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941.
AA3自动分析仪测定地表水中的NO2-N、NO3-N+NO2-N、NH3-N、PO4^3- 总被引:9,自引:0,他引:9
使用Bran+Luebbe AutoAnalyzer 3自动分析仪,同时测定地表水中的NO2-N、NO3-N+NO2-N、NH3-N、PO4^3-4个项目,结果显示相对标准偏差均〈1%,回收率在92%~108%之间,检测限较低,且系统运行稳定,能够满足地表水监测的要求。 相似文献
942.
Biodegradation of polycyclic aromatic hydrocarbons by a mixed culture 总被引:39,自引:0,他引:39
We investigated the potential biodegradation of polycyclic aromatic hydrocarbons (PAHs) by an aerobic mixed culture utilizing phenanthrene as its carbon source. Following a 3-5 h post-treatment lag phase, complete degradation of 5 mg/l phenanthrene occurred within 28 h (optimal conditions determined as 30 degrees C and pH 7.0). Phenanthrene degradation was enhanced by the individual addition of yeast extract, acetate, glucose or pyruvate. Results show that the higher the phenanthrene concentration, the slower the degradation rate. While the mixed culture was also capable of efficiently degrading pyrene and acenaphthene, it failed to degrade anthracene and fluorene. In samples containing a mixture of the five PAHs, treatment with the aerobic culture increased degradation rates for fluorene and anthracene and decreased degradation rates for acenaphthene, phenanthrene and pyrene. Finally, it was observed that when nonionic surfactants were present at levels above critical micelle concentrations (CMCs), phenanthrene degradation was completely inhibited by the addition of Brij 30 and Brij 35, and delayed by the addition of Triton X100 and Triton N101. 相似文献
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944.
Sampling and analysis of ambient dioxins in northern Taiwan 总被引:2,自引:0,他引:2
In this study, ambient air samples were taken concurrently in the vicinity area of a large-scale municipal waste incinerator (MWI) and the background area for measuring polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs) concentrations from November 1999 through July 2000 in northern Taiwan. The results obtained from eighteen ambient air samples indicate that the mean PCDD/F concentration of seventeen 2,3,7,8-substituted congeners in wintertime (188–348 fg-I-TEQ/m3) is significantly higher than that measured in summertime (56–166 fg-I-TEQ/m3). In addition, the seasonal PCDD/F concentrations are compared with the ambient air quality data including CO, NO2, PM10 and TSP sampled from Taipei area to gain better insights. It indicates that the variation of ambient air PCDD/F concentrations is closely correlated with that of PM10 concentrations. Besides, the results indicate that the I-TEQ concentration of ambient air in sampling site B (directly downwind of the MWI) is of the highest while the sampling site A (upwind of MWI) is of the lowest among all sampling sites. This implies that existing MWI can be a significant emitter of PCDD/Fs in this area. Furthermore, the patterns of the PCDD/F congener distribution at all sampling sites (including the background site in Taoyuan) are quite similar. OCDD concentration is of the highest among seventeen PCDD/F congeners investigated and accounts for about 35% of the total concentration. As for the I-TEQ concentrations, 2,3,4,7,8-PeCDF is the most significant contributor, generally being responsible for 30–45% of the total I-TEQ values depending on the sampling sites and seasons. 相似文献
945.
本文所研究江段的有机污染物主要来自两岸工业排放的废水、生活污水、工业废弃物及生活垃圾。污染源主要位于右岸,上游右岸沉积物中有机污染物的总浓度高于左岸,下游两岸沉积物中有机污染物的总浓度趋于一致。两岸沉积物中污染物总浓度随距离的变化规律如下: 右岸:C=92.044S~(-0.3028) R=-0.962 左岸:C=9.231e~(-0.0058) R=0.946 在该江段沉积物中共检出51种有机污染物。其中致癌、可疑致癌、致突变化合物25种,占检出化合物的49%。淤泥质沉积物中有机污染物的存在量60.67吨,岸边滩及心滩土壤中存在量138.2吨。 相似文献
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948.
Yiin LM Millette JR Vette A Ilacqua V Quan C Gorczynski J Kendall M Chen LC Weisel CP Buckley B Yang I Lioy PJ 《Journal of the Air & Waste Management Association (1995)》2004,54(5):515-528
The collapse of the World Trade Center (WTC) on September 11, 2001, generated large amounts of dust and smoke that settled in the surrounding indoor and outdoor environments in southern Manhattan. Sixteen dust samples were collected from undisturbed locations inside two uncleaned buildings that were adjacent to Ground Zero. These samples were analyzed for morphology, metals, and organic compounds, and the results were compared with the previously reported outdoor WTC dust/smoke results. We also analyzed seven additional dust samples provided by residents in the local neighborhoods. The morphologic analyses showed that the indoor WTC dust/smoke samples were similar to the outdoor WTC dust/smoke samples in composition and characteristics but with more than 50% mass in the <53-microm size fraction. This was in contrast to the outdoor samples that contained >50% of mass above >53 microm. Elemental analyses also showed the similarities, but at lower concentrations. Organic compounds present in the outdoor samples were also detected in the indoor samples. Conversely, the resident-provided convenience dust samples were different from either the WTC indoor or outdoor samples in composition and pH, indicating that they were not WTC-affected locations. In summary, the indoor dust/smoke was similar in concentration to the outdoor dust/smoke but had a greater percentage of mass <53 microm in diameter. 相似文献
949.
Xiaodong Zou Zhemin Shen Tao Yuan Shan Yin Jingping Cai Liping Chen Wenhua Wang 《Atmospheric environment (Oxford, England : 1994)》2006,40(40):8068-8073
In this paper, a shifted power-law model, based on the wind profile model, had been supposed to simulate concentration gradient of nitrogen dioxide (NO2) with distance from a highway. Field experiments were performed for NO2 gradients from a highway in Shanghai by using passive samplers. The shifted power-law model was fitted well with experimental results of field experiments both in this study and in the literature. The results not only verified the validity of shifted power-law relationship between NO2 concentration and the distance from a highway, but also partially demonstrated that there were some significant similarities between wind profile and air pollutants concentration profile near highway. With known concentration of chosen reference point and appropriate value of the parameter k, the model could be practically applied for predicting the NO2 distributions near a highway. The methods of determining the parameter k were also discussed for further detailed studies. 相似文献
950.