Dioxin uptake by Indian plant species

Dioxins like various gaseous pollutants and aerosols can be scavenged by appropriate vegetative greenbelts. Based on their stomatal properties and the models for contaminant uptake, uptake of dioxin (2,3,7,8-TCDD) by three important Indian plant species, viz. Eugenia jambolana (Jamun), Azadirachta indica (Neem) and Ficus religiosa (Peepal), has been estimated. 2,3,7,8-TCDD is a contaminant with severe harmful ecological ramifications. Computations show that Ficus religiosa has highest uptake capacity. The present exercise has its utility in designing appropriate green-belts for mitigating adverse environmental and human health impacts due to dioxins. This can be an effective management option for mitigating the damages caused by dioxins.     

Heavy metal concentration in fish tissues inhabiting waters of “Buško Blato” reservoar (Bosnia and Herzegovina)

Heavy metals concentration (mercury, lead, cadmium, arsenic, copper, zinc and chromium) in tissues (muscles, liver, kidney and gonads) of Dalmatian barbelgudgeon, the nase, the souffie and brown trout, inhabiting waters of Busko Blato reservoir in Bosnia and Herzegovina, has been determined by atomic absorption spectrophotometry. The meat of the tested fish sorts does not contain elevated concentration of most analyzed heavy metals with exception of lead (higher than MAC in Italy, Germany and Denmark) and mercury (in muscles of brown trout higher than MAC in most countries). The lowest level of all heavy metals is always detected in gonads, with higher values in fry compared to milt for copper, zinc, chromium and arsenic. The highest copper concentration is observed in the liver from the souffie which is suggested as a suitable biomonitor for copper intoxication. In muscles of all fish sorts, lead was always present in much higher concentration than cadmium, while in kidneys of most fish sorts, lead and cadmium concentrations were similar. We showed that bioaccumulation of some heavy metals in the fish sorts analyzed is tissue and sex dependent. Also, we concluded that the small water exchange in reversible shallow reservoir does not induce elevated concentration of heavy metals in fish tissues inhabiting Busko Blato.     

Application of GIS in the study of mass transport of pollutants by Adyar and Cooum Rivers in Chennai, Tamilnadu

Residential, industrial, commercial, institutional and recreational activities discharge degradable and non-degradable wastes that reach the coastal water through rivers and cause coastal pollution. In the present study, mass transport of pollutants by Adyar and Cooum Rivers to the coastal water as a result of land-based discharges was estimated during low tide. The lowest and the highest flow recorded in Adyar varied from 514.59 to 2,585.08×10⁶ litres/day. Similarly, the flow in Cooum River fluctuated between 266.45 and 709.34×10⁶ litres/day. The present study revealed that the Adyar River transported 53.89–454.11 t/d of suspended solids, 0.06–19.64 t/d of ammonia, 15.95–123.24 t/d of nitrate and 0.4–17.86 t/d of phosphate, 0.004–0.09 kg/d of cadmium, 0.15–1.29 kg/d of lead and 3.03–17.58 kg/d of zinc to the coastal water owing to its high discharge. Similarly, the Cooum River transported 11.87–120.06 t/d of suspended solids, 0.08–58.7 t/d of ammonia, 6.11–29.25 t/d of nitrate and 0.66–10.73 t/d of phosphate, 0.003–0.021 kg/d of cadmium, 0.02–0.44 kg/d of lead and 1.36–3.87 kg/d of zinc. A higher concentration of suspended solids was noticed in post monsoon and summer months. An increase in the mass transport of ammonia, nitrate, phosphate in summer months (April and May) and an increase in the mass transport of cadmium, lead and zinc were observed in monsoon months (October–December) in both the rivers. Thus mass transport of pollutants study reveal that Cooum and Adyar Rivers in Chennai contribute to coastal pollution by transporting inorganic and trace metals significantly through land drainage.     

