Photocatalytic remediation of methylene blue and antibacterial activity study using Schiff base-Cu complexes

This work describes the design of novel Cu(II) complexes and their application in the photocatalytic degradation of methylene blue (MB). The same photocatalyst exhibits antibacterial activity against Escherichia coli (gram-negative) and Bacillus circulans (gram-positive). The characterisation of the photocatalysts has been done by several up-to-date physical methods. The rationale behind the photocatalysts’ beneficial intervention is discussed in this study. Statistical analysis of the degradation of MB is done using a one-way ANOVA, and the significance of means is determined by a multiple comparison test using Turkey HSD. Also, the degradation of MB follows pseudo first-order kinetics with high correlation coefficient values (R²?>?0.95), making them useful as simple and low-cost organic dye degradation agents.

     

Discriminating zooplankton assemblages through multivariate methods: A case for a tropical polluted harbour and Bar-built estuary

A comparative study (June-July 2001) on zooplankton community structure amid polluted conditions in a stagnant harbour and relatively unaffected tidal estuary near Visakhapatnam, on the east coast of India, revealed a marked disparity in species composition and abundance. While the harbour supported a rich population of calanoids (46.4%), the estuary sustained mostly cyclopoids (55.2%). Univariate and multivariate techniques (species diversity, clustering, non-metric multi-dimensional scaling and one-way ANOSIM) revealed the existence of two differing zooplankton assemblages and associated water quality (similarity 50.6%). While the estuary is typified by high amounts of dissolved silica (67.4 ± 17.7 μmol l^-1) linked with monsoon influx, the harbour waters revealed abnormal levels of phosphate (40.9 ± 9.2 μmol l^-1) and nitrate (15.3 ± 5.41 μmol l^{- 1}) suggestive of intense eutrophication, caused by the discharge of fertilizer-factory waste and domestic sewage. On the basis of routines (e.g. BVSTEP, SIMPER) implemented in Plymouth Routines in Multivariate Ecological Research, it was possible to demonstrate that while species such as Oithona rigida, Oithona brevicornis, crustacean nauplii, gastropod veligers, Acartia spinicauda, and Acartia centrura played a key role in discriminating the zooplankton assemblage in the estuary, Acrocalanus spp. (mainly Acrocalanus gracilis) played a keyed role in harbour waters. Canonical Correspondence Analysis revealed species-environment relationships; for example, while the distribution of Oithona spp. and its associates in the estuary corresponded intimately with high silicate, temperature, and low salinity, it was high salinity, phosphate, and nitrate in the harbour channel that supported a different assemblage of copepods dominated by calanoids.     

IN-LAKE WATER QUALITY MANAGEMENT PLAN FOR A RECREATIONAL LAKE IN CENTRAL ILLINOIS1

Johnson Sauk Trail Lake remains highly eutrophic, even though the watershed has long been returned to an undisturbed condition with permanent vegetative cover and with little or no land disturbance in the watershed. Internal regeneration of nutrients has been identified as the major source of nutrients to the lake. Lake destratification, selective harvesting and removal of weeds, and control of algal blooms using chelated copper sulfate application followed by potassium permanganate application have all been chosen as management techniques for improving water quality conditions in the lake. These in-lake techniques are considered not as palliative measures, but as necessary tools in enhancing the lake's water quality characteristics.     

Synergy of adsorption and advanced oxidation processes in recalcitrant wastewater treatment

Environmental Chemistry Letters - The presence of recalcitrant organic pollutants in water is a major source of concern worldwide. These pollutants are not easily removed using conventional...     

Effect of Slash-and-Burn Shifting Cultivation on Rainforest Birds in Mizoram, Northeast India

Abstract: Slash-and-burn shifting cultivation, or jhum , the predominant form of agriculture in the hill tracts of northeast India, is believed to have caused considerable loss of forest cover in the species-rich tropical rainforests of the region. In this study I sought to understand how rainforest bird communities are affected by shifting cultivation in Mizoram State. I studied bird occurrence and abundance patterns in secondary successional and mature tropical rainforests in a shifting-cultivation habitat mosaic in Dampa Tiger Reserve. To compare replicate sites in fallows aged 1, 5, 10, 25, and 100 years with undisturbed primary forest, I used systematic strip-transect sampling over the winter and early summer ( breeding) seasons during 1994–1995. Many forest bird species, especially those with ranges restricted to northeast India, declined in abundance or disappeared in successional fallows that had regenerated for ≤10 years. Birds that colonized or increased in abundance in regrowth habitats were mainly common and widespread species of open-country and secondary-forest habitats, and of low importance for conservation. Primary forest was the main habitat for specialized forest birds, intrinsically rare species, and elevational migrants. Although protection and conservation of relatively undisturbed mature forests is imperative in the core area of the reserve, management in the buffer zone for long-rotation shifting cultivation (>10-year cycles) instead of plantation of monocultures may be important until alternate means of livelihood are available to cultivators.     

