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251.
文章从信息收集、环境危害评价、环境影响控制、应急恢复、HSE例卷管理等方面,分析了壳牌公司环境评价的概念和应用领域,总结了壳牌公司环境管理的经验,并据此提出了改进我国石油石化企业环境管理的若干建议。 相似文献
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255.
运用遥感动态监测与地理信息系统技术相结合的方法,以2005年和2009年遥感解译数据、土地侵蚀数据及环境统计数据为数据源,依据《生态环境状况评价技术规范(试行)》(HJ/T192-2006),对山东省17个城市生态环境质量现状及动态变化趋势进行了评价。结果表明:2009年17个城市生态环境状况指数在59.81~78.08之间,生态环境质量状况总体良好;2005-2009年17城市生态环境状况指数变化值在0.06~3.5之间,生态环境质量状况基本稳定。 相似文献
256.
Effect of humic acids on physicochemical property and Cd(II) sorption of multiwalled carbon nanotubes 总被引:1,自引:0,他引:1
Zinc pyrithione is used as an antifouling agent. However, the environmental impacts of zinc pyrithione have recently been of concern. Zinc induces diverse actions during oxidative stress; therefore, we examined the effect of zinc pyrithione on rat thymocytes suffering from oxidative stress using appropriate fluorescent probes. The cytotoxicity of zinc pyrithione was not observed when the cells were incubated with 3 μM zinc pyrithione for 3 h. However, zinc pyrithione at nanomolar concentrations (10 nM or more) significantly increased the lethality of cells suffering from oxidative stress induced by 3 mM H2O2. The application of zinc pyrithione alone at nanomolar concentrations increased intracellular Zn2+ level and the cellular content of superoxide anions, and decreased the cellular content of nonprotein thiols. The simultaneous application of nanomolar zinc pyrithione and micromolar H2O2 synergistically increased the intracellular Zn2+ level. Therefore, zinc pyrithione at nanomolar concentrations may exert severe cytotoxic action on cells simultaneously exposed to chemicals that induce oxidative stress. If so, zinc pyrithione leaked from antifouling materials into surrounding environments would be a risk factor for aquatic ecosystems. Alternatively, zinc pyrithione under conditions of oxidative stress may become more potent antifouling ingredient. 相似文献
257.
The initial degradation mechanisms of OH and 4-chloro-2-methylphenoxyacetic acid (MCPA) including molecular form and anionic form are studied at the MPWB1K/6-311+G(3df, 2p)//MPWB1K/6-31+G(d, p) level. Possible reaction pathways of H-atom abstraction and OH addition are considered in detail. By result comparison analysis, it is found that the reaction mechanisms for OH and two forms of MCPA are different, and most reactions for anionic MCPA are easier than those for molecular MCPA. For H-atom abstraction reactions, the calculated energies show that OH abstracting H-atom from -CH3 group of molecular MCPA is the most kinetically favorable process; the potential energy surface for anionic MCPA indicates that H-atom in -CH2 group is slightly easier to be abstracted than that in -CH3 group. For OH addition reactions, the addition of OH to the C1 site is the initial step for molecular MCPA and the predominant product is 4-chloro-2-methylphenol (denoted P3), while the C4 site is the most reactive site for anionic MCPA and the primary product results from the hydroxylation of the aromatic ring, which is in good agreement with the experimental observation. In additional, results from PCM calculations show that most reactions in water phase are more kinetically favorable than those in gas phase, though the mechanisms discussed above will not be changed. 相似文献
258.
The present study employed ozonation process to treat the bamboo industry wastewater (BIWW). The impact of ozone dosage and initial organic concentration on color, COD and TOC removal rates were studied along with characterization of the major organics in raw and treated wastewater. The results suggested the ozone dosage of 3.15 g h−1 (concentration 52.5 mg L−1) was suitable for the treatment. After 25 min ozonation of 1 L raw wastewater, the color, COD and TOC removal efficiencies were 95%, 56% and 40%, respectively, with an influent COD concentration of 835 mg L−1. The ratio of kg O3 kg−1 COD at 3.15 g h−1 was 2.8 (<3), revealing that ozonation was a cost effective process for tertiary treatment of BIWW. Longer oxidization time was required to achieve similar results for raw wastewater with higher COD concentration. The chromatogram from gel permeation chromatography revealed that ozonation resulted in the breakdown of high molecular weight compounds into lower molecular weight components but could not completely mineralize the organic matter. The majority of these compounds were identified in both raw and ozonated samples via GC-MS analysis. In addition to ester derivatives as the main intermediates of ozonation, 1-chloroctadecane, methyl stearate, benzophenone and α-cyperone were identified as the by-products of ozonation. 相似文献
259.
Li X Zhou Q Wei S Ren W 《Environmental science and pollution research international》2012,19(5):1773-1780
Purpose
Screening out cadmium (Cd) excluding cultivars of a crop in agricultural production is an effective way to prohibit Cd entering into food chain.Methods
A judging criterion for Cd-excluding cultivars based on food safety was suggested and used in the identification of Cd-excluding welsh onion (Allium fistulosum L.) cultivars. A pot culture experiment was carried out to screen out Cd-excluding cultivars, of which the results were confirmed by plot experiments. The relevant factors of Cd accumulation in the pseudostem were analyzed and used in the correlation analysis aiming to study the low Cd accumulation mechanisms.Results
The concentration of Cd in the pseudostem of welsh onions was 0.08?C0.20, 0.18?C0.41, and 0.26?C0.61?mg/kg fresh weight (FW) under three treatments (1.0, 2.5, and 5.0?mg/kg), respectively. The significant (p?0.05) difference in the concentration of Cd in the pseudostem was observed among 25 welsh onion cultivars, but Cd contamination in soil had little influence on biomass and the contents of soluble sugar, NO 3 ? ?CN, and eight other elements in the tested welsh onion cultivars. Two cultivars were identified as Cd-excluding cultivars, mainly because the accumulation of Cd in their pseudostem was only 0.041?±?0.003 and 0.046?±?0.002?mg/kg FW, and 0.054?±?0.001 and 0.066?±?0.011?mg/kg FW, when growing in plots with Cd concentration of 0.49 and 0.99?mg/kg, respectively.Conclusions
Ribentiegancongwang and Wuyeqi could be identified as Cd-excluding cultivars. Low bioaccumulation factor of the roots was the main mechanism of Cd-excluding welsh onion cultivars. 相似文献260.
Lead tolerance and physiological adaptation mechanism in roots of accumulating and non-accumulating ecotypes of Sedum alfredii 总被引:1,自引:0,他引:1
Huang H Gupta DK Tian S Yang XE Li T 《Environmental science and pollution research international》2012,19(5):1640-1651