全文获取类型
收费全文 | 1658篇 |
免费 | 109篇 |
国内免费 | 679篇 |
专业分类
安全科学 | 97篇 |
废物处理 | 124篇 |
环保管理 | 125篇 |
综合类 | 927篇 |
基础理论 | 331篇 |
污染及防治 | 645篇 |
评价与监测 | 87篇 |
社会与环境 | 51篇 |
灾害及防治 | 59篇 |
出版年
2024年 | 3篇 |
2023年 | 19篇 |
2022年 | 75篇 |
2021年 | 68篇 |
2020年 | 65篇 |
2019年 | 64篇 |
2018年 | 69篇 |
2017年 | 91篇 |
2016年 | 71篇 |
2015年 | 124篇 |
2014年 | 146篇 |
2013年 | 178篇 |
2012年 | 169篇 |
2011年 | 158篇 |
2010年 | 120篇 |
2009年 | 104篇 |
2008年 | 163篇 |
2007年 | 108篇 |
2006年 | 91篇 |
2005年 | 65篇 |
2004年 | 60篇 |
2003年 | 66篇 |
2002年 | 55篇 |
2001年 | 42篇 |
2000年 | 38篇 |
1999年 | 45篇 |
1998年 | 32篇 |
1997年 | 26篇 |
1996年 | 29篇 |
1995年 | 20篇 |
1994年 | 13篇 |
1993年 | 17篇 |
1992年 | 16篇 |
1991年 | 11篇 |
1990年 | 5篇 |
1989年 | 2篇 |
1988年 | 5篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1983年 | 3篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1977年 | 1篇 |
1956年 | 1篇 |
排序方式: 共有2446条查询结果,搜索用时 15 毫秒
101.
Potential particulate pollution derived from UV-induced degradation of
odorous dimethyl sulfide 总被引:1,自引:0,他引:1
UV-induced degradation of odorous dimethyl sulfide (DMS) was carried out in a static White cell chamber with UV irradiation. The
combination of in situ Fourier transform infrared (FT-IR) spectrometer, gas chromatograph-mass spectrometer (GC-MS), wide-range
particle spectrometer (WPS) technique, filter sampling and ion chromatographic (IC) analysis was used to monitor the gaseous and
potential particulate products. During 240 min of UV irradiation, the degradation e ciency of DMS attained 20.9%, and partially
oxidized sulfur-containing gaseous products, such as sulfur dioxide (SO2), carbonyl sulfide (OCS), dimethyl sulfoxide (DMSO),
dimethyl sulfone (DMSO2) and dimethyl disulfide (DMDS) were identified by in situ FT-IR and GC-MS analysis, respectively.
Accompanying with the oxidation of DMS, suspended particles were directly detected to be formed by WPS techniques. These
particles were measured mainly in the size range of accumulation mode, and increased their count median diameter throughout
the whole removal process. IC analysis of the filter samples revealed that methanesulfonic acid (MSA), sulfuric acid (H2SO4) and
other unidentified chemicals accounted for the major non-refractory compositions of these particles. Based on products analysis and
possible intermediates formed, the degradation pathways of DMS were proposed as the combination of the O(1D)- and the OH- initiated
oxidation mechanisms. A plausible formation mechanism of the suspended particles was also analyzed. It is concluded that UV-induced
degradation of odorous DMS is potentially a source of particulate pollutants in the atmosphere. 相似文献
102.
The aim of the present work was to produce a polyaluminium ferric silicate chloride (PAFSiC) coagulant from acidic and alkaline
wastewater of purifying graphite by roasting, and subsequently to evaluate coagulation efficiency of the reagent by treating surface
water from the Yellow River as well as municipal wastewater in comparison with the conventional coagulant polyaluminium chloride
(PAC). The PAFSiC coagulant was prepared by co-polymerization. The effects of (Al+Fe)/Si molar ratio, OH/(Al+Fe) molar ratio (i.e.,
value), coagulant dosage and pH value of test suspension on the coagulation behavior of FAFSiC and the stability of the PAFSiC were
also examined. Results showed that PAFSiC performed more efficiently than PAC in removing turbidity, chemical oxygen demand
(COD), and total phosphate (TP). The PAFSiC with a
value of 2.0 and (Al+Fe)/Si ratio of 5 (PAFSiC 2.0/5) showed excellent
coagulation effect for both turbidity and COD, while PAFSiC 1.0/5 was the best for TP. The optimum coagulation pH range of PAFSiC
2.0/5 was 5.0–9.0, slightly wider than that of PAC (6.0–8.0). The process can be easily incorporated into high-purity graphite production
plants, thereby reducing wastewater pollution and producing a valuable coagulant. 相似文献
103.