Development of an integrated sensor to measure odors

Odorous air samples collected from several sources were presented to an olfactometer, an electronic nose, a hydrogen sulfide (H(2)S) detector and an ammonia (NH(3)) detector. The olfactometry measurements were used as the expected values while measurements from the other instrumentation values became input variables. Five hypotheses were established to relate the input variables and the expected values. Both linear regression and artificial neural network analyses were used to test the hypotheses. Principal component analysis was utilized to reduce the dimensionality of the electronic nose measurements from 33 to 3 without significant loss of information. The electronic nose or the H(2)S detector can individually predict odor concentration measurements with similar accuracy (R (2) = 0.46 and 0.50, respectively). Although the NH(3) detector alone has a very poor relationship with odor concentration measurements, combining the H(2)S and NH(3) detectors can predict odor concentrations more accurately (R (2) = 0.58) than either individual instrument. Data from the integration of the electronic nose, H(2)S, and NH(3) detectors produce the best prediction of odor concentrations (R (2) = 0.75). With this accuracy, odor concentration measurements can be confidently represented by integrating an electronic nose, and H(2)S and NH(3) detectors.     

Simplified determination of lipophilic metabolites of nonylphenol ethoxylates: method development and application in aqueous samples from Buenos Aires, Argentina

In the present work we have developed an analytical methodology for the determination of nonylphenol (NP) and nonylphenol mono- and di-ethoxylates (NP1EO and NP2EO) in water samples. The applicability of this methodology was proved by means of the analysis of environmentally relevant aqueous samples from Buenos Aires. This constitutes a starting point for a rigorous assessment of the incidence of NPnEO surfactants in Argentina, as only very few, qualitative or semi-quantitative data on the occurrence of these compounds in local systems were available up to this time. Enrichment of the analytes was carried out by solid-phase extraction on a C-18 sorbent, followed by elution with ethyl acetate. Normal-phase high performance liquid chromatography on an amino-silica column and fluorescence detection at excitation-emission wavelengths of 230-300 nm were employed for separation and quantification of the analytes. Confirmation of peak assignment in selected real samples was performed by off-line coupling HPLC with GC-MS analysis. A non-polar GC capillary column was used, and a characteristic peak pattern was obtained for the alkyl chain isomers of each ethoxylated homologue and NP. GC-MS analyses yielded in all cases purity levels higher than 80% for the HPLC collected fractions. The elevated concentrations found for the estrogenic metabolites of NPnEO are in accordance with an unrestricted use of this class of non-ionic surfactants in the country.     

Coupling upland watershed and downstream waterbody hydrodynamic and water quality models (SWAT and CE-QUAL-W2) for better water resources management in complex river basins

Effective water resources management programs have always incorporated detailed analyses of hydrological and water quality processes in the upland watershed and downstream waterbody. We have integrated two powerful hydrological and water quality models (SWAT and CE-QUAL-W2) to simulate the combined processes of water quantity and quality both in the upland watershed and downstream waterbody. Whereas the SWAT model outputs water quality variables in its entirety, the CE-QUAL-W2 model requires inputs in various pools of organic matter contents. An intermediate program was developed to extract outputs from SWAT at required subbasin and reach outlets and converts them into acceptable CE-QUAL-W2 inputs. The CE-QUAL-W2 model was later calibrated for various hydrodynamic and water quality simulations in the Cedar Creek Reservoir, TX, USA. The results indicate that the two models are compatible and can be used to assess and manage water resources in complex watersheds comprised of upland watershed and downstream waterbodies.     

Quantitative arsenic speciation in two species of earthworms from a former mine site

