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101.
Influence of pH on the sonolysis of ciprofloxacin: Biodegradability, ecotoxicity and antibiotic activity of its degradation products 总被引:3,自引:0,他引:3
Evelien De Bel Jo Dewulf Bavo De Witte Herman Van Langenhove Colin Janssen 《Chemosphere》2009,77(2):291-295
The presence of antibiotics in the aquatic environment has raised concerns due to the potential risk for the emergence or persistence of antibiotic resistance. Antibiotics are often poorly degraded in conventional wastewater treatment plants. In this study, sonolysis at 520 kHz and 92 W L−1 was used for the degradation of the fluoroquinolone antibiotic ciprofloxacin. In a first experiment at pH 7, 57% of the ciprofloxacin (15 mg L−1) was degraded after 120 min of ultrasonic irradiation at 25 °C. pH proved to be an important parameter determining the degradation rate, since the pseudo first order degradation constant increased almost fourfold when comparing treatment at pH 7 (0.0058 min−1) and pH 10 (0.0069 min−1) with that at pH 3 (0.021 min−1). This effect can be attributed to the degree of protonation of the ciprofloxacin molecule. The BOD/COD ratio of the solutions, which is a measure for their biodegradability, increased from 0.06 to 0.60, 0.17, and 0.18 after 120 min of irradiation depending on the pH (3, 7, and 10, respectively). The solution treated at pH 3 can even be considered readily biodegradable (BOD/COD > 0.4). The antibiotic activity against Escherichia coli (G−) and Bacillus coagulans (G+) of the treated solutions also reduced after sonolysis. The highest decrease was again found when irradiated at pH 3. In contrast, ecotoxicity of the solutions to the alga Pseudokirchneriella subcapitata increased 3- to 10-fold after 20 min of treatment, suggesting the formation of toxic degradation products. The toxicity slowly diminished during further treatment. 相似文献
102.
Detlef Hinneburg Eberhard Renner Ralf Wolke 《Environmental science and pollution research international》2009,16(1):25-35
Background, aim, and scope The fraction of ambient PM10 that is due to the formation of secondary inorganic particulate sulfate and nitrate from the emissions of two large, brown-coal-fired
power stations in Saxony (East Germany) is examined. The power stations are equipped with natural-draft cooling towers. The
flue gases are directly piped into the cooling towers, thereby receiving an additionally intensified uplift. The exhausted
gas-steam mixture contains the gases CO, CO2, NO, NO2, and SO2, the directly emitted primary particles, and additionally, an excess of ‘free’ sulfate ions in water solution, which, after
the desulfurization steps, remain non-neutralized by cations. The precursor gases NO2 and SO2 are capable of forming nitric and sulfuric acid by several pathways. The acids can be neutralized by ammonia and generate
secondary particulate matter by heterogeneous condensation on preexisting particles.
Materials and methods The simulations are performed by a nested and multi-scale application of the online-coupled model system LM-MUSCAT. The Local
Model (LM; recently renamed as COSMO) of the German Weather Service performs the meteorological processes, while the Multi-scale
Atmospheric Transport Model (MUSCAT) includes the transport, the gas phase chemistry, as well as the aerosol chemistry (thermodynamic
ammonium–sulfate–nitrate–water system). The highest horizontal resolution in the inner region of Saxony is 0.7 km. One summer
and one winter episode, each realizing 5 weeks of the year 2002, are simulated twice, with the cooling tower emissions switched
on and off, respectively. This procedure serves to identify the direct and indirect influences of the single plumes on the
formation and distribution of the secondary inorganic aerosols.
Results and conclusions Surface traces of the individual tower plumes can be located and distinguished, especially in the well-mixed boundary layer
in daytime. At night, the plumes are decoupled from the surface. In no case does the resulting contribution of the cooling
tower emissions to PM10 significantly exceed 15 μgm−3 at the surface. These extreme values are obtained in narrow plumes on intensive summer conditions, whereas different situations
with lower turbulence (night, winter) remain below this value. About 90% of the PM10 concentrations in the plumes are secondarily formed sulfate, mainly ammonium sulfate, and about 10% originate from the primarily
emitted particles. Under the assumptions made, ammonium nitrate plays a rather marginal role.
