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191.
Carbamazepine (CBZ), caffeine and cetirizine were monitored by enzyme-linked immunosorbent assays (ELISAs) in surface and wastewaters from Berlin, Germany. This fast and cost-efficient method enabled to assess the spatial and temporal variation of these anthropogenic markers in a high-throughput screening. CBZ and cetirizine were detected by the same antibody, which selectively discriminates between both compounds depending on the pH value used in the incubation step. To our best knowledge, this is the first dual-analyte immunoassay working with a single antibody.The frequent sampling with 487 samples being processed allowed for the repeated detection of unusually high concentrations of CBZ and caffeine. ELISA results correlate well with the ones obtained by liquid chromatography tandem mass spectrometry (LC-MS/MS). Caffeine concentrations found in surface waters were elevated by combined sewer overflows after stormwater events. During the hay fever season, the concentrations of the antihistamine drug cetirizine increased in both surface and wastewaters.Caffeine was almost completely removed during wastewater treatment, while CBZ and cetirizine were found to be more persistent. The maximum concentrations of caffeine, CBZ and cetirizine found in influent wastewater by LC-MS/MS were 470, 5.0 and 0.49 μg L−1, while in effluent wastewater the concentrations were 0.22, 4.5 and 0.51 μg L−1, respectively. For surface waters, concentrations up to 3.3, 4.5 and 0.72 μg L−1 were found, respectively. 相似文献
192.
Effects of fifteen PBDE metabolites, DE71, DE79 and TBBPA on steroidogenesis in the H295R cell line 总被引:1,自引:0,他引:1
Song R He Y Murphy MB Yeung LW Yu RM Lam MH Lam PK Hecker M Giesy JP Wu RS Zhang W Sheng G Fu J 《Chemosphere》2008,71(10):1888-1894
Polybrominated diphenyl ethers (PBDEs) and tetrabromobisphenol A (TBBPA) are brominated flame retardants that are produced in large quantities and are commonly used in construction materials, textiles, and as polymers in electronic equipment. Environmental and human levels of PBDEs have been increasing in the past 30 years, but the toxicity of PBDEs is not fully understood. Studies on their effects are relatively limited, and show that PBDEs are neurotoxins and potential endocrine disrupters. Hydroxylated (OH) and methoxylated (MeO) PBDEs have also been reported in the adipose tissue, blood and milk of wild animals and humans. In the present study, 15 PBDE metabolites, two BDE mixtures (DE71 and DE79), and TBBPA were studied individually to determine their effects on ten steroidogenic genes, aromatase activity, and concentrations of two steroid hormones (testosterone and 17beta-estradiol) in the H295R human adrenocortical carcinoma cell line. Exposure to 0.05 microM 2'-OH-BDE-68 significantly induced the expression of CYP11A, CYP11B2, CYP17, CYP21, 3betaHSD2, 17betaHSD1, and 17betaHSD4, and the expression of StAR was induced by 6-OH-BDE-90 at the three exposure concentrations. Exposure to DE71 and DE79 resulted in dose-dependent trend towards induction, but these effects were not significant. Exposure to 0.5 microM 2-OH-BDE-123 and 2-MeO-BDE-123 resulted in significantly greater aromatase activity. However, none of the compounds affected sex hormone production at the concentrations tested. Generally, OH-BDEs had a much stronger ability to affect steroidogenic gene expression than MeO-BDEs. 相似文献
193.
Polycyclic aromatic hydrocarbons and their hydroxylated metabolites in fish bile and sediments from coastal waters of Colombia 总被引:3,自引:0,他引:3
Johnson-Restrepo B Olivero-Verbel J Lu S Guette-Fernández J Baldiris-Avila R O'Byrne-Hoyos I Aldous KM Addink R Kannan K 《Environmental pollution (Barking, Essex : 1987)》2008,151(3):452-459
Sediments and fish bile collected from the Atlantic coastal waters of Colombia were analyzed for 16 parent polycyclic aromatic hydrocarbons (PAHs), and 23 hydroxylated PAHs (OH-PAHs), respectively. Sediments contained overall mean SigmaPAH concentrations of 2090, 234 and 170 ng/g, dry wt, for Cartagena Bay, Caimanera Marsh, and Totumo Marsh, respectively. The mean concentration of the summed OH-PAHs in fish bile was 1250, 180 and 64.1 ng/g bile wt for Cartagena Bay, Caimanera Marsh, and Totumo Marsh, respectively. The results suggest that Cartagena Bay is heavily polluted by PAHs, and that exposure to high concentrations of PAHs together with other factors could contribute to the decreased health of fish living in this ecosystem. This is one of the first studies to describe the analysis of 23 individual OH-PAHs in fish bile, using authentic standards. 相似文献
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195.
