In situ transformations of fine lead oxide particles in different soils

We present a field application of a new in situ technique to analyze phase transformations of fine lead oxide particles (50-100mum) in different soils directly in the field over 18 months. After the first month of exposure to a calcareous sand we found newly precipitated secondary mineral phases on the lead oxide. The samples exposed to two loamy soils (Dystric Cambisol and Luvisol) showed only very few traces of new phases. We identified the new phases as mainly lead-hydroxy carbonates (hydrocerussite). Whereas the results confirm the transformation of lead phases to lead carbonates in calcareous soil, they also show that an easily soluble phase such as PbO may persist in soils virtually unweathered for more than one year. The formation of a weathering crust is therefore not necessarily needed for preservation of easily soluble phases. The use of experimental in situ methods is thus giving new information on contaminant mineral behavior under field conditions.     

Global fate of POPs: current and future research directions

For legacy and emerging persistent organic pollutants (POPs), surprisingly little is still known in quantitative terms about their global sources and emissions. Atmospheric transport has been identified as the key global dispersal mechanism for most legacy POPs. In contrast, transport by ocean currents may prove to be the main transport route for many polar, emerging POPs. This is linked to the POPs' intrinsic physico-chemical properties, as exemplified by the different fate of hexachlorocyclohexanes in the Arctic. Similarly, our current understanding of POPs' global transport and fate remains sketchy. The importance of organic carbon and global temperature differences have been accepted as key drivers of POPs' global distribution. However, future research will need to understand the various biogeochemical and geophysical cycles under anthropogenic pressures to be able to understand and predict the global fate of POPs accurately.     

Seasonal differences and within-canopy variations of antioxidants in mature spruce (Picea abies) trees under elevated ozone in a free-air exposure system

The effect of free-air ozone fumigation and crown position on antioxidants were determined in old-growth spruce (Picea abies) trees in the seasonal course of two consecutive years (2003 and 2004). Levels of total ascorbate and its redox state in the apoplastic washing fluid (AWF) were increased under double ambient ozone concentrations (2xO3), whilst ascorbate concentrations in needle extracts were unchanged. Concentrations of apoplastic and symplastic ascorbate were significantly higher in 2003 compared to 2004 indicating a combined effect of the drought conditions in 2003 with enhanced ozone exposure. Elevated ozone had only weak effects on total glutathione levels in needle extracts, phloem exudates and xylem saps. Total and oxidised glutathione concentrations were higher in 2004 compared to 2003 and seemed to be more affected by enhanced ozone influx in the more humid year 2004 compared to the combined effect of elevated ozone and drought in 2003 as observed for ascorbate.     

Survey of organochlorine pesticides in horticultural soils and there grown Cucurbitaceae

Organochlorine pesticides (OCP) are still found in food and feed crops although they were applied about 40 years ago. There is a considerable knowledge gap concerning the extent of soil and crop contamination by OCP. We performed two surveys in 2002 and 2005 to assess the loads of OCP in 41 Swiss horticultural fields under organic and conventional production and corresponding Cucurbitaceae fruits (cucumbers, zucchini, and pumpkin), whereas these fields stay for intensive agricultural production in Europe. In addition, soil organic carbon, texture, and pH were measured also. OCP were detected in 27 out of 41 fields (65.9%). The farming practice had no influence on the contamination or level of OCP in soil. The sum of OCP-loads per field ranged from <0.01 to 1.3mgkg(-1) dry soil and pentachloroaniline (PCA, 2.1mgkg(-1)), p,p'-DDT (0.5mgkg(-1)), and p,p'-DDE and dieldrin (0.4mgkg(-1)) were the most detected pesticides over all investigated soils. PCA (up to 0.02mgkg(-1)), dieldrin (up to 0.04mgkg(-1)), alpha-chlordane and cis-heptachloroepoxide (<0.01mgkg(-1)) were detected in five cucumber samples out of 41 Cucurbitaceae samples. Statistical analysis revealed no significant influence of the measured soil properties on the OCP-load of soils and cucumbers, although there is evidence that the bioavailability of OCP in soils to Cucurbitaceae plants was influenced by the sorption of the compounds to soil organic matter and by the polarity of the pesticide molecules. It is suggested, that OCP contamination is widespread in all European regions with intensive plant production and associated pesticide use, and deserves more attention with respect to save food production.     

