Rapid adsorption of toxic Pb(Ⅱ) ions from aqueous solution using multiwall carbon nanotubes synthesized by microwave chemical vapor deposition technique

Multiwall carbon nanotubes(MWCNTs) were synthesized using a tubular microwave chemical vapor deposition technique, using acetylene and hydrogen as the precursor gases and ferrocene as catalyst. The novel MWCNT samples were tested for their performance in terms of Pb(Ⅱ)binding. The synthesized MWCNT samples were characterized using Fourier Transform Infrared(FT-IR), Brunauer, Emmett and Teller(BET), Field Emission Scanning Electron Microscopy(FESEM) analysis, and the adsorption of Pb(Ⅱ) was studied as a function of p H,initial Pb(Ⅱ) concentration, MWCNT dosage, agitation speed, and adsorption time, and process parameters were optimized. The adsorption data followed both Freundlich and Langmuir isotherms. On the basis of the Langmuir model, Qmaxwas calculated to be 104.2 mg/g for the microwave-synthesized MWCNTs. In order to investigate the dynamic behavior of MWCNTs as an adsorbent, the kinetic data were modeled using pseudo first-order and pseudo second-order equations. Different thermodynamic parameters, viz., ΔH0, ΔS0and ΔG0were evaluated and it was found that the adsorption was feasible, spontaneous and endothermic in nature. The statistical analysis revealed that the optimum conditions for the highest removal(99.9%) of Pb(Ⅱ) are at p H 5, MWCNT dosage 0.1 g, agitation speed 160 r/min and time of 22.5 min with the initial concentration of 10 mg/L. Our results proved that microwave-synthesized MWCNTs can be used as an effective Pb(Ⅱ) adsorbent due to their high adsorption capacity as well as the short adsorption time needed to achieve equilibrium.     

Effect of Pollution On the Occurrence, Distribution and Sulphur Transformation Ability of the Thiobacilli in the River Ganga

The occurrence, distribution and nature of ambient thiobacilli along with their ability to oxidize different sulphur species under simulated natural and in vitro culture conditions were studied in the polluted and unpolluted sites of the River Ganga.

Thiobacillus thioparus, T. thiooxidans and T. denitrificans were isolated from the river water. the former two occurred in both polluted and unpolluted sites, while T. denitrificans occurred in polluted areas only. the paper pulp mill effluent discharge area contained the highest population of T. thioparus. the sewage drainage area showed relatively higher populations of T. thiooxidans and T. denitrificans.

The present study revealed that only biological oxidation of either thiosulphate or elemental sulphur occurred in the river water. All the thiobacilli screened oxidized thiosulphate, and three-fourths of them oxidized elemental sulphur. Some strains were found to be very good acidifiers. in spite of such acidification by the ambient thiobacilli, the pH of the river water remained alkaline. the specific rates of thiosulphate (0.18 -0.51 μMmolh^-1 mg^-1 cell) and sulphur (1.3 - 6.2 Normality day^-1 mg^-1 biomass) oxidations under simulated natural condition were found to be higher in polluted areas when compared with the unpolluted one (sulphur: 0.8 - 1.0 Normality day^-1 mg^-1).

Further, addition of thiouslphate or elemental sulphur in the river water in simulated in vitro condition resulted in the increase of respective oxidation rates. the variations in the natae of pollutants discharged into the river water influenced the oxidation rate of thiosulphate or sulphur.     

Bacterial extracellular polymeric substance (EPS): a carrier of heavy metals in the marine food-chain

The ecological implications of metal binding properties of bacterial EPS and its possible role in the bioaccumulation of pollutants in the marine food-chain was investigated using a partially purified and chemically characterized microbial EPS isolated from a species of Marinobacter. Various factors influencing metal sorption by the EPS including the influence of initial metal concentrations, incubation time, pH and sodium chloride concentrations on binding of lead (Pb2+) and copper (Cu2+) were evaluated. The bacterial EPS selectively bound more amount of Cu2+ per mg of EPS than Pb2+. Both copper and lead were sorbed more at near neutral pH than acidic pH. The sorption of Cu2+ increased with increasing copper concentration. The estimated maximum binding ability (MBA) of the EPS was 182 nmol copper and 13 nmol lead mg(-1) EPS. However, the sorption of these metals decreased with the increase in sodium chloride concentration. Furthermore, up to 35% of 14C-labeled Marinobacter was ingested by a benthic polychaete Hediste diversicolor. On an average, 29% of the ingested EPS was absorbed into tissues and 49% of the EPS was respired. It was apparent that the animals used the EPS as a source of energy and nutrition. The labile nature of the bacterial EPS and its ability to bind heavy metals might route the bound metals through the marine food chain, thereby transferring and aiding bioaccumulation of metal pollutants in the higher trophic animals.     

