POLLUTIONAL ASPECTS OF PESTICIDES IN NATURAL STREAMS

The extensive use of synthetic organic pesticides in this country during the past twenty-five years has resulted in widespread pollution of our water resources. An obvious detrimental effect of such pollution has been observed in the numerous fish kills that have occurred. The most widely used pesticides, and the ones that have been implicated in the vast majority of the pollutional episodes, are the chlorinated hydrocarbon insecticides. These compounds, generally speaking, have almost no solubility in water, are subject to very slow microbial degradation if any at all, and are so resistent to natural degradation forces they can persist almost indefinitely in aqueous environments; characteristics that are all detrimental from a stream pollution standpoint. In addition, studies have shown that, as a group, the chlorinated hydrocarbons are more toxic to higher forms of aquatic life than other chemicals widely used for pest control. Because of these undesirable characteristics, present trends are to discontinue using these highly toxic, persistent compounds for pest control in outdoor areas. Legislation banning the sale of DDT has been introduced. Similar legislation controlling the use of several of the chlorinated hydrocarbon pesticides is probably the most effective way to reduce pollution.     

Integrated Aquaculture in Subsaharan Africa

An incremental, farmer participatory approach to the development of sustainable aquaculture in integrated farming systems has been tested in Malawi. Average fish production rose from 900 to approximately 1500 kg ha^-1 as farms achieved increasing levels of integration. Integrated farms produce almost six times the cash generated by the typical Malawian smallholder. The integrated pond-vegetable garden generates almost three times the annual net income from the staple maize crop and the homestead combined. The ecological footprint of integrated aquaculture is approximately 4 m² per kg of fish produced compared to 170 m² for more intensive systems. The incremental approach offers the possibility of fostering substantial improvement in rural livelihoods among African smallholding farmers.     

Copper, zinc, and arsenic in soil surrounding Douglas-fir poles treated with ammoniacal copper zinc arsenate (ACZA)

The levels of copper, zinc, and arsenic in soil surrounding Douglas-fir [Pseudotsuga menziesii (Mirb.) Franco] utility poles treated with ammoniacal copper zinc arsenate (ACZA) were investigated at sites in Florida, Virginia, and New York. Copper levels were elevated near the poles and declined with both horizontal distance away from the pole and depth beneath the soil surface. Zinc levels were also elevated next to the poles, but the levels declined more slowly than did those of copper. Arsenic levels were elevated in soil immediately next to the poles but declined to near background levels farther away. The results indicate that metals can leach from ACZA-treated poles, but do not migrate far in the soil, and thus the levels decline sharply with distance from the poles.     

Stray field nuclear magnetic resonance of soil water: development of a new, large probe and preliminary results

Development, characterization, and preliminary results of a recent technique capable of local measurements of pore-size distribution by a spatially resolved low resolution nuclear magnetic resonance (NMR) technique are described. Potential environmental uses include studying the change in pore-size distribution caused by surface compaction, which influences surface runoff, and obtaining information on the physical state of non-aqueous compounds in porous materials, which should aid the selection of appropriate soil remediation methods. Stray field (STRAFI) imaging is an NMR technique that allows distortion-free imaging of materials with short NMR relaxation times. The sample is placed in the strong axial fringe field gradient of a superconducting NMR magnet. We report on a new, unique, large 5-cm-diameter STRAFI probe, and its use for three preliminary test cases: water in ceramics of known pore size, paraffin wax and oil in sandstone rock, and water in soil at different matric potentials. The imaging is confined to one dimension with a spatial resolution of the order of 100 microm for protons. The optimum position for imaging occurs at 2.62 T and a gradient of 12.1 T/m. Water relaxation decay curves can be measured at any position in the 8-cm-long sample. These curves are decomposed into a series of terms each corresponding to a different pore size. Preliminary results show continuum fits to decay curves for a soil drained to three different matric potentials. Such information will be useful for interpreting water retention curves and will lead to understanding of the behavior of fluids in the vadose zone.     

Salmonella typhimurium survival and viability is unaltered by suspended particles in freshwater

Rolling microcosm experiments were conducted to determine whether suspended particles affect the survival and viability of a model pathogen, Salmonella choleraesuis, serotype typhimurium (American Type Culture Collection no. 23567), in a freshwater microbial community. Water from the Duluth, MN harbor of Lake Superior (including native microorganisms) was inoculated with clay, silt, or flocculent organic particles in a range of concentrations and a streptomycin-resistant strain of S. typhimurium. Microcosms (incubated at 20 degrees C) were rolled horizontally (3 rpm) and sampled periodically for total bacteria and total, viable, and culturable S. typhimurium. Total S. typhimurium abundance decreased rapidly in all experiments (8.5-73.1% d-1). Total bacteria did not decrease as rapidly as the S. typhimurium population in any experiment, suggesting that a microcosm effect was not responsible for the decline in S. typhimurium populations. Loss rates of attached and free cells were similar, indicating that attachment to particles did not enhance the persistence of Salmonella cells beyond our minimum detectable differences. After eight days, only 0.1 to 11.9% of the initial S. typhimurium inocula were detected by direct counts. Suspended particles had a minimal effect on the survival and viability of S. typhimurium; the losses of total, viable, or culturable Salmonella were generally the same across particle treatments and concentrations. Silt and flocculent particles affected loss rates of total and viable S. typhimurium similarly to inorganic particles (clay). It appears unlikely that suspended particles would provide a means for S. typhimurium to persist at hazardous levels in freshwater.     

