The use of ultra filtration in trace metal speciation studies in sea water

During this work, size fractionation technique "ultra filtration" is used in speciation studies of trace elements in the coastal sea water. Filtration is the most commonly used method to fractionate trace metal species, but often only "dissolved" and "particulate" fraction. The purpose of the present study is to determine colloidal and suspended particulate concentrations of Fe, Zn, Cu, Ni, and Mn in sea water. Suspended particulate matter were separated in three different size groups namely (>2.7 microm, <2.7->0.45 microm and <0.45->0.22 microm) by suction filtration using cellulose acetate and nitrate filter membranes. Thereafter to concentrate the solution with colloidal particle <0.22 microm-1.1 nm (0.5 k Nominal Molecular Weight cut-off Limit {NMWL}), the solution obtained from filtration through <0.22 microm, is sequentially passed through the ultra-filtration membranes having pore diameters of 14 nm (300 k NMWL), 3.1 nm (50 k NMWL), 2.2 nm (30 k NMWL), 1.6 nm (10 k NMWL) and 1.1 nm (0.5 k NMWL) by using Stirred Ultra-filtration Cells, operating in concentration mode. The concentration of Fe, Zn, Cu, Ni, and Mn were measured in suspended and dissolved fraction by ion chromatography, ICP-AES and Atomic Absorption Spectrometer. The salinity of the solution in various dissolved fractions of sequential filtration varies between 30.89-34.22 parts per thousand. The maximum concentrations of colloidal Zn, Cu, Ni and Mn in dissolved fraction were in <2.2->1.6 nm fraction. In case of Fe, colloidal fractions <2.2->1.6 nm and <1.6-<1.1 nm shows higher concentration. The concentration of Zn, Cu, Ni and Mn increase with decrease in size in suspended particulate matter, while the reverse is observed in case of Fe. This size separation data that specifies the partitioning of metals between dissolved and suspended solid phases is necessary for developing physically based models of metal transport in aquatic system.     

Informal e-waste recycling: environmental risk assessment of heavy metal contamination in Mandoli industrial area,Delhi, India

Nowadays, e-waste is a major source of environmental problems and opportunities due to presence of hazardous elements and precious metals. This study was aimed to evaluate the pollution risk of heavy metal contamination by informal recycling of e-waste. Environmental risk assessment was determined using multivariate statistical analysis, index of geoaccumulation, enrichment factor, contamination factor, degree of contamination and pollution load index by analysing heavy metals in surface soils, plants and groundwater samples collected from and around informal recycling workshops in Mandoli industrial area, Delhi, India. Concentrations of heavy metals like As (17.08 mg/kg), Cd (1.29 mg/kg), Cu (115.50 mg/kg), Pb (2,645.31 mg/kg), Se (12.67 mg/kg) and Zn (776.84 mg/kg) were higher in surface soils of e-waste recycling areas compared to those in reference site. Level exceeded the values suggested by the US Environmental Protection Agency (EPA). High accumulations of heavy metals were also observed in the native plant samples (Cynodon dactylon) of e-waste recycling areas. The groundwater samples collected form recycling area had high heavy metal concentrations as compared to permissible limit of Indian Standards and maximum allowable limit of WHO guidelines for drinking water. Multivariate analysis and risk assessment studies based on total metal content explains the clear-cut differences among sampling sites and a strong evidence of heavy metal pollution because of informal recycling of e-waste. This study put forward that prolonged informal recycling of e-waste may accumulate high concentration of heavy metals in surface soils, plants and groundwater, which will be a matter of concern for both environmental and occupational hazards. This warrants an immediate need of remedial measures to reduce the heavy metal contamination of e-waste recycling sites.     

Determinants of CO2 emissions in upper middle-income group countries: an empirical investigation

Environmental Science and Pollution Research - This study investigates the kinked exponential growth, degree of association, and causation between economic growth, energy consumption, population,...     

Heavy metal accumulation in certain marine animals along the East Coast of Chennai, Tamil Nadu, India

Heavy metals disposed through anthropogenic activities find their way into the oceans and seas through the rivers or through direct fall out from factory effluents. These heavy metals resuspend back into the water column along with the sediments and are known to affect the marine animals. Marine animals like fish, prawn, crab and mussel were collected along the East Coast (off Pulicat lake to Chennai Harbour) to evaluate trace metal concentrations in various tissues. The above specimens accumulated heavy metals such as Zn, Pb, Cu, Co, Cr, Ni and Cd. Fish, prawn, crab and mussel revealed higher concentration of heavy metals such as Zn, Pb, Cr Co, Cu and Ni and Cd in low levels. The results revealed that the heavy metal concentrations in the marine animals are below the threshold levels associated with the toxicological effects and the regulatory limits. The bioconcentration factors revealed that the animals have accumulated heavy metals along the food chain rather than from the water column and sediment.     