Tao Zhang Qiucheng Li Lili Ding Hongqiang Ren Ke Xu Yonggang Wu Dong Sheng 《环境科学学报(英文版)》2011,23(6):881-890
Chemical precipitation to form magnesium ammonium phosphate (MAP) is an effective technology for recovering ammonium
nitrogen (NH4
+-N). In the present research, we investigated the thermodynamic modeling of the PHREEQC program for NH4
+-N
recovery to evaluate the effect of reaction factors on MAP precipitation. The case study of NH4
+-N recovery from coking wastewater
was conducted to provide a comparison. Response surface methodology (RSM) was applied to assist in understanding the relative
significance of reaction factors and the interactive effects of solution conditions. Thermodynamic modeling indicated that the saturation
index (SI) of MAP followed a polynomial function of pH. The SI of MAP increased logarithmically with the Mg2+/NH4
+ molar ratio
(Mg/N) and the initial NH4
+-N concentration (CN), respectively, while it decreased with an increase in Ca2+/NH4
+ and CO3
2??/NH4
+
molar ratios (Ca/N and CO3
2??/N), respectively. The trends for NH4
+-N removal at different pH and Mg/N levels were similar to the
thermodynamic modeling predictions. The RSM analysis indicated that the factors including pH, Mg/N, CN, Ca/N, (Mg/N) (CO3
2??/N),
(pH)2, (Mg/N)2, and (CN)2 were significant. Response surface plots were useful for understanding the interaction effects on NH4
+-N
recovery. 相似文献
104.
105.
106.
107.
The brominated products, formed in chlorination treatment of benzophenone-4 in the presence of bromide ions, were identified, and the formation pathways were proposed.Under disinfection conditions, benzophenone-4 would undertake electrophilic substitution generating mono- or di-halogenated products, which would be oxidized to esters and further hydrolyzed to phenol derivatives. The generated catechol intermediate would be transformed into furan-like heterocyclic product. The product species were p H-dependent,while benzophenone-4 elimination was chlorine dose-dependent. When the chlorination treatment was performed on ambient water spiked with benzophenone-4 and bromide ions, most of brominated byproducts could be detected, and the acute toxicity significantly increased as well. 相似文献
108.
Qinqin Lou Yinfeng Zhang Dongkai Ren Haiming Xu Yaxian Zhao Zhanfen Qin Wuji Wei 《环境科学学报(英文版)》2014,26(10):2084-2094
Considering some advantages of Rana nigromaculata as an experimental species, we propose that this species, like Xenopus laevis, could be used to assay thyroid hormone(TH) signaling disrupting actions. To validate the utilizability of R. nigromaculata, we investigated the responsiveness of R. nigromaculata to a TH receptor(TR) agonist(T3) and antagonist(amiodarone) by analyzing expression, based on characterizing TR cDNA and developmental expression patterns. With high levels of identity with the corresponding genes in X. laevis, both TRα and TRβ in R. nigromaculata exhibited roughly similar developmental expression patterns to those of X. laevis, in spite of some species-specific differences. Both TRα and TRβ expression had greater changes in the liver and intestine than in the tail and brain during metamorphosis. T3 exposure for 2 days induced more dramatic increases of TRβ expression in stage 27 than in stage34 tadpoles but not in stage 42 tadpoles, showing that the responsiveness of R. nigromaculata to TH decreased with development and disappeared at the onset of metamorphic climax.Corresponding to greater changes of TRβ expression in the liver and intestine than in the tail and brain during metamorphosis, the liver and intestine had higher responsiveness to exogenous T3 than the tail and brain. Amiodarone inhibited T3-induced TRβ expression. Our results show that R. nigromaculata can be used as a model species for assaying TH signaling disrupting actions by analyzing TRβ expression, and intestine tissues at stage 27 are ideal test materials due to high responsiveness and easy accessibility. 相似文献
109.
Higher concentrations of Hg can be emitted from coal pyrolysis or gasification than from coal combustion, especially elemental Hg. Highly efficient Hg removal technology from coal-derived fuel gas is thus of great importance. Based on the very excellent Hg removal ability of Pd and the high adsorption abilities of activated carbon(AC) for H2 S and Hg, a series of Pd/AC sorbents was prepared by using pore volume impregnation, and their performance in capturing Hg and H2 S from coal-derived fuel gas was investigated using a laboratory-scale fixed-bed reactor. The effects of loading amount, reaction temperature and reaction atmosphere on Hg removal from coal-derived fuel gas were studied. The sorbents were characterized by N2 adsorption, X-ray diffraction(XRD) and X-ray photoelectron spectroscopy(XPS). The results indicated that the efficiency of Hg removal increased with the increasing of Pd loading amount, but the effective utilization rate of the active component Pd decreased significantly at the same time. High temperature had a negative influence on the Hg removal. The efficiency of Hg removal in the N2-H2S-H2-CO-Hg atmosphere(simulated coal gas) was higher than that in N2-H2S-Hg and N2-Hg atmospheres, which showed that H2 and CO, with their reducing capacity, could benefit promote the removal of Hg. The XPS results suggested that there were two different ways of capturing Hg over sorbents in N2-H2S-Hg and N2-Hg atmospheres. 相似文献
110.
于丽萍 《安全.健康和环境》2014,14(1):21-23,33
介绍了一种基于海洋移动式平台应用的安全信息预警与保护装置的研制,实现具有移动式平台海上安全信息采集、记录、预警、保护及再现等功能。 相似文献