Coastal and riverine ecosystems as adaptive flood defenses under a changing climate

Adaptation planning for flood risk forms a significant part of global climate change response. Engineering responses to higher water levels can be prohibitively costly. Several recent studies emphasize the potential role of ecosystems in flood protection as adaptive risk reduction measures while also contributing to carbon fixation. Here, we use a conceptual model study to illustrate the built-in adaptive capability of ecosystems to reduce a wide range of wave heights, occurring at different water levels, to a narrower range. Our model shows that wave height of waves running through a forested section is independent of initial height or of water level. Although the underlying phenomenon of non-linear wave attenuation within coastal vegetation is well studied, implications of reducing variability in wave heights for design of ecosystem and levee combinations have not yet been properly outlined. Narrowing the range of wave heights by a vegetation field generates an adaptive levee that is robust to a whole range of external conditions rather than only to a maximum wave height. This feature can substantially reduce costs for retrofitting of levees under changing future wave climates. Thereby, in wave prone areas, inclusion of ecosystems into flood defense schemes constitutes an adaptive and safe alternative to only hard engineered flood risk measures.     

Lung subcellular fractions and surfactant lipid metabolism of rats exposed with DDT or endosulfan intratracheally

The effect of intratracheally administered DDT (5 mg/100 g body weight) or endosulfan (1 mg/100 g body weight) for three consecutive days has been studied on lipid metabolism of rat lung subcellular fractions. Both the insecticides did not affect the lung weight and the protein contents of microsomes, lamellar bodies and surfactant but significantly increased the phospholipid contents of microsomal and surfactant system. Most of the neutral lipid components of lung subcellular fractions were also increased by DDT or endosulfan treatments, except that of surfactant triglycerides which were decreased by DDT treatment. DDT or endosulfan both increased the incorporation of radioactive [methyl-3H]choline into microsomal phosphatidylcholine (PC) and surfactant dipalmitoylphosphatidylcholine (DPPC) without affecting the incorporation of radioactive [methyl-14C]methionine, showing the increased synthesis of PC via CDPcholine pathway. The results presented in this communication showed that DDT and endosulfan, the two different chloroinsecticides have similar effects on microsomal lipid metabolism but produce different biochemical manifestations on the secretion of surfactant phospholipids.     

Correction to: Experimental performance evaluation of an impinging jet with fins type solar air heater

Environmental Science and Pollution Research - A Correction to this paper has been published: https://doi.org/10.1007/s11356-021-12458-z     

Force and acceleration corridors from lateral head impact

This study was conducted to provide force and acceleration corridors at different velocities describing the dynamic biomechanics of the lateral region of the human head. Temporo-parietal impact tests were conducted using specimens from ten unembalmed post-mortem human subjects. The specimens were isolated at the occipital condyle level, and pre-test x-ray and computed tomography images were obtained. They were prepared with multiple triaxial accelerometers and subjected to increasing velocities (up to 7.7 m/s) using free-fall techniques by impacting onto a force plate from which forces were recorded. A 40-durometer padding (50-mm thickness) material covering the force plate served as the impacting boundary condition. Computed tomography images obtained following the final impact test were used to identify pathology. Four specimens sustained skull fractures. Peak force, displacement, acceleration, energy, and head injury criterion variables were used to describe the dynamic biomechanics. Force and acceleration responses obtained from this experimental study along with other data will be of value in validating finite element models. The study underscored the need to enhance the sample size to derive probability-based human tolerance to side impacts.     

The Influence of Enhanced Side Impact Protection on Kinematics and Injury Measures of Far- or Center-Seated Children in Forward-Facing Child Restraints

Objective: To evaluate the influence of forward-facing child restraint systems’ (FFCRSs) side impact structure, such as side wings, on the head kinematics and response of a restrained, far- or center-seated 3-year-old anthropomorphic test device (ATD) in oblique sled tests.

Methods: Sled tests were conducted utilizing an FFCRS with large side wings and with the side wings removed. The CRS were attached via LATCH on 2 different vehicle seat fixtures—a small SUV rear bench seat and minivan rear bucket seat—secured to the sled carriage at 20° from lateral. Four tests were conducted on each vehicle seat fixture, 2 for each FFCRS configuration. A Q3s dummy was positioned in FFCRS according to the CRS owner's manual and FMVSS 213 procedures. The tests were conducted using the proposed FMVSS 213 side impact pulse. Three-dimensional motion cameras collected head excursion data. Relevant data collected during testing included the ATD head excursions, head accelerations, LATCH belt loads, and neck loads.

