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941.
942.
Occurrence, distribution, and seasonal variation of estrogenic compounds and antibiotic residues in Jiulongjiang River, South China 总被引:1,自引:1,他引:0
Zhang X Zhang D Zhang H Luo Z Yan C 《Environmental science and pollution research international》2012,19(5):1392-1404
Background and purpose
Estrogenic compounds and antibiotic residues in environment are receiving significant attention because of their potential adverse effects on ecosystems and human health. The objectives of this study were to determine the occurrence and seasonal variability of eight kinds of estrogenic compounds and 14 antibiotics. The study developed an occurrence database of the estrogenic compounds and antibiotics in spatial and temporal scale in Jiulongjiang River, South China, to provide useful information for environmental management of this region.Methods
Eight estrogenic compounds and 14 antibiotic compounds were detected in Jiulongjiang River from 19 sampling sites during high-flow and low-flow season in surface water. The samples were preconcentrated by solid-phase extraction for analysis. Eight estrogenic compounds were analyzed by gas chromatography mass spectrometry (Agilent 7890A-5975C), and antibiotics were determined by liquid chromatography-tandem mass spectrometry (LC?CMS/MS) system (ABI 3200 Q TRAP).Results
All target compounds could be detected, except 17??-ethynylestradiol, sulfamerazine, and ofloxacin. The median concentrations for seven estrogenic compounds ranged from 6.00 to 610.72?ng/L, with the detection frequency range of 16.00?C100%. However, the detection frequencies of 13 antibiotics detected varied from 50% to 100%, with the median concentrations ranged from 0.89 to 117.97?ng/L. Seasonal variations were obvious for most estrogenic compounds in Jiulongjiang River, except for octylphenol and estriol. There were significant (P?0.001) differences for three tetracyclines, sulfadiazine, and sulfamethoxazole between in low-flow season and in high-flow season. Besides, spatially considerable variations in the concentrations were observed for antibiotics, nonylphenol, octylphenol, and bisphenol A.Conclusion
The Jiulongjiang River water was more seriously contaminated by diethylstilbestrol, estrone, sulfamethazine, and tetracyclines. Higher overall concentration levels of estrogenic compounds and antibiotics were detected in low-flow water than those in high-flow water. The pollution of estrogenic compounds and antibiotics in Jiulongjiang River mainly came from municipal sewage and livestock breeding activities. 相似文献943.
混凝法深度处理废纸造纸废水实验研究 总被引:4,自引:2,他引:2
按照烧杯实验方法,重点考察了pH值、混凝剂种类和投加量等因素对生化处理后废纸造纸废水混凝处理效果的影响。实验结果表明:PAC作为混凝剂,PAM作为助凝剂联合处理该废水时,能够取得较好的去浊率、SS、色度和COD去除率。混凝沉淀最佳运行条件为:废水pH为6.5,含铝量10%的PAC和2 g/L的PAM投加量分别为1 mL/L、0.5 mL/L,浊度从35 NTU降低到1 NTU,去除率达97.1%,SS从30 mg/L降低到7 mg/L,去除率达76.7%,色度从64倍降低到18倍,去除率达71.9%,COD从95 mg/L降低到44.8 mg/L,去除率可达52.8%,取得了较好的去除效果,达到国家造纸废水新排放标准限值。 相似文献
944.
理顺运转机制,做好环境保护工作 总被引:1,自引:0,他引:1
阐述了环境管理,环境监测,环境监测三者之间的相互关系,并对三者之间的交叉点,矛盾点做了进一步的探讨和分析,提出了可行性的建议,以期形成统一,高效,具有强大战斗力的一支环保队伍。 相似文献
945.
Bioaccumulative characteristics of hexabromocyclododecanes in freshwater species from an electronic waste recycling area in China 总被引:1,自引:0,他引:1
Xiaoling Zhang Fangxing Yang Caihong Luo Sheng Wen Xian Zhang Ying Xu 《Chemosphere》2009,76(11):1572-1578
Hexabromocyclododecanes (HBCDs) are now emerging ubiquitous contaminants due to their wide usage, persistence and toxicities. To investigate the bioaccumulative characteristics of HBCDs, sediments, Winkle (Littorina littorea), crucian carp (Carassius carassius) and loach (Misgurnus anguillicaudatus) were collected from two streams near an E-waste dismantling site in China, and HBCD exposure test was then conducted on Chinese rare minnow. The concentration of HBCDs was 14 ng g−1 dry weight in sediments, 186, 377 and 1791 ng g−1 lipid weight in winkle, crucian carp and loach, respectively. γ-HBCD was found to be the dominant diastereoisomer in the sediments (63% of total HBCDs). However, α-HBCD was selectively accumulated in the biotic samples and contributed to 77%, 63% and 63% of total HBCDs in winkle, crucian carp and loach, respectively. Moreover, an enrichment of (−)-enantiomers of α- and γ-HBCD were found in the winkle. The reverse results were observed in the crucian carp and loach. Similar observations of diastereoisomeric and enantiomeric composition were obtained in Chinese rare minnow with those found in the crucian carp and loach. These results indicate that the freshwater species from the streams are contaminated by HBCDs. α-HBCD can be selectively accumulated in organisms and the accumulative characteristics are enantioselective among species. 相似文献
946.
以浙江田村为个案,从村民的生活方式和生产方式的变化出发,分析没有外来工业污染情况下的农村水污染社会原因.我国广大农村正在遭受"现代化"生产、生活方式的包围和侵袭,要改变这种现状,首先要做的就是改变农民传统的对水的认识、提高广大农民的环境保护意识. 相似文献
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