Recommendations and perspectives The analyzed results depend on the specific emission data of power plants with flue gas emissions piped through the cooling
towers. The emitted fraction of ‘free’ sulfate ions remaining in excess after the desulfurization steps plays an important
role at the formation of secondary aerosols and therefore has to be measured carefully. 相似文献
103.
Joachim Maes Jo Vliegen Karen Van de Vel Stijn Janssen Felix Deutsch Koen De Ridder Clemens Mensink 《Atmospheric environment (Oxford, England : 1994)》2009,43(6):1246-1254
CORINAIR atmospheric emission inventories are frequently used input data for air quality models with a domain situated in Europe. In CORINAIR emission inventories, sources are broken down over 11 major source categories. This paper presents spatial surrogates for the disaggregation of CORINAIR atmospheric emission inventories for input of air pollutants and particulate matter to grid or polygon based air quality model domains inside Europe. The basis for the disaggregation model was the CLC2000 land cover data to which statistical weights were added. Weights were population census data for residential emissions, employment statistics for agricultural and industrial area emissions, livestock statistics for ammonia emissions and annual aircraft movements for emissions realized by air transport. Additional road and off-road network information was used to disaggregate emissions realized by traffic. A comparison of top down produced emission estimates with spatially resolved national emission data for The Netherlands and the United Kingdom gave confidence in the present spatial surrogates as a tool for the top down production of atmospheric emission maps. Explained variance at a spatial resolution of 5 km was >70% for CO, NMVOC and NOx, >60% for PM10 and almost 50% for SO2. 相似文献
104.
María A. Rubio Eduardo Lissi Guillermo Villena Y.F. Elshorbany Jörg Kleffmann Ralf Kurtenbach Peter Wiesen 《Atmospheric environment (Oxford, England : 1994)》2009,43(38):6106-6109
The amounts of formaldehyde and nitrous acid (HONO) in gas phase and dews of Santiago de Chile were simultaneously measured. Formaldehyde concentrations values in the liquid phase (dews) correlate fairly well with those in the gaseous phase and are even higher than those expected from gas–dew equilibrium. On the other hand, nitrite concentrations in dews were considerably smaller (ca. 15 times) than those expected from the gas-phase concentrations. This under-saturation is attributed to diffusion limitations due to the relatively large HONO solubility. In agreement with this, under-saturation increases with the rate of dew formation and the pH of the collected waters, factors that should increase the rate of gas to liquid HONO transfer required to reach equilibrium. 相似文献
105.
106.
Martin Volk Sven Lautenbach Hedwig van Delden Lachlan T. H. Newham Ralf Seppelt 《Environmental management》2010,46(6):834-849
This article analyses the benefits and shortcomings of the recently developed decision support systems (DSS) FLUMAGIS, Elbe-DSS,
CatchMODS, and MedAction. The analysis elaborates on the following aspects: (i) application area/decision problem, (ii) stakeholder
interaction/users involved, (iii) structure of DSS/model structure, (iv) usage of the DSS, and finally (v) most important
shortcomings. On the basis of this analysis, we formulate four criteria that we consider essential for the successful use
of DSS in landscape and river basin management. The criteria relate to (i) system quality, (ii) user support and user training,
(iii) perceived usefulness and (iv) user satisfaction. We can show that the availability of tools and technologies for DSS
in landscape and river basin management is good to excellent. However, our investigations indicate that several problems have
to be tackled. First of all, data availability and homogenisation, uncertainty analysis and uncertainty propagation and problems
with model integration require further attention. Furthermore, the appropriate and methodological stakeholder interaction
and the definition of ‘what end-users really need and want’ have been documented as general shortcomings of all four examples
of DSS. Thus, we propose an iterative development process that enables social learning of the different groups involved in
the development process, because it is easier to design a DSS for a group of stakeholders who actively participate in an iterative
process. We also identify two important lines of further development in DSS: the use of interactive visualization tools and
the methodology of optimization to inform scenario elaboration and evaluate trade-offs among environmental measures and management
alternatives. 相似文献
107.
108.
109.
