Multivariate statistics explaining groundwater chemistry,Asyut, Egypt

Environmental Monitoring and Assessment - Water quality monitoring is very important in agricultural catchments. UV–Vis spectrometry is widely used in place of traditional analytical methods...     

Quaternary stratigraphy, sediment characteristics and geochemistry of arsenic-contaminated alluvial aquifers in the Ganges-Brahmaputra floodplain in central Bangladesh

This study focuses on the Quaternary stratigraphy, sediment composition, mineralogy, and geochemistry of arsenic (As)-contaminated alluvial aquifers in the Ganges-Brahmaputra floodplain in the central Bangladesh. Arsenic concentrations in 85 tubewells in Manikganj area, 70 km northwest of Dhaka City, range from 0.25 microg/L to 191 microg/L with a mean concentration of 33 microg/L. Groundwater is mainly Ca-HCO(3) type with high concentrations of dissolved As, Fe, and Mn, but low level of SO(4). The uppermost aquifer occurs between 10 m and 80 m below the surface that has a mean arsenic concentration of 35 microg/L. Deeper aquifer (>100 m depth) has a mean arsenic concentration of 18 microg/L. Sediments in the upper aquifer are mostly gray to dark-gray, whereas sediments in the deep aquifer are mostly yellowing-gray to brown. Quartz, feldspar, mica, hornblende, garnet, kyanite, tourmaline, magnetite, ilmenite are the major minerals in sediments from both aquifers. Biotite and potassium feldspar are dominant in shallow aquifer, although plagioclase feldspar and garnet are abundant in deep aquifer sediments. Sediment composition suggests a mixed provenance with sediment supplies from both orogenic belts and cratons. High arsenic concentrations in sediments are found within the upper 50 m in drilled core samples. Statistical analysis shows that As, Fe, Mn, Ca, and P are strongly correlated in sediments. Concentrations of Cd, Cu, Ni, Zn, and Bi also show strong correlations with arsenic in the Manikganj sediment cores. Authigenic goethite concretions, possibly formed by bacteria, are found in the shallow sediments, which contain arsenic of a concentration as high as 8.8 mg/kg. High arsenic concentrations in aquifers are associated with fine-grained sediments that were derived mostly from the recycled orogens and relatively rapidly deposited mainly by meandering channels during the Early to Middle Holocene rising sea-level conditions.     

Canopy slope effect on the performance of the solar chimney power plant

Solar chimney power plants constitute an impressive construction by its size and its output seems low for its dimensions. Although many works have been carried out on the subject, there is still much scientific and technical improvement to be done. In the present work, we consider the modeling of turbulent flow under the effect of natural convection within a solar chimney power plant (SCPP) by performing numerical simulation using the Saturne Code coupled with Syrthes code. The objective of the study is the analysis of the collector cover slope influence on the performance of the SCPP in two cases. In the first case, the storage system considered is composed solely of the ground under the collector. For the second case, the storage system is made, in addition to the ground, of a 10 cm thick tub filled with water, covering the entire surface of the collector. The concept of minimizing the entropy production is also studied with the objective of optimizing the geometric configuration as well as the effect of the collector cover slope on the efficiency of SCPP. The boundary conditions are defined according to the meteorological data for a typical day available on the site of Adrar, Algeria. The results allow us to focus on the storage system influence on the SCPP performance and the duration of its operation after sunset. This leads to the improvement of the global efficiency of the SCPP. Results show the positive impact of the extra storage media use and the configuration which improves the velocity at the chimney entrance.     

The performance of biological and tertiary wastewater treatment procedures for rotaviruses A removal

Environmental Science and Pollution Research - Enteric viruses, generally found in sewage, are recognized as the main cause of waterborne and foodborne public health outbreaks. Among leading...     

Nexus between renewable energy consumption,economic growth,and CO2 emissions in Algeria: New evidence from the Fourier-Bootstrap ARDL approach

Governments often impose new energy strategies to support new CO₂ emission-reducing technologies without affecting economic growth. Hence, this study aims to re-investigate the relationship between economic growth, renewable energy use, and CO₂ emissions in Algeria from 1990 to 2018. Motivated by the mixed findings of the existing literature, which ignore the Fourier function and bootstrap test and apply the newly developed Fourier bootstrap autoregressive distributed lag model (FARDL). Our findings indicate that renewable energy use and growth have a long-run relationship with CO₂ emissions and do not accept the existence of the Environmental Kuznets Curve (EKC) hypothesis for CO₂ emissions in Algeria. In the long term, the results show that renewable energy use has a negative and significant impact, and growth has a positive and statistically significant effect on CO₂ emissions. In the short run, the findings indicate that renewable energy use reduces CO₂ emissions, while both the growth and squared growth had positive and statistically insignificant impacts on CO₂ emissions, confirming the lack of evidence supporting the EKC hypothesis. Moreover, the causality test indicates a one-way causation from growth to renewable energy use, confirming the conservation hypothesis for Algeria and from growth to CO₂ emissions. Interestingly, we found one-way causality from CO₂ emissions to renewable energy use, attributing this to the fact that renewable energy usage has yet to reach a point that it can significantly cause a CO₂ emissions reduction. Based on the results, we recommend that policymakers design appropriate policies to decarbonize energy consumption, e.g., increasing fossil fuel costs and implementing a carbon tax. In contrast, Algeria should promote new CO₂ emission-reducing technologies without affecting economic growth, e.g., tax exemptions and reductions for enterprise owners in the renewable energy industry.     