Results: Results indicate that side wings have little influence on head excursions and ATD response. The median lateral head excursion was 435 mm with side wings and 443 mm without side wings. The primary differences in head response were observed between the 2 vehicle seat fixtures due to the vehicle seat head restraint design. The bench seat integrated head restraint forced a tether routing path over the head restraint. Due to the lateral crash forces, the tether moved laterally off the head restraint reducing tension and increasing head excursion (477 mm median). In contrast, when the tether was routed through the bucket seat's adjustable head restraint, it maintained a tight attachment and helped control head excursion (393 mm median).

Conclusion: This testing illustrated relevant side impact crash circumstances where side wings do not provide the desired head containment for a 3-year-old ATD seated far-side or center in FFCRS. The head appears to roll out of the FFCRS even in the presence of side wings, which may expose the occupant to potential head impact injuries. We postulate that in a center or far-side seating configuration, the absence of door structure immediately adjacent to the CRS facilitates the rotation and tipping of the FFCRS toward the impact side and the roll-out of the head around the side wing structure. Results suggest that other prevention measures, in the form of alternative side impact structure design, FFCRS vehicle attachment, or shared protection between the FFCRS and the vehicle, may be necessary to protect children in oblique side impact crashes.     

Temporal Changes in Streamflow and Attribution of Changes to Climate and Landuse in Wisconsin Watersheds

Previous historic trends analyses on 21st Century hydrologic data in the United States generally focus on annual flow statistics and have continued to use USGS hydro‐climatic data network (HCDN) stations, although post‐1988 diversions and runoff regulations are not reflected in the HCDN. Using a more recent dataset, Geospatial Attributes of Gages for Evaluating Streamflow, version II (GAGES II), compiled by Falcone (2012), which includes more watersheds with reference conditions, a comprehensive analysis of changes in seasonal, and annual streamflow in Wisconsin watersheds is demonstrated. Given the pronounced influence of seasonal hydrology in Wisconsin watersheds, the objective of this study is to elucidate the nature of temporal (annual, seasonal, and monthly) changes in runoff. Considerable temporal and regional variability was found in annual and seasonal streamflow changes between the two historic periods 1951‐1980 and 1981‐2010 considered in the study. For example, the northern watersheds show relatively small changes in streamflow discharge ranging from ?6.0 to 4.2%, while the southern watersheds show relatively large increases in streamflow discharge ranging from 13.1 to 18.2%. To apportion streamflow changes to climate and nonclimatic factors, a method based on potential evapotranspiration changes is demonstrated. Results show that nonclimatic factors account for more than 60% of changes in annual runoff in Wisconsin watersheds considered in the study.     

Influence of ATD versus PMHS reference sensor inputs on computational brain response in frontal impacts to advanced combat helmet (ACH)

ABSTRACT

Objective: This study analyzed the influence of reference sensor inputs from anthropomorphic test devices (ATDs) versus postmortem human subjects (PMHSs) on simulations of frontal blunt impacts to the advanced combat helmet (ACH).

Methods: A rigid-arm pendulum was used to generate frontal impacts to ACHs mounted on ATDs and PMHS. An appropriately sized ACH was selected according to standard fitting guidelines. The National Operating Committee on Standards for Athletic Equipment (NOCSAE) head was selected for ATD tests due to shape features that enabled a realistic helmet fit. A custom procedure was used to mount a reference sensor internally near the center of gravity (CG) of the PMHS. Reference sensor data from the head CG were used as inputs for the Simulated Injury Monitor (SIMon). Brain responses were assessed with the cumulative strain damage measure set at 10%, or CSDM(10).

Results: Compared to ATD tests, PMHS tests produced 18.7% higher peak linear accelerations and 5.2% higher peak angular velocities. Average times to peak for linear accelerations were relatively similar between ATDs (5.5?ms) and PMHSs (5.8?ms). However, times to peak for angular velocities were higher by a factor of up to 3.4 for PMHSs compared to ATDs. Values for were also higher by a factor of up to 13.1 when PMHS inputs were used for SIMon.

Conclusions: The preliminary findings of this work indicate that small differences in ATD versus PMHS head kinematics could lead to large differences in strain-derived brain injury metrics such as CSDM.