Natural gas engine driven heat pump system – a case study of an office building

ABSTRACT

An eQUEST model was developed to conduct a simulation study of a natural gas engine-driven heat pump (GEHP) for an office building in Woodstock, Ontario, Canada. Prior to the installation of the GEHP, the heating and cooling demands of the office building were provided by rooftop units (RTUs), comprising of natural gas heater and electric air conditioner. Energy consumption for both GEHP and RTUs were monitored for operation in alternating months. These recorded energy consumptions along with weather data were used in the regression analysis. The developed eQUEST models were validated and calibrated with the regression analysis results with respect to the ASHRAE Guideline 14–2014. The eventual models were then applied to investigate the potential annual energy consumption, greenhouse gas (GHG) emission and energy cost savings achieved by using the GEHP in Woodstock, and other cities in Canada, particularly in Ontario.     

Effect of commercial pesticides on plant growth-promoting activities of Burkholderia sp. strain L2 isolated from rhizosphere of Lycopersicon esculentum cultivated in agricultural soil

The in vitro study was carried out to examine the toxicity of four commercially used pesticides (phorate, mancozeb, chlorpyrifos, and endosulfan) at the recommended dose (1X) and higher field doses (1.5X, 2X, 2.5X, and 3X) on plant growth-promoting activities of Burkholderia sp. strain L2, isolated from pesticide-treated rhizosphere of Lycopersicon esculentum. At the recommended dose, level of toxicity of all the pesticides to phosphate solubilization activity and indole-3-acetic acid (IAA) production was less detrimental as compared to exceeding doses. At maximum dose rate of each pesticide, the percentage decrease in phosphate solubilization and IAA production over control was found in order of chlorpyrifos < mancozeb < endosulfan < phorate. Present study proves that Burkholderia sp. strain L2 could be used as a potential microbial inoculant in the agricultural soil having persistent pesticide residues.     

Fluoride, boron and nitrate toxicity in ground water of northwest Rajasthan, India

The study was carried out to access the fluoride, boron, and nitrate concentrations in ground water samples of different villages in Indira Gandhi, Bhakra, and Gang canal catchment area of northwest Rajasthan, India. Rural population, in the study site, is using groundwater for drinking and irrigation purposes, without any quality test of water. All water samples (including canal water) were contaminated with fluoride. Fluoride, boron, and nitrate were observed in the ranges of 0.50–8.50, 0.0–7.73, and 0.0–278.68 mg/l, respectively. Most of the water samples were in the categories of fluoride 1.50 mg/l, of boron 2.0–4.0 mg/l, and of nitrate <?45 mg/l. There was no industrial pollution in the study site; hence, availability of these compounds in groundwater was due to natural reasons and by the use of chemical fertilizers.     

Development of controlled release formulations of azadirachtin-A employing poly(ethylene glycol) based amphiphilic copolymers

Controlled release (CR) formulations of azadirachtin-A, a bioactive constituent derived from the seed of Azadirachta indica A. Juss (Meliaceae), have been prepared using commercially available polyvinyl chloride, polyethylene glycol (PEG) and laboratory synthesized poly ethylene glycol–based amphiphilic copolymers. Copolymers of polyethylene glycol and various dimethyl esters, which self assemble into nano micellar aggregates in aqueous media, have been synthesized. The kinetics of azadirachtin-A, release in water from the different formulations was studied. Release from the commercial polyethylene glycol (PEG) formulation was faster than the other CR formulations. The rate of release of encapsulated azadirachtin-A from nano micellar aggregates is reduced by increasing the molecular weight of PEG. The diffusion exponent (n value) of azadirachtin-A, in water ranged from 0.47 to 1.18 in the tested formulations. The release was diffusion controlled with a half release time (t_1/2) of 3.05 to 42.80 days in water from different matrices. The results suggest that depending upon the polymer matrix used, the application rate of azadirachtin-A can be optimized to achieve insect control at the desired level and period.     

Investigations of an intense aerosol loading during 2007 cyclone SIDR – A study using satellite data and ground measurements over Indian region

Tropical cyclones are prominent weather systems characterized by high atmospheric pressure gradients and wind speeds. Intense tropical cyclones occur in India during the pre-monsoon (spring), early monsoon (early summer), or post-monsoon (fall) periods. Originating in both the Bay of Bengal (BoB) and the Arabian Sea (AS), these tropical cyclones often attain velocities of more than 100 km h^?1 and are notorious for causing intense rain and storm surge as they cross the Indian coast. In this study, we examine the changes in the aerosol properties associated with an intense tropical cyclone “SIDR”, that occurred during 11–16 November 2007 over BoB. This cyclone, accompanied with very strong surface winds reaching 223 km h^?1, caused extensive damage over Bangladesh. Ground-based measurements of Aerosol Optical Depth (AOD) in the neighboring urban environment of Hyderabad, India, showed significant variations due to changes in wind velocity and direction associated with the cyclone passage. The Terra-MODIS and AVHRR satellite images showed prevalence of dust particles mixed with emissions from anthropogenic sources and biomass-burning AS, while the aerosol loading over BoB was significantly lower. The positive values of Aerosol index (AI) obtained from the Ozone Monitoring Instrument (OMI) suggested the presence of an elevated aerosol layer over the West coast of India, AS and Thar Desert during and after the cyclone episode. Meteorological parameters from the MM5 mesoscale model were used to study the variations in winds associated with the cyclonic activity. Particulate matter loading over the region during the cyclone period increased by ～45% with an accompanying decrease in columnar aerosol optical depth. The variations in Angstrom parameters suggested coarse-mode particle loading due to dust aerosols as observed in satellite data.