Trace element accumulation in woody plants of the Guadiamar Valley, SW Spain: a large-scale phytomanagement case study

Phytomanagement employs vegetation and soil amendments to reduce the environmental risk posed by contaminated sites. We investigated the distribution of trace elements in soils and woody plants from a large phytomanaged site, the Guadiamar Valley (SW Spain), 7 years after a mine spill, which contaminated the area in 1998. At spill-affected sites, topsoils (0-25 cm) had elevated concentrations of As (129 mg kg(-1)), Bi (1.64 mg kg(-1)), Cd (1.44 mg kg(-1)), Cu (115 mg kg(-1)), Pb (210 mg kg(-1)), Sb (13.8 mg kg(-1)), Tl (1.17 mg kg(-1)) and Zn (457 mg kg(-1)). Trace element concentrations in the studied species were, on average, within the normal ranges for higher plants. An exception was white poplar (Populus alba), which accumulated Cd and Zn in leaves up to 3 and 410 mg kg(-1) respectively. We discuss the results with regard to the phytomanagement of trace element contaminated sites.     

Meister

A mobile remote sensing system is presented for measuring the concentration of gaseous pollutants in ambient air and in directed effluent streams. MEISTER is based on Fourier-Transform-Infrared-Spectroscopy (FTIS), which is predestinated for a simultaneous analysis of a large number of atmospheric gases. The Kayser-Threde Double-Pendulum interferometer K300 and the Multicomponent Air Pollution Software (MAPS) of the Fraunhofer Institute of Atmospheric Environmental Research, which is based on radiative transfer modeling and least square fit procedures, enable a concentration determination under almost all meteorological conditions. CO, CO₂, NO, N₂O, CH₄, H₂O and HCl concentrations have been determined in good agreement with results from conventionalin situ sensors. NO₂, SO₂, NH₃, HCHO and hydrocarbons have been successfully detected provided their concentrations were high enough.     

Assessment of Bacterial Degradation of Aromatic Hydrocarbons in the Environment by Analysis of Stable Carbon Isotope Fractionation

¹³C/¹²C stable carbon isotope fractionation was used to assess biodegradation in contaminated aquifers with toluene as a model compound. Different strains of anaerobic bacteria (Thauera aromatica, Geobacter metallireducens, and the sulfate-reducing strain TRM1) showed consistent ¹³C/¹²C carbon isotope fractionation with fractionation factors between C = 1.0017 and 1.0018. In contrast, three cultures of aerobic organisms, using different mono- and dioxygenase enzyme systems to initiate toluene degradation, showed variable isotope fractionation factors of C = 1.0027 (Pseudomonasputida strain mt-2), C = 1.0011 (Ralstonia picketii), andC = 1.0004 (Pseudomonas putida strain F1). The great variability of isotope fractionation between different aerobic bacterial strains suggests that interpretation of isotope data in oxic habitats can only be qualitative. A soil column was run as a model system for contaminated aquifers with toluene as the carbon source and sulfate as the electron acceptor and samples were taken at different ports along the column. Microbial toluene degradation was calculated based on the ¹³C/¹²C isotope fractionation factors of the batch culture experiments together with the observed ¹³C/¹²C isotope shifts of the residual toluene fractions. The calculated percentage of biodegradation, B, correlated well with the decreasing toluene concentrations at the sampling ports and indicated the increasing extent of biodegradation along the column. The theoretical toluene concentrations as calculated based on the isotope values matched the measured concentrations at the different sampling ports indicating that the Rayleigh equation can be used to calculate biodegradation in quasi closed systems based on measured isotope shifts. A similar attempt was performed to assess toluene degradation in a contaminated, anoxic aquifer. A transect of groundwater wells was monitored along the main direction of the groundwater flow and revealed decreasing concentrations accompanied with an increase in the ¹³C/¹²C stable carbon isotope ratio of the residual toluene. Calculation of the extent of biodegradation based on the isotope values and laboratory derived isotope fractionation factors showed that the residual toluene was degraded to more than 99% by microbial activity. Calculation of the theoretical residual toluene concentrations based on the measured isotope values described the strongly decreasing concentrations along the plume. Other aromatic hydrocarbons like benzene and naphthalene which were analysed in the same course also showed decreasing concentrations along the groundwater flow path accompanied by increasing ¹³C values indicating biodegradation.     

