinking water have caused worldwide concern due to their potential carcinogenic effects. The formation of phenazine from diphenylamine (DPhA) chloramination was studied and its cytotoxicities for two human cancer cells were also investigated. Phenazine was detected synchronously with the consumption of DPhA by chloramination, which further confirmed that the new DBP phenazine can be produced along with N-nitrosodiphenylamine (NDPhA) from DPhA chloramination. The formation of phenazine had a maximum molar yield with solution pH increasing from 5.0 to 9.0, with phenazine as the main product for DPhA chloramination at lower pH, but higher pH favored the formation of NDPhA. Thus, solution pH is the key factor in controlling the formation of phenazine and NDPhA. Both the initial DPhA and chloramine concentrations did not show a significant effect on the molar yields of phenazine, although increasing the chloramine concentration could speed up the reaction rate of DPhA with chloramines. The cytotoxicity assays showed that phenazine had significant cell-specific toxicity towards T24 (bladder cancer cell lines) and HepG2 (hepatic tumor cell lines) cells with IC50 values of 0.50 and 2.04 mmol/L, respectively, and T24 cells being more sensitive to phenazine than HepG2 cells. The IC50 values of phenazine, DPhA, and NDPhA for T24 cells were of the same order of magnitude and the cytotoxicity of phenazine for T24 cells was slightly lower than that of NDPhA (IC50, 0.16 mmol/L), suggesting that phenazine in drinking water may have an adverse effect on human health.     

固体径迹探测器与RAD-7测氡仪测定民用建筑工程室内氡浓度的比较

民用建筑工程室内氡的监测方法很多,其中固体径迹探测器法属于国标方法,RAD-7测氡仪法为近年来引进的仪器监测方法。本文对两种方法进行了比较,包括监测方法及原理、比对试验,并分析了2种方法的相关性、一致性和精度,以及两者在民用建筑工程室内氡验收监测的实际应用中的优缺点等,结果表明:以上两种方法从技术角度上讲,各有优点,均能满足一般室内空气中氡浓度的监测要求,虽然可利用固体径迹探测器法累积测量的结果来估算居住者受照剂量,进而评价氡的辐射危害,但因检验周期(至少30 d)过长,所以不适宜于工程检测;比较而言,RAD-7测氡仪的配置参数和测量方式更适宜于民用建筑工程的室内氡监测,已成为目前监测的主要方法,但在实际监测中,还需注意合理设置足够长的采样时间、湿度控制在10%以下、气路中残留气体的冲洗净化以及当初测值接近或超过《规范》规定的限量值时,有必要进一步延长监测时间进行跟踪监测等事项,以保证监测结果准确可靠。     

Formation of secondary inorganic aerosol in a frigid urban atmosphere

•Harbin showed relatively high threshold RH (80%) for apparent increase of SOR. •The observed SOR were at the lower end of the ratios from Beijing’s winter. •Temperature-dependent increase of NOR was sharper than that of SOR. • NOR increased with stronger biomass burning impact but SOR was largely unchanged. Formation of secondary inorganic aerosol (SIA) was investigated during a six-month long heating season in Harbin, China. Enhanced sulfate formation was observed at high relative humidity (RH), with the same threshold RH (80%) for both colder and warmer measurement periods. Compared to wintertime results from Beijing, the threshold RH was considerably higher in Harbin, whereas the RH-dependent enhancement of sulfur oxidation ratio (SOR) was less significant. In addition, the high RH events were rarely encountered, and for other periods, the SOR were typically as low as ~0.1. Therefore, the sulfate formation was considered inefficient in this study. After excluding the several cases with high RH, both SOR and the nitrogen oxidation ratio (NOR) exhibited increasing trends as the temperature increased, with the increase of NOR being sharper. The nitrate to sulfate ratio tended to increase with increasing temperature as well. Based on a semi-quantitative approach, this trend was attributed primarily to the temperature-dependent variations of precursors including SO₂ and NO₂. The influence of biomass burning emissions on SIA formation was also evident. With stronger impact of biomass burning, an enhancement in NOR was observed whereas SOR was largely unchanged. The different patterns were identified as the dominant driver of the larger nitrate to sulfate ratios measured at higher concentrations of fine particulate matter.