Multinuclear magnetic resonance analysis of two humic acid fractions from lowland rice soils

To determine the effects of intensive cropping of tropical lowland rice (Oryza sativa L.) and the associated long-term soil submergence on chemical properties of soil organic matter, we used solid-state 13C and 15N and solution 31P nuclear magnetic resonance (NMR) spectroscopy to analyze the labile mobile humic acid (MHA) and the more recalcitrant calcium humate (CaHA) fractions extracted from a series of soils supporting several long-term field experiments in the Philippines. The soils varied mainly in degree of submergence and cropping intensity, ranging from a rainfed rice field without soil submergence to irrigated double- and triple-cropped fields in which soil remains submerged almost all year long. As reported previously, all analyses associated increasing intensity of rice cropping with larger proportions of less humified material in the MHA and CaHA, such as diester phosphorus (P), amide nitrogen (N), and phenolic carbon (C). We established significant correlations between proportions of various spectral areas as well as between some spectral areas and other humic acid (HA) properties such as visible light absorption and free radical concentration (positive indices of humification) and hydrogen (H) concentration (negative index of humification). For example, spectral proportions of heterocyclic N were positively, and proportions of amide N and phenolic C negatively, correlated with visible light absorption and free radical concentration, and each of these spectral proportions had an opposite sign when correlated with H concentration. The correlations of N-alkyl C proportions were the strongest with these properties and with other functional group proportions.     

FARMERS' ATTITUDES TOWARD NONPOINT POLLUTION CONTROL AND PARTICIPATION IN COST-SHARE PROGRAMS1

The success of government programs to control nonpoint source pollution depends upon attitudes toward those programs and the availability of technical and financial assistance. Applicants for the Rural Clean Water Program cost-share funding in Virginia possess different personal and operational characteristics than do nonapplicants. Factors associated with participation in the Rural Clean Water Program differed from those associated with the more traditional soil conservation programs. Discriminant analysis was used to differentiate between other farmers who may become applicants and nonapplicants. Farmers' attitudes toward various policy options for inducing implementation of nonpoint source management practices varied greatly. Farmers were most favorable to cost sharing, low-interest loans and tax credits, and least favorable to a soil loss tax. They were either very favorably or very unfavorably inclined toward cross-compliance between pollution control and other agricultural programs.     

The effects of temperature on decomposition and allelopathic phytotoxicity of boneseed litter

Decomposition of plant litter is a fundamental process in ecosystem function, carbon and nutrient cycling and, by extension, climate change. This study aimed to investigate the role of temperature on the decomposition of water soluble phenolics(WSP), carbon and soil nutrients in conjunction with the phytotoxicity dynamics of Chrysanthemoides monilifera subsp. monilifera(boneseed) litter. Treatments consisted of three factors including decomposition materials(litter alone, litter with soil and soil alone), decomposition periods and temperatures(5–15, 15–25and 25–35°C(night/day)). Leachates were collected on 0, 5, 10, 20, 40 and 60 th days to analyse physico-chemical parameters and phytotoxicity. Water soluble phenolics and dissolved organic carbon(DOC) increased with increasing temperature while nutrients like SO-24 and NO-13 decreased. Speed of germination, hypocotyl and radical length and weight of Lactuca sativa exposed to leachates were decreased with increasing decomposition temperature. All treatment components had significant effects on these parameters. There had a strong correlation between DOC and WSP, and WSP content of the leachates with radical length of test species. This study identified complex interactivity among temperature, WSP, DOC and soil nutrient dynamics of litter occupied soil and that these factors work together to influence phytotoxicity.     

Aggregating high-priority landscape areas to the parcel level: an easement implementation tool

Landscape characteristics and parcel ownership information are often collected on different spatial scales leading to difficulties in implementing land use plans at the parcel level. This study provides a method for aggregating highly resolute landscape planning information to the parcel level. Our parcel prioritization model directly incorporates a Land Trust's conservation goals in the form of a compromise programming model. We then demonstrate the use of our approach for implementation decisions, including parcel selection under a budget constraint and the estimation of a total conservation budget necessary to meet specific conservation goals. We found that these cost constraints significantly alter the composition of the 'best' parcels for conservation and can also provide guidance for implementation. The model's results were integral to a local Land Trust's ability to further define and achieve their goals.