Solvophobic approach for predicting sorption of hydrophobic organic chemicals on synthetic sorbents and soils

The application of a solvophobic approach for predicting the sorption of hydrophobic organic compounds (HOC) was evaluated with data collected using synthetic sorbents and soils. The experimental data consisted of batch equilibrium sorption coefficients (K_D), as well as soil-TLC and reversed-phase liquid chromatographic (RPLC) retention factors (κ′). All data were collected using aqueous solutions and binary or ternary solvent mixtures of water, methanol, acetone, and acetonitrile. As predicted by the theory, the chromatographic retention factors and sorption coefficients for HOC decreased log-linearly with increasing fraction of organic cosolvent in binary solvents. Model parameters estimated from the binary solvent data could be used to predict sorption (or retention) from ternary solvents. Reasonable agreement was found between model parameters reported in the literature and those estimated using the data from batch sorption, soil-TLC, and RPLC studies.     

An improved product-process for cleaner chrome tanning in leather processing

Severe restrictions imposed by the pollution control authorities on the disposal of chromium, total dissolved solids and chlorides in tannery effluents have forced the tanners to look for low-waste, high exhaust chrome tanning salts. An improved chrome syntan with more than 90% uptake of chrome has been developed. The new product serves both as tanning and retanning agent and can be applied directly to delimed pelts thus eliminating the conventional pickling stage in the leather processing. This modified process helps to reduce the chemical oxygen demand (COD), total dissolved solids (TDS) and chlorides in the spent tan liquor by 51, 81 and 99%, respectively. The product offers full, soft leathers having shrinkage temperature comparable to conventional chrome tanned skins. Since the developed product is highly reactive, it saves time and reduces the water requirement when compared to the conventional chrome tanning method. Thus the novel product/process developed not only has advantages in reducing pollution loads but also seems to be techno-economically viable.     

The effects of application of phosphatic fertilizer on cadmium concentration in ground waters around vineyards of Hyderabad

Cadmium is an important contaminant of superphosphate. Market samples of superphosphate revealed a concentration of cadmium in the range of 18.2–28.5 mg/kg. Application of periodic excess doses of superphosphate in vineyards 5–35 years old has led to elevated concentrations of cadmium in the ground water in the vineyards. Ground water samples from different vineyards analysed for cadmium by atomic absorption spectrophotometry revealed concentrations of cadmium in the range of 3.2–99.2 µg/I. These concentrations of cadmium in the ground water can be regarded as significant, since ground water serves as the only source of water for the vineyards.     

Simple and sensitive spectrophotometric determination of ziram, zineb and ferbam in commercial samples and foodstuffs using phenylfluorone

A procedure has been developed for the determination of ziram, zineb and ferbam dithiocarbamate pesticides by converting ziram and zineb into a zinc-phenylfluorone complex and ferbam into an iron phenylfluorone complex, which are then dissolved in water in the presence of cetylpyridinium bromide and pyridine as a surfactant. The method is sensitive, highly selective and can be used for the determination of ziram, zineb and ferbam in commercial samples and in foodstuffs.     

River evaluation using ecotoxicological and microbiological procedures

One of the many problems researchers and managers face is to try and interpret data collected from various river studies. There is an underlying awareness of the incompleteness of most data bases due to a variety of problems outside of those concerning sample processing.In this study we have attempted, by using the battery of tests approach (12 tests) and the examination of different types of samples such as water, Milli-Q water extracted sediments, and organic solvent extracted sediments, to explore the implication of spacial and temporal sampling programmes.The results obtained were not unexpected: there were spatial and temporal influences, sometimes so great that it would appear that you were examining samples from different parts of the country. However, data arising from solvent extracted sediments were found to be much less influenced by temporal sampling than by spatial variation. Another interesting and important observation was that sediment composition appeared to have no relationship to toxicant content.In this study, the first field application of the Mutatox test (genotoxicity) was carried out and it was found to be a very responsive test in all three types of samples. This test shows great promise as laboratory studies indicate it is sensitive to many of the chemicals which trigger the Ames test.     

Watershed development in India. 2. New approaches for managing externalities and meeting sustainability requirements

This paper recognises the need for a revision of watershed development policy in India in relation to the planning of development interventions involving agricultural intensification and rainwater harvesting and the need for new approaches to assist the planning process. Building on, and using as an example, the results of biophysical and societal impact studies carried out on two watershed development projects in Karnataka three new management/dissemination tools, are suggested. These are (1) the web-based geographical information systems exploratory, climate land assessment and impact management tool dissemination tool for disseminating to policymakers and non-specialist stakeholders the downstream impacts of watershed interventions, (2) the ‘quadrant’ approach for ensuring that sustainability criteria are met and (3) Bayesian networks to investigate the biophysical and societal impacts of interventions. Readers should send their comments on this paper to BhaskarNath@aol.com within 3 months of publication of this issue     

Report: Hospital waste management--awareness and practices: a study of three states in India.

The study was conducted in Andhra Pradesh, Maharashtra and Uttar Pradesh in India. Hospitals/nursing homes and private medical practitioners in urban as well as rural areas and those from the private as well as the government sector were covered. Information on (a) awareness of bio-medical waste management rules, (b) training undertaken and (c) practices with respect to segregation, use of colour coding, sharps management, access to common waste management facilities and disposal was collected. Awareness of Bio-medical Waste Management Rules was better among hospital staff in comparison with private medical practitioners and awareness was marginally higher among those in urban areas in comparison with those in rural areas. Training gained momentum only after the dead-line for compliance was over. Segregation and use of colour codes revealed gaps, which need correction. About 70% of the healthcare facilities used a needle cutter/destroyer for sharps management. Access to Common Waste Management facilities was low at about 35%. Dumping biomedical waste on the roads outside the hospital is still prevalent and access to Common Waste facilities is still limited. Surveillance, monitoring and penal machinery was found to be deficient and these require strengthening to improve compliance with the Bio-medical Waste Management Rules and to safeguard the health of employees, patients and communities.     

Fuelwood assessment at micro-watershed level in Northeast Himalaya: a case study in Manipur,India

Fuelwood is one of the major sources of energy in the domestic sector across the rural areas, especially in the developing regions across the world. The Northeastern Himalayan state of Manipur is dominated by the tribal population that largely depends on fuelwood from the nearby forest area. The entire dependence on forests for energy resources is affecting the sustainability of the forest ecosystem in the region, thus indicating the livelihood conditions. Since land-use land-cover change is the key driver to the change in resource availability of a region, the present study has tried to analyze the land-cover changes over a period 28 years. The second major component affecting resource availability is the increasing population pressure that leads to changes in the land dynamics, which directly affect the resource production. Based on the existing consumption pattern, the total consumption of fuelwood in the watershed ranges from a minimum of 289.992 tons/year to a maximum of 3545.719 tons/year with an average of 1561.956 tons/year in the year 2009 and simulated fuelwood consumption for the year 2021 is around 1469.260 tons/year. Nine different probable scenarios of resource are proposed to calculate the stress value that can be used by the policy-makers and planners for suitable policy implementation at the micro level with a complex social system.