Development of an enzyme-linked immunosorbent assay for atrazine monitoring in water samples 总被引:1,自引:0,他引:1
Diana L. D. Lima Rudolf J. Schneider Valdemar I. Esteves 《Environmental science and pollution research international》2013,20(5):3157-3164
The implementation of the Water Framework Directive (2000/60/EC) requires the establishment of monitoring programs. However, conventional procedures for sample preparation prior to chromatographic analysis are rather expensive and time consuming, being the development of cost-effective and easy tool a necessity. The aim of this work was to develop an enzyme-linked immunosorbent assay (ELISA) able to determine atrazine in water samples. Matrix effects evaluation showed that the increase of humic acid (HA) concentration leads to flattened calibration curves and to the loss of the sigmoidal shape. However, such interference was overcome, by the presence of an environmental sample buffer, incubated together with the samples. Recoveries from 88.5 to 119.2 % were obtained in the presence of HA concentrations up to 20 mg?L?1. An analytical range from 0.003 to 1 μg?L?1 was obtained, and atrazine was detected in a sewage treatment plant with concentrations ranging from 14 to 52 ng?L?1. 相似文献
196.
Stefan R. Falke Rudolf B. Husar Bret A. Schichtel 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1579-1585
ABSTRACT Spaceborne sensors allow near-continuous aerosol monitoring throughout the world. This paper illustrates the fusion of Sea-Viewing Wide Field-of-View Sensor (SeaWiFS) and TOMS satellite data with surface observations and topographic data during four extreme aerosol events: (1) the April 1998 Asian dust storm that impacted the west coast of North America, (2) the May 1998 Central American forest fire smoke that impacted eastern North America, (3) the intense fall 1999 northern California fires, and (4) the massive February 2000 Sahara dust storm. During these dust and smoke events, the aerosol was visualized on true color SeaWiFS images as a distinct yellowish dye, the result of the aerosol increasing the reflectance of darker surfaces (ocean and land) and decreasing the reflectance of clouds. TOMS imagery also indicated increased aerosol absorption in the affected areas, while surface monitors measured major reductions in visual range. Fusing these data aids in the determination of the aerosol's spatial, temporal, and optical properties and provides supporting evidence for characterizing what is being visualized as dust or smoke. A 3-dimensional perspective of the events is obtained when incorporating topographic data and provides insight into the vertical properties of the aerosol plumes. 相似文献
197.
Carbamazepine is a psychiatric pharmaceutical widely detected in aquatic environments. Due to its generalized occurrence and environmental persistence it might be considered as an anthropogenic pollution indicator. In this research, a previously developed enzyme-linked immunosorbent assay (ELISA), based on a commercial monoclonal antibody, was applied to the quantification of carbamazepine in ground, surface and wastewaters and results were validated by liquid chromatography-tandem mass spectrometry (LC-MS/MS).The performance of the applied ELISA methodology was tested in the presence of high concentrations of sodium chloride and dissolved organic matter. The method was not significantly affected by matrix effects, being adequate for the quantification of carbamazepine in environmental samples, even without sample pre-treatment. This method allows the quantification of carbamazepine in the range of 0.03-10 μg L−1, with a relative error lower than 30%. Due to a pH dependent cross-reactivity with cetirizine, an antihistaminic drug, the assay also enabled the quantification of cetirizine in the samples.The application of the developed method to the quantification of carbamazepine was performed by using environmental samples with very different matrices, collected in the geographical area of Ria de Aveiro, an estuarine system located in the North of Portugal. Carbamazepine was detected in all analyzed wastewater samples and in one surface water with concentrations between 0.1 and 0.7 μg L−1. Validation with LC-MS/MS revealed that results obtained by ELISA are 2-28% overestimated, which was considered highly satisfactory due to the absence of sample pre-treatments. 相似文献
198.
Iraj Emadodin Daiju Narita Hans Rudolf Bork 《Environment, Development and Sustainability》2012,14(5):611-625
During the past six decades, agriculture as a main sector in Iran’s economy has been affected by economic development, land-use policies, and population growth and its pressures. From the 1940s until 2010, the percentage of the total urban population of Iran increased from about 21?% to around 72?%. Urbanization, industrialization, and intensive cultivation have dramatically affected soil and water resources. The exploitation of groundwater has been increased around fourfold from the 1970s to the mid-2000s. Total water resources per capita reduced around 23?% from 1956 to 2008. The average annual decrease in the groundwater table in Iran during the last two decades is 0.51?m. In 2008, the groundwater table fell around ?1.14?m in average in Iran. The average use of chemical fertilizers increased from around 2.1?million tons in 1990s to about 3.7?million tons in 2009. During that period, fertilizer use efficiency decreased from around 28?% to around 21?%. Approximately 77?% of the agricultural land under irrigation suffers from different levels of salinity. According to the quantification of four indices, such as soil erosion, fall in groundwater levels, salinity, and use of chemical fertilizer, that are directly related to agricultural land use, the results show that agricultural management in Iran needs special attention to reach sustainable conditions. The total cost of soil and water degradation and use of fertilizers in agriculture are estimated around than US $12.8?billion (about 157,000?billion IRRials)—approximately 4?% of the total gross domestic product (GDP) and approximately 35?% of the GDP of the agricultural sector in Iran. 相似文献
199.
200.