公路运输化学事故应急救援体系研究

以动态源的定义为基础 ,结合危化品公路运输特殊性 ,阐述了危化品在公路运输过程中发生化学事故后应急救援的原则、工作特点与基本要求 ;提出化学事故应急救援中的基本任务是控制危险源 ,抢救受害人员 ,指导并组织群众疏散、自救和做好事故现场清理洗消工作 ,消除危害后果 ;提出公路运输化学事故应急救援预案系统建设的总体目标是 ,在应用ITS智能交通系统对动态源精确定位的基础上 ,建立公路运输化学事故应急救援预案动态库及应急救援组织保障系统和应急救援技术支持系统 ,一旦事故发生 ,能够做到尽快有效处理 ,最大限度地减小或消除事故损失。     

重大事故应急救援法律法规体系建设

重大事故应急救援法律法规体系作为生产安全应急救援体系建设的重要内容之一 ,在重特大事故多发的今天 ,已显得尤为重要。笔者结合国内外重大事故应急救援立法的现状 ,论述加强我国应急救援法律法规体系建设的必要性 ;提出重大应急救援法律法规体系建设要从法律、行政法规及部门规章、地方性法规及规章3个方面进行 ;同时提出建立联席会议制度、应急预案编制审核和备案制度、报告与信息发布制度、应急救援的分级响应制度、应急救援演习制度、应急救援资金补偿制度、应急救援的奖惩制度等急救援工作制度体系。最后 ,还强调建立重大事故应急救援体系对于提高政府对国家危机的管理能力有着深远的影响和意义。     

池火灾热辐射下的最小安全距离

防火间距是石油化工企业平面设计中的一个重要参数 ,笔者旨在从流体力学角度研究池火灾发生情况下邻罐之间最小安全距离 ,从而给防火间距的制定提供依据。辐射是储罐区池火灾的主要传热方式 ,作者对池火灾形状以及介质辐射吸收性质进行了适当的简化 ,用CFD软件Fluent对丙烷液化烃储罐池火灾热辐射进行了数值模拟。模拟结果表明对于锰钢材料、内径为 1 2 4 1 0mm液化烃压力储罐 ,稳态池火灾情况下 ,相邻两储罐之间的最小安全距离为 1 5m。     

建筑装璜中几种常用板材热解特性及动力学研究

对建筑装璜中几种常用板材变工况的热解行为进行了热重分析（TG）和差分热重分析（DTG）研究。通过对TG和DTG曲线的分析,深入研究了影响样品热解过程的几个重要因素：升温速率、样品粒径和试样量对热解过程的影响,通过对十种模型的比较,发现热解过程符合两阶段一级反应模型。并得出了各阶段的动力学参数、表观活化能和频率因子。     

"开放型"区域资源策略探析--以浙江省为例

本文从区域资源安全的内涵出发,以浙江省为研究对象,在分析了省域资源条件及供给现状的基础上,提出了构建“开放型”区域资源安全体系的总体思路。     

长江三角洲及其附近地区两千年来水灾的研究

通过对长江三角洲及其附近地区两千年来水灾生成频率和强度的分析。认为两晋、南北朝时期和南宋、元、明、清时期是两千年来本区的主要水灾期。对照两千年来中国东部气候变化、海面升降与长江口河道变迁关系,认为在本区水灾生成事件中,气候因素起着主导控制作用。当然,人类活动对本区水灾生成的影响也不容忽视。本地区近百年来的旱涝灾害规律可用非线性科学的方法进行研究,旱涝灾害的准60年、准35年和准11年的长周期变化与地球自转速度、地极移动和太阳黑子活动的3个周期变化基本一致。本地区气候系统的行为具有混沌特征。这是线性逼近和周期叠加预报方法难以得出灾害预报正确结果的原因,但气候系统半个月的确定性预测可以实现。     

Microbial degradation of phthalic acid esters under anaerobic digestion of sludge

The microbial degradation by anaerobic sludge of three phthalates, priority pollutants, listed by both China National Environmental Monitoring Center and the U.S.EPA, namely, dimethyl (DMP), di-n-butyl (DBP) and di-n-octyl (DOP) phthalates was investigated. The experimental results indicated that the biodegradation rate and the biodegradability of three phthalates under anaerobic conditions appeared to be related to the length of the alkyl-side chains. More than 90% of DMP and DBP with the short alkyl-side chain phthalates can be degraded, whereas the DOP degradation appeared to be relatively slow under the same experimental conditions. The quantity of methane produced was measured and the results showed that both the ester groups and the phthalate ring were mineralized at a significant rate. The kinetics study demonstrated that the biodegradation of three phthalates conformed to the first-order model with respect to their concentrations.     

Carbon disulfide at a Chinese viscose factory external and internal exposure assessment

This article presents the results of carbon disulfide exposure measurements in a Chinese viscose rayon factory. The objectives of the study were to identify the external exposure levels at a large factory and to investigate the 2-thiothiazolidine-4-carboxylic acid (TTCA) concentrations in the urine of the subjects who were exposed to carbon disulfide in the working place atmosphere. The metabolism of carbon disulfide in the exposed subjects was also studied in order to demonstrate the best points in time for the internal exposure sampling. The measurement of the amount of personal exposure to carbon disulfide in the air of the workplace was performed by GC-FPD; the presence of TTCA in the workers urine was analyzed by use of a modified HPLC method. The kinetics of TTCA excretion was studied by analyses at different time-points both during and after exposure to carbon disulfide in the subjects. A total of 155 personal samples were obtained. The carbon disulfide concentration in the staple viscose hall was 13.72 +/- 1.12 mg m-3 in terms of the geometric mean +/- geometric standard deviation, and was 20.05 +/- 1.33 mg m-3 in the filament spinning hall. The TTCA values in the subjects who worked in the staple spinning hall were 1.18 +/- 0.43 mg g-1 creatinine and 1.07 +/- 0.38 mg g-1 creatinine for subjects working in the filament spinning hall. The best time for TTCA sampling is at the end of the working shift, the TTCA excretion was stable for a period of 4-12 h after exposure of the subjects to the carbon disulfide. It might be that the Chinese have different anthropometric characteristics; a sampling bias may therefore appear among different races.     

对铁碳处理硝基酚废水的研究

铁碳降解水中难降解有机污染物的影响因素、最佳工艺参数及处理效果;初步探讨了氧化降解污染物的作用机理;通过分析污染物降解的中间产物,提出了污染物降解的可能途径.探讨了pH、铁碳用量、温度以及锰矿物的粒径等对处理效果的影响,在最佳的工艺条件下,CODCr的去除率达到95%以上,TOC测定表明：大部分硝基酚被氧化降解为H2O和CO2.对硝基酚的降解途径主要是微电解将对硝基酚还原为对氨基酚,对氨基酚在酸性条件下被软锰矿氧化为H2O和CO2做探索性研究.     

全密闭电石炉尾气治理及综合利用

由于全密闭电石炉的尾气性质特殊，治理和综合利用存在一定的难度。本文总结了国内电石生产厂家的多种治理和利用方法，并根据国家产业政策的要求，提出了适合我国国情的电石炉烟气治理及综合利用方法。