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231.
Fu-Sheng Liu Zhuo Li Shi-Tao Yu Xiao Cui Cong-Xia Xie Xiao-Ping Ge 《Journal of Polymers and the Environment》2009,17(3):208-211
Alkali-catalyzed methanolysis and hydrolysis of polycarbonate (PC) in a solvent in which PC can substantially dissolve such
as N-methyl-2-pyrrolidone, 1,4-dioxane, tetrahydrofuran and so on were studied. Reaction conditions were optimized for the purpose
of recycling PC in the form of bisphenol A and carbon carbonate. The results showed that both the methanolysis and hydrolysis
of PC could take place under moderate conditions. Under the conditions of reaction temperature 40 °C, m(PC):m(MeOH) = 1:1,
m(PC):m(NaOH) = 50:1, reaction time 35 min and using tetrahydrofuran as solvent, the methanolysis conversion of PC was almost
100% and the yield of bisphenol A was over 95%. Moreover, under the conditions of reaction temperature 100 °C, m(PC):m(H2O) = 1:0.7, m(PC):m(NaOH) = 10:1, reaction time 8 h and using 1,4-dioxane as solvent, the hydrolysis conversion of PC was
almost 100% and the yield of bisphenol A was over 94%. 相似文献
232.
Cascade-based attack vulnerability on the US power grid 总被引:5,自引:0,他引:5
The vulnerability of real-life networks subject to intentional attacks has been one of the outstanding challenges in the study of the network safety. Applying the real data of the US power grid, we compare the effects of two different attacks for the network robustness against cascading failures, i.e., removal by either the descending or ascending orders of the loads. Adopting the initial load of a node j to be Lj=[kj(ΣmΓjkm)]α with kj and Γj being the degree of the node j and the set of its neighboring nodes, respectively, where α is a tunable parameter and governs the strength of the initial load of a node, we investigate the response of the US power grid under two attacks during the cascading propagation. In the case of α<0.7, our investigation by the numerical simulations leads to a counterintuitive finding on the US power grid that the attack on the nodes with the lowest loads is more harmful than the attack on the ones with the highest loads. In addition, the almost same effect of two attacks in the case of α=0.7 may be useful in furthering studies on the control and defense of cascading failures in the US power grid. 相似文献
233.
234.
作者把气相色谱仪(GC)与自行研制的光离子化检测器(PID)联用,实现了大气中痕量烃类化合物的直接测定,给出了仪器的构成和性能指标及测量结果. 相似文献
235.
用Ames试验检测水源水和自来水中的遗传毒性 总被引:3,自引:0,他引:3
用微伤寒沙门氏菌/哺乳动物微粒体酶系的Amaes试验,研究了不同季节物水源水及管网自来水中的遗传毒性,以XAD2树脂为吸附剂,以丙酮-甲醇的混合液为洗脱液,浓率水样中的有机物,并对部分阳性水样进行有机成分的定性分析。结果发现:13个水样中有7个样品在淡需要代谢活化系统S9的情况下,可诱导鼠伤寒沙门氏菌碱基移码型菌株的回复突变;不同水样在不同季节不同的诱导作用;同时通过GC/MS方法分析,发现阳性水 相似文献
236.
过氯乙烯滤膜采样-酸消解-钼蓝光度法测定磷酸雾 总被引:1,自引:0,他引:1
建立了过氯乙烯滤膜采样 -酸消解 -钼蓝分光光度法测定磷化车间磷酸雾的监测方法。实验室模拟采样的捕集效率为 95 7%~ 99 1 %。单个实验室对含 5μg和 1 5μg样品进行多次测定 ,其相对标准差小于 5% ,样品加标回收率为 98 2 %~ 1 0 0 5% ,方法检测限为 0 0 0 7mg/m3。对标样测定 ,结果均在给定值范围内。用该法与等离子发射光谱法(ICP)对 5个样品进行比对测定 ,结果均令人满意。 相似文献
237.
对2种氰化物显色剂配制方法进行了对比,发现用无水乙醇配制的显色剂具有方便,经济,实用,无毒且显色剂保存期长等优势。 相似文献
238.
Ma YG Cheng JP Jiao F Duo KX Rong Z Li M Wang WH 《Environmental monitoring and assessment》2008,146(1-3):127-138
Distribution and risk assessment of polycyclic aromatic hydrocarbons (PAHs) in drinking water resources have been carried out for the first time in Henan Province, China. Water samples collected from four river systems and their tributaries, as well as groundwater resources, were analyzed according to EPA method 525.2. Total of 68 water samples were collected in 18 cities in Henan province in May, August and November, 2001. Concentrations of sum of 16 priority PAHs in water samples ranged from 15 to 844 ng/L with a mean value of 178 +/- 210 ng/L (n = 68). The spatial and temporal distribution of PAHs showed that the Huanghe and the Huaihe river systems had relatively higher concentrations of total PAHs. Higher concentrations of total PAHs were observed in August and November than in May, with respective mean values of 262, 232 and 33.6 ng/L. Ratios of Ant/(Ant + Phe) and Flur/(Flur + Pyr) were calculated to evaluate the possible sources of PAH contamination, which indicated that the coal combustion sources were the main contributors to PAHs in most drinking water resources. Some petrogenic (or pyrolytic) sources of PAHs were also found. The toxic equivalency factors (TEFs) were used to calculate benzo[a]pyrene equivalents (BaPE) for water samples. The average value of BaPE was 0.6 ng/L. The values in most stations were much lower than the guideline values in drinking water of Chinese Environmental Protection Agency (CEPA, 2.8 ng/L) and the US Environmental Protection Agency (US EPA, 200 ng/L). Overall, the drinking water resources in Henan province showed some carcinogenic potential. 相似文献
239.
秸秆焚烧对北京市空气质量的影响 总被引:38,自引:8,他引:30
用火焰原子吸收光谱法测试了北京市两个采样点 1 #站 (十三陵站 ,清洁对照点 )和 5#站 (天坛站 ,居民生活区 )1 1 0个大气颗粒物样品中的水溶性钾 ,以表征秸秆焚烧颗粒物。 1 #站水溶性钾的质量浓度年均值为 1 .2 1 μg/m3,其中以1 998年 6月份浓度 (3 .0 7μg/m3)最高 ,是 5月份 (1 .0 2μg/m3)的 3倍 ;5#站水溶性钾的质量浓度年均值为 1 .94μg/m3,6月份 (4 .2 2 μg/m3)最高 ,是 5月份 (1 .97μg/m3)的 2 .1倍。数据分析结果表明 1 998年 6月份麦收季节存在以秸秆焚烧为主的生物质燃烧现象 ,使大气颗粒物中有机碳浓度水平升高 ,并对北京市的空气质量带来负面影响 相似文献
240.