The relationship between the total arsenic concentration and the chemical speciation of arsenic in two species of earthworm (Lumbricus rubellus and Dendrodrilus rubidus) in relation to the host soil, was investigated for 13 sites of varying arsenic content, including a background level garden soil and a former mine site at the Devon Great Consols, UK. Earthworms were collected with the host soil (As soil concentration range 16-12, 466 mg kg(-1) dry weight) and measured for their total arsenic (concentration range 7-595 mg kg(-1) dry weight) using inductively coupled plasma mass spectrometry (ICP-MS). A methanol-water mixture was used to extract arsenic species from the earthworms prior to determination of the individual arsenic species by a combination of anion and cation exchange high performance liquid chromatography coupled to inductively coupled plasma mass spectrometry (HPLC-ICP-MS). A gradient elution anion exchange method is presented whereby nine arsenic species could be measured in one sample injection. Arsenic species were identified by comparison of retention times and sample spiking with known standards and a fully characterised seaweed extract. Arsenic was generally present in the earthworm as arsenate (As(V)) or arsenite (As(III)) and arsenobetaine (AB). Methylarsonate (MA), dimethylarsinate (DMA) and three arsenosugars (glycerol, phosphate, sulfate) were present as minor constituents. These results are discussed in relation to the mechanisms for coping with exposure to soil bound arsenic.     

Origin and characterisation of microparticles in an ice core from the Central Dronning Maud Land, East Antarctica

The scanning electron microscopy-energy dispersive spectroscopic (SEM-EDS) study of selected samples from an ice core collected from Central Dronning Maud Land (CDML), East Antarctica, revealed several microparticles. They are mainly siliceous and carbonaceous particles and have distinct variations in their shape and composition. The morphology and major element chemistry of the particles suggest their origin from either volcanic eruptions or continental dust. The EDS analysis revealed that the volcanic particles are enriched in silica (average SiO2 62%), compared to the continental dust particle (average SiO2 56%). We found that the tephra relating to Agung (1963) and Karkatau (1883) volcanic eruptions, as recorded, in the ice core harbored microbial cells (both coocoid and rods). The occurrence of organic and inorganic particles which bear relation to volcanic eruption and continental dust implies significant environmental changes in the recent past.     

The comparison of heavy metal accumulation ratios of some fish species in Enne Dame Lake (Kütahya/Turkey)

The metal accumulation levels for muscle, skin, gill, liver and intestine tissues of some Cyprinidae species (Carassius carassius, Condrostoma nasus, Leuciscus cephalus and Alburnus alburnus) in Enne Dame Lake (Kütahya/Turkey), which is mostly fed by hot spring waters, were investigated. Analyses were performed for copper (Cu), zinc (Zn), manganese (Mn), iron (Fe), cobalt (Co), magnesium (Mg), nickel (Ni), chrome (Cr) and boron (B) using inductively coupled plasma-optic emission spectroscopy (ICP-OES), and cadmium (Cd) using atomic absorption spectrophotometer (AAS) utilizing microwave digestion techniques. The concentrations of the heavy metals found in the fish varied in the follow ing ranges: Cu: < DL-7.04, Zn: 6.96-357.25, Mn: < DL-20.70, Ni: < DL-6.21, Fe: 9.62-2500.33, Cr: < DL-1.74, Co: < DL-0.54, Cd: 0.01-0.27 and Mg: 197.44-904.90 mg/kg wet weight. While B had the second highest concentration in the water of the lake, it was not encountered in any tissue of the investigated species. In all tissues and the species, While the bioaccumulation factors (BAFs) of Mn, Zn, Fe and Cu were remarkably high, the BAFs of Mg, Cr, Co, and B were also fairly low or none. Although the heavy metal accumulation levels for the muscle were generally lower than other tissues, there were some exceptions. Cd level in the muscle of C. carassius was higher than the permissible limit stated by Turkish legislation, FAO and WHO. The mean metal amounts for all the investigated tissues and species are statistically compared and discussed in this study.     

An assessment of fluoride in the coastal aquifer of the Bara tract in Bharuch district, Gujarat (India)

The fluoride (F) concentration in the coastal aquifers of Bara tract in Bharuch district, Gujarat was determined by potentiometric method using an ion-selective electrode. The fluoride concentration in these aquifers varies between 0.060 to 3.51 mg/L. It was also found that F has a positive correlation with pH and HCO(3)(-) whereas negatively correlated with Ca(2+), indicating that high fluoride in ground water is associated with low calcium content. This suggests that the higher pH of water promotes the leaching of fluoride and thus affects the concentration of fluoride in the ground water. It was also found that there exists no relationship between F, EC, and ground water table from surface in the ground water.