全文获取类型
收费全文 | 4340篇 |
免费 | 500篇 |
国内免费 | 1489篇 |
专业分类
安全科学 | 586篇 |
废物处理 | 125篇 |
环保管理 | 352篇 |
综合类 | 3341篇 |
基础理论 | 643篇 |
污染及防治 | 493篇 |
评价与监测 | 329篇 |
社会与环境 | 265篇 |
灾害及防治 | 195篇 |
出版年
2024年 | 30篇 |
2023年 | 79篇 |
2022年 | 242篇 |
2021年 | 241篇 |
2020年 | 308篇 |
2019年 | 176篇 |
2018年 | 176篇 |
2017年 | 238篇 |
2016年 | 182篇 |
2015年 | 266篇 |
2014年 | 260篇 |
2013年 | 325篇 |
2012年 | 398篇 |
2011年 | 389篇 |
2010年 | 351篇 |
2009年 | 348篇 |
2008年 | 317篇 |
2007年 | 361篇 |
2006年 | 362篇 |
2005年 | 311篇 |
2004年 | 217篇 |
2003年 | 125篇 |
2002年 | 139篇 |
2001年 | 123篇 |
2000年 | 103篇 |
1999年 | 79篇 |
1998年 | 34篇 |
1997年 | 34篇 |
1996年 | 35篇 |
1995年 | 29篇 |
1994年 | 14篇 |
1993年 | 9篇 |
1992年 | 9篇 |
1991年 | 4篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1988年 | 6篇 |
1984年 | 1篇 |
1964年 | 1篇 |
排序方式: 共有6329条查询结果,搜索用时 187 毫秒
391.
通过对昆明市餐饮和居民生活污水厌氧模拟实验研究,初步探讨生活污水中CH4的产生规律,实验结果表明,在自然条件下,餐饮和居民生活污水中产生的甲烷浓度最大值分别为1.63 mg/L和3.82 mg/L。并且将COD、硫酸盐、硫化物、TN的浓度变化与甲烷浓度变化进行Pearson简单相关性分析,结果表明,1/COD、COD/硫酸盐和1/TN与甲烷在置信度为0.01时极显著相关,硫化物与甲烷在置信度为0.05时不相关;COD、硫酸盐和TN浓度的变化对生活污水中甲烷的产生起关键性作用。对居民生活污水中甲烷产生规律进行温度和pH控制分析研究,实验结果表明,生活污水在25~30℃时,24 h内甲烷产生量最大值为8.6494 mg/L,明显大于其他温度段的甲烷产生量;在pH为7~8之间时,甲烷的产生量在24 h内达到的最大值为3.0477 mg/L,明显高于其他pH控制段的甲烷产生量。 相似文献
392.
The production of water-extractable organic carbon (WEOC) during arctic coastal erosion and permafrost degradation may contribute significantly to C fluxes under warming conditions, but it remains difficult to quantify. A tundra soil collected near Barrow, AK, was selected to evaluate the effects of soil pretreatments (oven drying vs. freeze drying) as well as extraction solutions (pure water vs. seawater) on WEOC yields. Both oven drying and freeze drying significantly increased WEOC release compared with the original moist soil samples; dried samples released, on average, 18% more WEOC than did original moist samples. Similar results were observed for the production of low-molecular-weight dissolved organic C. However, extractable OC released from different soil horizons exhibited differences in specific UV absorption, suggesting differences in WEOC quality. Furthermore, extractable OC yields were significantly less in samples extracted with seawater compared with those extracted with pure water, likely due to the effects of major ions on extractable OC flocculation. Compared with samples from the active horizons, upper permafrost samples released more WEOC, suggesting that continuously frozen samples were more sensitive than samples that had experienced more drying-wetting cycles in nature. Specific UV absorption of seawater-extracted OC was significantly lower than that of OC extracted using pure water, suggesting more aromatic or humic substances were flocculated during seawater extraction. Our results suggest that overestimation of total terrestrial WEOC input to the Arctic Ocean during coastal erosion could occur if estimations were based on WEOC extracted from dried soil samples using pure water. 相似文献
393.
