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221.
Joachim Tessmann Toralf Beitz Wolfgang Bechmann Rolf Mitzner 《Environmental Sciences Europe》1999,11(2):67-72
The azaarenes and the structurally analogous PAH accompany each other and occur ubiquitously in nature. Photochemical conversions like direct photolysis or the photoreaction with nitrate are important natural degradation reactions of azaarenes. Furthermore, photoreactions with chlorine and bromine radicals can be expected in nature. The reactions generate a large number of oxidized, nitrated and halogenated products with unknown toxicity. In this paper, a first screening of changes is reported in acute toxicity during the course of the photochemical reactions. As test system luminescent bacteria are used. For quinoline, isoquinoline and phthalazine the investigations show different changes of the toxicity of the reaction mixtures in dependence on the respective reaction type. The toxicity of the reaction mixtures of quinazoline and quinoxaline increases in all reactions investigated. Furthermore the reactions of bromine radicals with azaarenes also show an increase of the toxicity in all cases. Compared with the azaarenes in all reactions products with significantly higher toxicity are formed. 相似文献
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Thomas Hofer Hartmut Nies Stephan Gollasch Rolf von Ostrowski 《Environmental Sciences Europe》2007,19(4):219-225
Background and Scope
The marine shipping lanes have become the most important path for the invasion of foreign aquatic organisms. The increasing global trade results in an increase in the number of marine vessels. Without any protective measures, with every ship carrying foreign organisms the risk of biological invasions will rise.Results
The International Martime Organization (IMO) of the United Nations developed a convention to reduce the transfer of organisms with ballast water. After the entry-into-force of this convention the fleet of the world has to be equipped with effective ballast water management technology before 2016. This article discusses potential options for action. To comply with the limit values of the ballast water convention, the current state of the art demands the use of active substances. Any decision on the approval of active substances used for ballast water treatment and the environmental impact assessment lies with the IMO. Proposed to day are UV-radiation, active chlorine, active oxygen, the creation of biocides through electrolysis and a change in gases contained in the ballast water. The technologies and the potential risks are presented.Conclusions
Despite the introduction of an approval procedure by IMO any reliable assessment of the real risks involved in the use of biocides is impossible, as the risk assessment approaches have still to be developed. On the regulatory level, the main focus in data requirements for the risk assessment is on a comprehensive testing of the toxic potential of the biocides proposed. Strategies for the identification and evaluation of the chemical resulting from the treatment of limnic, marine and brackish water are not fully developed. An integrating assessment of risks involved in the introduction of foreign organisms versus the toxic effects of the substances used or created during treatment is still missing. 相似文献223.
Rolf W. Boehnke 《Natural resources forum》1990,14(4):328-330
The International Lead and Zinc Study Group was founded by the United Nations in 1959. There are 32 member countries which together cover over 90% of world production and consumption of total lead and zinc. The Study Group, inter alia provides opportunities for consultation on lead and zinc, provides information regarding supply and demand, collects and disseminates statistics, studies different aspects of the world situation in lead and zinc and considers possible solutions to any special problems. This paper presents excerpts of the activities of the International Lead and Zinc Study Group in each of the above areas. 相似文献
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Paul L.G. Vlek Gabriela Rodríguez-Kuhl Rolf Sommer 《Environment, Development and Sustainability》2004,6(1-2):213-233
Carbon dioxide emissions due to fossil fuel consumption are well recognized as a major contributor to climate change. In the debate on dealing with this threat, expectations are high that agriculture based economies of the developing world can help alleviate this problem. But, the contribution of agricultural operations to these emissions is fairly small. It is the clearing of native ecosystems for agricultural use in the tropics that is the largest non-fossil fuel source of CO2 input to the atmosphere. Our calculation show that the use of fossil energy and the concomitant emission of CO2 in the agricultural operational sector - i.e. the use of farm machinery, irrigation, fertilization and chemical pesticides - amounts to merely 3.9% of the commercial energy use in that part of the world. Of this, 70% is associated with the production and use of chemical fertilizers. In the absence of fertilizer use, the developing world would have converted even more land for cultivation, most of which is completely unsuitable for cultivation. Current expectations are that reforestation in these countries can sequester large quantities of carbon in order to mitigate excessive emissions elsewhere. But, any program that aims to set aside land for the purpose of sequestering carbon must do so without threatening food security in the region. The sole option to liberate the necessary land for carbon sequestration would be the intensification of agricultural production on some of the better lands by increased fertilizer inputs. As our calculations show, the sequestration of carbon far outweighs the emissions that are associated with the production of the extra fertilizer needed. Increasing the fertilizer use in the developing world (without China) by 20%, we calculated an overall net benefit in the carbon budget of between 80 and 206 Mt yr?1 dependent on the carbon sequestration rate assumed for the regrowing forest. In those regions, where current fertilizer use is low, the relative benefits are the highest as responding yield increases are highest and thus more land can be set aside without harming food security. In Sub-Saharan Africa a 20% fertilizer increase, which amounts to 0.14 Mt of extra fertilizer, can tie up somewhere between 8 and 19 Mt of CO2 per year (average: 96 t CO2 per 1 t fertilizer). In the Near East and North Africa with a 20%-increased fertilizer use of 0.4 Mt yr-1 between 10 and 24 Mt of CO2 could be sequestered on the land set aside (40 t CO2 per 1 t fertilizer). In South Asia this is 22–61 Mt CO2 yr?1 with an annual additional input of 2.15 Mt fertilizer (19 t CO2 per 1 t fertilizer). In fact, carbon credits may be the only way for some of the farmers in these regions to afford the costly inputs. Additionally, in regions with already relatively high fertilizer inputs such as in South Asia, an efficient use of the extra fertilizer must be warranted. Nevertheless, the net CO2 benefit through implementation of this measure in the developing world is insignificant compared to the worldwide CO2 output by human activity. Thus, reforestation is only one mitigating measure and not the solution to unconstrained fossil fuel CO2 emissions. Carbon emissions should, therefore, first of all be reduced by the avoidance of deforestation in the developing world and moreover by higher energy efficiency and the use of alternative energy sources. 相似文献
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