Phylogeographic study of the dwarf oyster, Ostreola stentina, from Morocco, Portugal and Tunisia: evidence of a geographic disjunction with the closely related taxa, Ostrea aupouria and Ostreola equestris

Despite the economic importance of oysters due to the high aquaculture production of several species, the current knowledge of oyster phylogeny and systematics is still fragmentary. In Europe, Ostrea edulis, the European flat oyster, and Ostreola stentina, the Provence oyster or dwarf oyster, are both present along the European and African, Atlantic and Mediterranean, coasts. In order to document the relationship not only between O. stentina and O. edulis, but also with the other Ostrea and Ostreola species, we performed a sequence analysis of the 16S mitochondrial fragment (16S rDNA: the large subunit rRNA-coding gene) and the COI fragment (COI: cytochrome oxidase subunit I). Oysters were sampled from populations in Portugal (two populations), Tunisia (two populations) and Morocco (one population), identified as O. stentina on the basis of shell morphological characters. Our data supported a high degree of differentiation between O. stentina and O. edulis and a close relationship between O. stentina and both Ostrea aupouria (from New Zealand) and Ostreola equestris (from Mexico Gulf/Atlantic). The status of this geographic disjunction between these closely related species is discussed. Furthermore, although identified in a separate genus Ostreola by Harry (Veliger 28:121–158, 1985), our molecular data on O. stentina, together with those available for the other two putative congeneric species, O. equestris and Ostreola conchaphila, would favour incorporation of Ostreola in Ostrea. Finally, a PCR-RFLP approach allowed the rapid identification of O. edulis and O. stentina.     

Highly efficient photodegradation of the pesticide metolcarb induced by Fe complexes

Here we show the efficient photoinduced degradation of the pesticide metolcarb, in less than 400 min, using iron(III) aquacomplexes and 365 nm light. The degradation is mainly due to the formation of hydroxyl radical. It was complete when molecular oxygen was present. The analytical study gives evidence for the primary formation of several byproducts formed from 1) the scission of the O–C bond, 2) the hydroxylation of the aromatic moiety and 3) the attack of the two methyl groups. Under prolonged irradiation and in aerated solutions, efficient mineralization was evidenced by the study of total organic carbon evolution as a function of irradiation time.     

Reinforcement of thermoplastic rejects in the production of manhole covers

Thermoplastic rejects are un-recyclable plastics that are either incinerated causing harmful emissions into the air or land-filled. A common problem associated with manhole covers is the theft of the cover made out of cast iron and then selling it on the black market leaving a large empty hole in the road causing many potential safety and health hazards. This paper investigates the reinforcement of un-recyclable thermoplastic rejects to be used in the application of a manhole cover. Foundry sand and steel were used with the thermoplastic rejects as reinforcement of the material. Foundry sand is a hazardous waste that may cause many potential health hazards. It was shown that with 10% foundry sand, 90% thermoplastic rejects, and a steel mesh of diameter size 12 mm reinforcement, the manhole cover could withstand an average load of 112 kN. This value exceeds Grades A, AA, AAA, and B of acclaimed standards BS EN 124 for manhole covers, which ultimately indicates that the manhole cover may be used in pedestrian precincts and areas with occasional vehicular access. This composite material is produced out of waste materials (foundry sand and un-recyclable thermoplastic rejects) thus not utilizing or depleting the earth's natural resources, and eliminating the safety hazards, health hazards, and pollution associated with these waste materials. Not only is this product a benefit to the environment, but also inexpensive due to the fact that the materials are un-recyclable waste materials, and thus do not attain any value or cost.     

Selenium and nano-selenium in plant nutrition

Selenium (Se) is a naturally occurring metalloid element which occurs nearly in all environments. Se is considered as a finite and non-renewable resource on the Earth. The common sources of Se in earth’s crust occur in association with sulfide minerals such as metal selenide, whereas it is rarely found in elemental form (Se⁰). While there is no evidence of Se need for higher plants, several reports show that when Se added at low concentrations, Se exerts beneficial effects on plant growth. Se may act as quasi-essential micronutrient through altering different physiological and biochemical traits. Thus, plants vary considerably in their physiological and biochemical response to Se. This review focusses on the physiological importance of Se forms as well as different Se fertilizers for higher plants, especially plant growth, uptake, transport, and metabolism.     

Natural radioactive nuclides in some Tunisian thermo-mineral springs

Radioactivity in some Tunisian thermo-mineral springs (11 hot mineral springs and one cold spring) has been determined for the first time in Tunisia using radiochemical separation procedures. The obtained results show that 238U activity concentrations vary between 1.5 and about 43 mBq/l. The measured activities of 234U and 226Ra range from 1.1 to about 82.2 mBq/l and 34-3,900 mBq/l. respectively. The radioactive disequilibria in these waters are in excess of concentration of 234U compared to that of 238U. The 226Ra/234U activity ratios are high and in the range of 9.0-691.0). U, Th and Ra activities are similar to those published for other non-polluted regions of the world. Radioactivity in the only cold mineral water from A?n Oktor is very low, and thus health hazards due to the consumption of this water are not expected.