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251.
Robert Blanchard Detlef Arndt Rainer Grätz Marco Poli Swen Scheider 《Journal of Loss Prevention in the Process Industries》2010,23(2):253-259
There is a general lack of information on the effects of full-bore obstacles on combustion in the literature, these obstacles are prevalent in many applications and knowledge of their effects on phenomena including burning rate, flame acceleration and DDT is important for the correct placing of explosion safety devices such as flame arresters and venting devices. In this work methane, propane, ethylene and hydrogen–air explosions were investigated in an 18 m long DN150 closed pipe with a 90 degree bend and various baffle obstacles placed at a short distance from the ignition source. After carrying out multiple experiments with the same configuration it was found that a relatively large variance existed in the measured flame speeds and overpressures, this was attributed to a stochastic element in how flames evolved and also how they caused and interacted with turbulence to produce flame acceleration. This led to several experiments being carried out for one configuration in order to obtain a meaningful average. It was shown that a 90 degree bend in a long tube had the ability to enhance flame speeds and overpressures, and shorten the run-up distance to DDT to a varying degree for a number of gases. In terms of the qualitative effects on these parameters they were comparable to baffle type obstacles with a blockage ratios of between 10 and 20%. 相似文献
252.
As it is practically impossible in an industrial society to reduce impacts into ecosystems to a level that would preclude any damages, the need for damage valuation arises. One of the available valuation tools is the economic approach. Subsequent publications present this approach using the example of soils. In this second part, two methods are presented for monetarising ecosystem services, the contingent valuation method, the valuation on the basis of restoration and replacement costs. Common arguments against the monetarisation of ecosystems, like the omission of intrinsic values or the incomplete information of individuals, are then discussed. In conclusion, limits and possibilities of monetarising ecosystem services are described. 相似文献
253.
Ethylarsine dichloride was used during WW I as a chemical warfare agent. Residues of this chemical warfare agent and its metabolites
are still present today and continue to contaminate soil and water.
A gas Chromatographic method for the detection and determination of ethylarsine dichloride is shown. Six dithiols were tested
as possible derivatization reagents for ethylarsine dichloride. With selection of the dithiol, matrix interferences can be
eliminated because of the different retention times of the derivatives. 相似文献
254.
Rainer W. Sieke Günter Lippke Alfred Krippendorf Rainer Haas Sven Lüdtke 《Environmental science and pollution research international》1998,5(4):199-201
The new technology of Plasmazon® uses the extremely strong oxidation of radicals to break up the compocunds of organic connections, e.g. chemical warfare agents like Clark I. In making a comparison of oxidation to normal ozone, the factor of the Plasmazon® -technology is available up to 103. The investigation in an experimental test shows that it is possible to destroy the warfare agent character of Clark I. As the possibility of a large-lot application this technology is the method of choice for other chemical or biological warfare agents. 相似文献
255.
Karsten E. Braun Burkhard Schmidt 《Journal of environmental science and health. Part. B》2017,52(2):122-130
The fate of 14C-labeled herbicide prosulfocarb was studied in an agricultural soil and in a sediment-water system, the sediment part of which was derived from Yangtze Three Gorges Reservoir, China. Time-course studies were performed for 28 d and 49 d, respectively. Main transformation routes of 14C-prosulfocarb were mineralization to 14CO2 and formation of nonextractable residues amounting to 12.13% and 10.43%, respectively, after 28 days (soil), and 9.40% and 11.98%, respectively, after 49 d (sediment-water system). Traces of prosulfocarbsulfoxide were detected by means of TLC, HPLC, and LC-MS; other transformation products were not found. Initial extraction of soil assays using 0.01 M CaCl2 solution showed that the bioavailability of the herbicide was considerably low; immediately after application (0.1 d of incubation), only 4.78% of applied radioactivity were detected in this aqueous fraction. DT50 values of 14C-prosulfocarb estimated from radio-TLC and -HPLC analyses were above 28 d in soil and ranged between 29 d and 49 d in the sediment-water system. Partitioning of 14C from water to sediment phase occurred with DT50 slightly above 2 d. With regard to the sediment-water system, adsorption occurred with log Koc = 1.38 (calculated from 2 day assays) and 2.35 (49 d assays). As similarly estimated from portions of 14C found in CaCl2 extracts of the 0.1 d assays, 14C-prosulfocarb's log Koc in soil was 2.96. With both experiments, similar portions of nonextractable radioactivity were associated with all soil organic matter fractions, i.e. nonhumics, fulvic acids, humic acids, and humin/minerals. Throughout all sample preparation, the experiments were severely impaired by losses of radioactivity especially with concentration of samples containing water in vacuo. All findings pointed to volatility of parent prosulfocarb in presence of water rather than volatility of transformation products. According to literature data, this behavior of prosulfocarb was not expected, though volatility was demonstrated under field conditions. 相似文献
256.
Jann Peyrat Małgorzata Braun Christian Dolnik Maike Isermann Hartmut Roweck 《Journal of Coastal Conservation》2009,13(4):235-246
Coastal dune ecosystems are among the most dynamic habitats with high conservation value in Europe but are also under strong
anthropogenic pressure regarding coastal protection and recreation. Hence, it is of high importance to know about long-term
natural and anthropogenic changes and development of protected dune habitats for nature conservation, as well as for coastal
management. This paper aims to identify the vegetation dynamics on the Łeba Bar/Poland over a period of 74 years by cartometric
comparison using modern Geographical Information System (GIS). To quantify the rate of vegetation dynamics two aerial photographs
dating from 1932 and 2006 were digitalized and analyzed with GIS to produce digital vegetation maps. Information about decrease,
increase and stability of vegetation types of this area are discussed. The results show that there has been a clear reduction
in the total area of bare sand and a considerable increase of woodlands and dense grass communities. Nevertheless, the remaining
extensive drift sand areas and deflation hollows on the Łeba Bar offer one of the most important habitats for pioneer vegetation
on bare sand of migrating dunes and dunes at the Southern Baltic coast. The present work proved the need to observe the future
development of the vegetation communities and to implement management measures to maintain the dynamic of this unique dune
landscape. 相似文献
257.
Den Boychuk W. John Braun Reg J. Kulperger Zinovi L. Krougly David A. Stanford 《Environmental and Ecological Statistics》2009,16(2):133-151
We consider a stochastic fire growth model, with the aim of predicting the behaviour of large forest fires. Such a model can
describe not only average growth, but also the variability of the growth. Implementing such a model in a computing environment
allows one to obtain probability contour plots, burn size distributions, and distributions of time to specified events. Such
a model also allows the incorporation of a stochastic spotting mechanism.
相似文献
Reg J. KulpergerEmail: |
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