Functional nonredundancy of elephants in a disturbed tropical forest

Conservation efforts are often motivated by the threat of global extinction. Yet if conservationists had more information suggesting that extirpation of individual species could lead to undesirable ecological effects, they might more frequently attempt to protect or restore such species across their ranges even if they were not globally endangered. Scientists have seldom measured or quantitatively predicted the functional consequences of species loss, even for large, extinction‐prone species that theory suggests should be functionally unique. We measured the contribution of Asian elephants (Elephas maximus) to the dispersal of 3 large‐fruited species in a disturbed tropical moist forest and predicted the extent to which alternative dispersers could compensate for elephants in their absence. We created an empirical probability model with data on frugivory and seed dispersal from Buxa Tiger Reserve, India. These data were used to estimate the proportion of seeds consumed by elephants and other frugivores that survive handling and density‐dependent processes (Janzen‐Connell effects and conspecific intradung competition) and germinate. Without compensation, the number of seeds dispersed and surviving density‐dependent effects decreased 26% (Artocarpus chaplasha), 42% (Careya arborea), and 72% (Dillenia indica) when elephants were absent from the ecosystem. Compensatory fruit removal by other animals substantially ameliorated these losses. For instance, reductions in successful dispersal of D. indica were as low as 23% when gaur (Bos gaurus) persisted, but median dispersal distance still declined from 30% (C. arborea) to 90% (A. chaplasha) without elephants. Our results support the theory that the largest animal species in an ecosystem have nonredundant ecological functionality and that their extirpation is likely to lead to the deterioration of ecosystem processes such as seed dispersal. This effect is likely accentuated by the overall defaunation of many tropical systems.     

Annual and seasonal variability of ambient aerosols over an urban region in western India

Annual and seasonal variabilities in source contribution to total suspended particles (TSP) measured over an urban location in western India, Ahmedabad between May 2000 and January 2003 are examined in this study. Positive matrix factorization (PMF) resolved six factors including airborne regional dust, calcium carbonate rich dust, biomass burning/vehicular emissions, secondary nitrate/sulfate, marine aerosol, and smelter. In this study, non-parametric statistical tests including the Kruskal–Wallis analysis of variance (K–W ANOVA) and Spearman rank correlation (ρ) test were used to assess the annual and seasonal variations in factor contributions, and the influence of meteorology on these contributions, respectively. None of the factor contributions exhibited annual variations except airborne regional dust, and biomass burning/vehicular emissions factors. All of the factors exhibited seasonal variations. Several factor monsoon (July–September) median concentrations were significantly different from one or more of the other season medians. In general, it appeared that meteorological factors played a role in establishing the seasonal behavior of factor contributions. Factor contributions exhibited low to moderate correlations with meteorological parameters such as temperature, relative humidity, wind direction, and wind speed. Amongst all of the relationships, marine aerosol factor was reasonably well correlated with relative humidity (ρ = 0.73) and wind direction (ρ = 0.73) during the pre-monsoon season (March–May). This observation suggests that the aerosol transported by moisture laden winds from the Arabian sea contribute to this factor. The airborne regional dust factor was also moderately correlated with wind speed (ρ = 0.70) during the post-monsoon season. This relationship indicates that high regional dust concentrations are favored by high wind speeds and the resultant increase in dispersion.     

A design for the additive manufacture of functionally graded porous structures with tailored mechanical properties for biomedical applications

CAD/CAM-based layered manufacturing and additive manufacturing techniques of metals have found applications in near-net-shape fabrication of complex shaped parts with tailored mechanical properties for several applications. Especially with the onset of newer processes such as electron beam melting (EBM) and direct metal laser sintering (DMLS), revolutionary advances may be achieved in material substitution in the medical implant industry. These processes must be suitably developed and tested for the production of medical grade substitutions. In this article, we discuss a design process for creating periodic cellular structures specifically targeted for biomedical applications. Electron beam melting is used to fabricate the parts. Evaluation of the mechanical properties is performed and compared with design parameters. Compression tests of the samples show effective stiffness values ranging from 0.57 (±0.05) to 2.92 (±0.17) GPa and compressive strength values of 7.28 (±0.93) to 163.02 (±11.98) MPa. Substituting these values for simulation of biomechanical performance of patient-specific implants illustrates the compatibility and matched functional performance characteristics of highly porous parts at a safety factor of 5 and an effective reduction in weight. These developments are unique for the construction of maxillofacial and craniofacial implants. The novel design strategy also lends itself very well to metal additive manufacturing technologies. Implants designed and fabricated with this design strategy and manufacturing process would have mechanical properties equivalent to the part they replace and restore better function and esthetics as against the currently used methods of reconstruction. Suitable examples of a titanium porous cranioplasty plate and a sandwich structure are illustrated.