A review is presented on trace gas exchange of CH4, CO, N2O, and NOx arising from agriculture and natural sources in the world's semiarid and arid zones due to soil processes. These gases are important contributors to the radiative forcing and the chemistry of the atmosphere. Quantitative information is summarized from the available studies. Between 5 and 40% of the global soil-atmosphere exchange for these gases (CH4, CO, N2O, and NOx) may occur in semiarid and arid zones, but for each of these gases there are fewer than a dozen studies to support the individual estimates, and these are from a limited number of locations. Significant differences in the biophysical and chemical processes controlling these trace gas exchanges are identified through the comparison of semiarid and arid zones with the moist temperate or wet/dry savanna land regions. Therefore, there is a poorly quantified understanding of the contribution of these regions to the global trace gas cycles and atmospheric chemistry. More importantly, there is a poor understanding of the feedback between these exchanges, global change, and regional land use and air pollution issues. A set of research issues is presented. 相似文献
394.
395.
396.
397.
通过对比分析目前WebGIS的常用开发方法和软件平台的特点,结合实际需求选择.NET和AreIMS技术,利用ArcIMS中的Serdet连接器和ArcXML语言的优点,在.NET环境下对ArcXML的生成进行封装,并结合ASP.NET技术设计了通用的WebGIS控件。该控件较好地实现了WebGIS中表现层与服务层的分离,可以方便地进行二次开发和与其他.NET系统集成,从而大大降低了WebGIS在.NET平台下的实现难度,并使系统具有了更好的可扩展性,通过在博州水利信息系统的应用实例介绍了实现过程。 相似文献
398.
The microscopic reaction mechanisms of diphenylether (DPE) and 4-bromodiphenylether (4-BrDPE) with nitrous acid (HNO(2)) in the absence of O(2) have been explored by the 355nm laser flash photolysis. It was proposed that OH radical, from the photolysis of HNO(2), added to DPE forms the C(12)H(10)O-OH adduct while added to 4-BrDPE forms the 4-BrDPE-OH and 4-BrOH-DPE adducts. The first-order decay rate constants of the C(12)H(10)O-OH adduct, 4-BrDPE-OH adduct and 4-BrOH-DPE adduct were measured to be (1.86+/-0.14)x10(5)s(-1), (2.19+/-0.04)x10(5)s(-1) and (1.56+/-0.03)x10(5)s(-1), respectively. The final photolysis products of DPE and HNO(2) identified by GC/MS analysis were phenol, o-hydroxydiphenylether, p-hydroxydiphenylether and p-nitrodiphenylether, while the final photolysis product of 4-BrDPE and HNO(2) identified by LC/MS analysis was mainly the dimer. 相似文献
399.
The endocrine response of crucian carp injected intraperitoneally with extracted microcystins (MC) was investigated in this study. Fish were injected intraperitoneally either with 0.75% NaCl (control) and Microcystis extract corresponding to 150 and 600 microg microcystins per kg body weight. The plasma levels of triiodothyronine (T(3)), thyroxine (T(4)), free triiodothyronine (FT(3)), free thyroxine (FT(4)), and cortisol were determined at 0, 1, 3, 12, 24, and 48h post-administration of MC-containing extract. Treated fish displayed abnormal behaviors, such as a startle response and disoriented swimming, as well as changes in ventilation rates. Plasma cortisol concentrations of fish in both dose groups significantly increased after administration of extracted MC and remained high throughout the experiment, which suggested that MC elicited a stress response in treated fish. The profiles of cortisol changes in treated fish appeared to be dose dependent, indicating that fish in the high dose group experienced greater MC-induced disturbance. Mortality occurred after 12h in the high dose group. Plasma levels of T(4), T(3), FT(4), and FT(3) did not vary significantly between the control fish. In contrast to this, fish exposed to MC-containing extract showed significant declines in T(3), FT(4), and FT(3) levels in a dose-dependent manner throughout the experiment. Plasma T(4) levels, however, did not vary significantly in the low dose group, whereas they decreased significantly at 48h post injection in the high dose group. This study demonstrates that administration of microcystins-containing extract causes a stress response and reduces the plasma levels of thyroid hormones in crucian carp. These results illustrate that microcystins exerted potent effects on the endocrine system of crucian carp, through activating their hypothalamus-pituitary- interrenal axis and disturbing thyroid function. 相似文献
400.
沈立 《中国安全科学学报》2008,18(2):166-170
重大危险源及其监管越来越受到关注,历经十多年,重大危险源的表述及其基本定义并没有取得共识而完全统一,现在开始实施重大危险源申报登记制度,涉及重大危险源的辨识、评价、分级等大量的具体工作,相关的理论和方法应用比较复杂。笔者就有关问题提出了自己的看法,认为重大危险源分级不仅是一项技术方法,而且是一项政策性行为,标准的制定一定要紧密联系实际,有利推动安全生产工作。 相似文献