Global environmental consequences of increased biodiesel consumption in Switzerland: consequential life cycle assessment

This study assesses the direct and indirect environmental impacts to be expected if Switzerland should replace one percent of its current diesel consumption with imports of A) soybean methyl ester (SME) from Brazil, or B) palm methyl ester (PME) from Malaysia. In order to take into account possible future consequences, what-if scenarios were developed and assessed by means of a consequential LCA. In contrast to attributional LCA, the consequential approach uses system enlargement to include the marginal products affected by a change of the physical flows in the central life cycle. This means that the LCA considers all inputs and outputs which are linked to biodiesel production and that the product system is subsequently expanded to include the marginal products affected. Both future systems are assessed in comparison with the environmental scores of the fossil equivalent to biodiesel, i.e. diesel low in sulphur. The environmental burdens are measured by means of greenhouse gas emissions (GHG), land occupation and various non-aggregated and aggregated environmental impact indicators.In sum, the environmental impacts of an increased SME consumption depend on the environmental scores of the marginal replacement products on the world market, rather than on local production factors. In other words, the marginal products assumed to be affected are most important for the results obtained, i.e. in particular the marginal vegetable oil, fodder cake and land areas. In this study it is SME production increased at the expense of the available soybean oil which shifts the impacts associated with soybean oil production to the production of the marginal vegetable oils on the world market. In this perspective, it is not relevant in which country biodiesel production takes place, but rather which vegetable oil is involved. With respect to PME, the most relevant determining factor for the environmental impacts is the land area affected by the increased cultivation of oil palms. Currently, this expansion displaces primarily peat land and rain forest. This causes GHG emissions which are much higher than the emissions of the fossil reference. All in all, both PME from Malaysia and SME from Brazil cause more environmental impact than allowed by the Swiss tax redemption on agro-biofuels (max. 60% GHG emissions and 125% UBP of the fossil reference).     

Mapping Land-Cover and Mangrove Structures with Remote Sensing Techniques: A Contribution to a Synoptic GIS in Support of Coastal Management in North Brazil

This article deals with the development and application of a cartographic database for a synoptic Geographic Information System (GIS). Its purpose is the storage and evaluation of the heterogeneous datasets of the interdisciplinary scientific research program MADAM (Mangrove Dynamics and Management), which aims to develop recommendations for a tailored integrated coastal management scheme for the mangrove ecosystem at Bragança (North Brazil). The article describes the integration of remote sensing data, aerial photographs, as well as point data provided by fieldwork from different scientific fields. Using various innovative processing techniques and different scale-resolution levels, an assessment of temporal–spatial changes of the mangrove peninsula and the adjacent rural socioeconomic impact area, the type of mangrove structure, as well as a land-use cover analyses was undertaken. The definition of the spatial level of detail was found to be a major issue in the development of the GIS, as well as during the processing and analysis procedures. A division between strong and weak patterns in the mangrove ecosystem could be made, which implies different management measures and sets of specific interdisciplinary studies and monitoring at hierarchical scales.