Ralf Blank 《Environmental Sciences Europe》2002,14(2):104-109
Mycotoxins are a heterogeneous group of secondary fungal metabolites. Their formation in food and feedstuffs is influenced by many factors, including humidity, temperature, pH, oxygen concentration, type of substrate or presence of competitive microflora. The Food and Agriculture Organisation of the United Nations estimated in 1985 that approximately 25% of the world’s grain supply is contaminated with mycotoxins. There are more than 300 known mycotoxins; however, due to their occurrence and concentrations in food, and their toxic potential, only few of these are relevant with regard to consumer protection. These include the aflatoxins, ochratoxins and trichothecenes like deoxynivalenol, zearalenone and fumonisins. In Germany, only aflatoxins in food and feedstuffs are subjected to legal regulations. Beside the negative effects of mycotoxins on health and performance of farm animals, it is of importance to consider to what extent mycotoxins might be carried over into edible tissues like meat, milk and eggs when fed to farm animals. The present review shows that the carry over of mycotoxins into edible tissues is relatively low and is dependent on the specific mycotoxin and animal species. For example, due to the microbial decomposition of mycotoxins in the rumen, the carry over of mycotoxins into edible tissues of ruminants is considerably lower compared to monogastric species (pigs, chickens). Furthermore, after a short withdrawal period of 4 to 14 days combined with the feeding of non-contaminated diets, most of the mycotoxins, aside from ochratoxin A, are no longer detectable in any edible tissue. Ochratoxin A has a high binding affinity to specific blood proteins and is reabsorbed in the kidney; these mechanisms delay its elimination and increase the withdrawal period to at least 4 weeks. However, aside from the concentration of these substances in food, the daily intake of contaminated food is important for the risk analysis of mycotoxins to humans. In a recent study, it has been shown that more than 50% of the daily intake of ochratoxin A is derived from cereals and cereal products, and 30% from red wine, coffee and beer. Mear products from pigs and chickens only account for 4% of the total intake, while products from ruminants are considered to be negligible. These results indicate that mycotoxin-contaminated edible tissue, as compared to plant products, only plays a minor role with respect to consumer protection. 相似文献
110.
Henner Hollert Ralf Petto Peter Ebke und Hans-Christian Stolzenberg 《Umweltwissenschaften und Schadstoff-Forschung》2003,15(3):138-139
Ohne Zusammenfassung
Dr. rer. nat. Henner Hollert: • Leitung lokales Organisationskomittee SETAC-GLB 2003 • Studium der Biologie und Geographie an der Universit?t Heidelberg
von 1990 bis 1997. Februar 1997: Diplom in Biologie, Oktober 1997: Erstes Staatsexamen für das h?here Lehramt in Biologie/Geographie
• Von November 1997 bis April 2001: Promotion über die Entwicklung eines kombinierten Untersuchungssystems für die Bewertung
der ?kotoxikologischen Belastung von Flie?gew?ssersedimenten und-schwebstoffen • Forschungsaufenthalte 1999 und 2000 an den
Universit?ten Uppsala und ?rebro (Schweden) zur Untersuchung der Dioxin-?hnlichen Wirksamkeit von Sedimenten in embryonaler
Hühnerleberkultur • In der Lehre seit 2000 als Wissenschaftlicher Angestellter am Zoologischen Institut (Abt. Morphologie/?kologie)
mit den Schwerpunkten ?kotoxikologie, ?kologie und Zoologie t?tig • Leitung der Arbeitsgruppe Sediment- und Bodentoxikologie
• Forschungsschwerpunkte: Sediment- und Bodentoxikologie, Hochwasseruntersuchunge, Bioassay-dirigierte Fraktionierungstechniken,
Statistische Bewertungsmethoden, Integrierte Sedimentuntersuchungen (Kombination aus Makrozoobenthosanalysen, in-vitro-Biotests
und chemischer Analytik) • Vizepr?sident der deutschsprachigen Sektion der SETAC-GLB (Society of Environmental Toxicology
and Chemistry) • Organisationskomitee der europ?ischen Jahrestagung der SETAC und des Club of Rome in Hamburg-Harburg 2003
• Seit dem 11. Juni 2003 geh?rt Henner Hollert dem UWSF-Herausgebergremium an 相似文献