全文获取类型
收费全文 | 194篇 |
免费 | 4篇 |
国内免费 | 12篇 |
专业分类
安全科学 | 8篇 |
废物处理 | 23篇 |
环保管理 | 10篇 |
综合类 | 45篇 |
基础理论 | 29篇 |
污染及防治 | 68篇 |
评价与监测 | 17篇 |
社会与环境 | 9篇 |
灾害及防治 | 1篇 |
出版年
2023年 | 3篇 |
2022年 | 4篇 |
2021年 | 5篇 |
2018年 | 7篇 |
2017年 | 6篇 |
2016年 | 5篇 |
2015年 | 3篇 |
2014年 | 11篇 |
2013年 | 15篇 |
2012年 | 19篇 |
2011年 | 27篇 |
2010年 | 11篇 |
2009年 | 12篇 |
2008年 | 21篇 |
2007年 | 13篇 |
2006年 | 12篇 |
2005年 | 7篇 |
2004年 | 7篇 |
2003年 | 11篇 |
2002年 | 2篇 |
2001年 | 2篇 |
2000年 | 1篇 |
1998年 | 1篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1993年 | 1篇 |
1979年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有210条查询结果,搜索用时 0 毫秒
171.
Nishimura S Maie N Baba M Sudo T Sugiura T Shima E 《Journal of environmental quality》2012,41(3):823-833
Chromophoric dissolved organic matter (CDOM) leached from leaf litter is a major source of humus in mineral soil of forest ecosystems. While their functions and refractoriness depend on the physicochemical structure, there is little information on the quality of CDOM, especially for that leached in the very early stages of litter decomposition when a large amount of dissolved organic matter (DOM) is leached. This study aimed to better understand the variations/changes in the composition of CDOM leached from senescent leaf litter from two tree species during the early stage of decomposition. Leaf litter from a conifer tree (Japanese cedar, D. Don) and a deciduous broad-leaved tree (Konara oak, Thunb.) were incubated in columns using simulated rainfall events periodically for a total of 300 d at 20°C. The quality of CDOM was investigated based on the fluorescence properties by using a combination of excitation-emission matrix fluorescence (EEM) and parallel factor analysis (PARAFAC). In addition, the phenolic composition of DOM was investigated at a molecular level by thermally assisted hydrolysis and methylation-gas chromatography-mass spectrometry (THM-GC-MS) in the presence of tetramethylammonium hydroxide (TMAH). The EEM was statistically decomposed into eight fluorescence components (two tannin/peptide-like peaks, one protein-like peak, and five humic-like peaks). A significant contribution of tannin/peptide-like peaks was observed at the beginning of incubation, but these peaks decreased quickly and humic-like peaks increased within 1 mo of incubation. The composition of humic-like peaks was different between tree species and changed over the incubation period. Since tannin-derived phenolic compounds were detected in the DOM collected after 254 d of incubation on THM-GC-MS, it was suggested that tannins partially changed its structure, forming various humic-like peaks during the early decomposition. 相似文献
172.
Wanyang Liu Satoshi Takahashi Yui Sakuramachi Kouji H. Harada Akio Koizumi 《Chemosphere》2013,90(5):1672-1677
The fluorotelomer alcohols (FTOHs) have been detected in various environmental compartments, including indoor and outdoor air, in North America and Europe. In our previous studies, FTOHs were detected at a relative higher concentration in outdoor air in the Keihan (Kyoto–Osaka, one of the major industrial zones) area, Japan compared to reported data. The exposure level of FTOHs in indoor air in the Keihan area remains unclear. In the present study, indoor air FTOH concentrations were investigated using a passive air sampler containing activated carbon felts. The indoor air sampling was conducted in 49 households of the Keihan area, during winter and summer 2008. Most samples contained 6:2 FTOH, 8:2 FTOH, 10:2 FTOH and 8:2 FTOAc. The median concentration of 8:2 FTOH (5.84 ng m?3) was highest among fluorotelomers, followed by those of 10:2 FTOH (1.12 ng m?3), 6:2 FTOH (0.29 ng m?3), and others. Significant correlations among fluorotelomers were observed in collected samples. The association between housing conditions and 8:2 FTOH concentrations showed that samples collected from bed rooms have higher 8:2 FTOH concentrations than those collected from other locations. In addition, samples collected in winter showed lower levels of 8:2 FTOH than those collected in summer. These findings suggest that 8:2 FTOH is the predominant component among fluorotelomers in indoor air, and that there are emission sources of fluorotelomers in indoor environments of the Keihan area. Further investigations into the origins of fluorotelomers are needed to evaluate indoor contamination with fluorotelomers. 相似文献
173.
Chovancová J Conka K Fabišiková A Sejáková ZS Dömötörová M Drobná B Wimmerová S 《Chemosphere》2012,88(11):1383-1389
Blood serum specimens from 81 non-occupationally exposed adults residing in four areas close to municipal and waste incinerators as well as metallurgical industry plant and 44 adult subjects coming from control area of Slovakia were analysed for polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), dioxin-like polychlorinated biphenyls (dl-PCBs) and polybrominated diphenylethers (PBDEs). The concentration of total WHO(98)TEQ PCDD/F/dl-PCBs in whole group of donors from areas where known sources causing dioxin contamination are present was significantly higher than in control group of donors (p<0.001). Correlation between the age of donors and PCDD/F and dl-PCB levels was confirmed (Spearman's r(PCDD/Fs)=0.543, r(dl-PCBs)=0.521, p<0.001). Furthermore, this study presents first results concerning the PBDE congeners in human serum of Slovak general population. The total concentration (congeners 28, 47, 99, 100, 153, 154, 183) in control group was approximately 1.5-times higher in comparison to that of residents coming from areas with supposed environmental pollution. The most abundant congeners in all samples were BDE-47 and BDE-153 with median values of 0.24 ng g(-1) lipid and 0.23ngg(-1) lipid, respectively. The positive association between PBDE values and age of donors was not found. 相似文献
174.
Poulsen AH Kawaguchi S Kukkonen JV Leppänen MT Bengtson Nash SM 《Environmental pollution (Barking, Essex : 1987)》2012,160(1):185-191
This study evaluated the toxicological sensitivity of non-feeding larval stages of a key Antarctic species (Antarctic krill, Euphausia superba) to p,p'-dichlorodiphenyl dichloroethylene (p,p'-DDE) exposure. The aqueous uptake clearance rate of 84 mL g(-1) preserved weight (p.w.) h(-1) determined for p,p'-DDE in Antarctic krill larvae is comparable to previous findings for small cold water crustaceans and five times slower than the rates reported for an amphipod inhabiting warmer waters. Natural variations in larval physiology appear to influence contaminant uptake and larval krill behavioural responses, strongly highlighting the importance of time of measurement for ecotoxicological testing. Sublethal narcosis (immobility) was observed in larval Antarctic krill from p,p'-DDE body residues of 0.2 mmol/kg p.w., which is in agreement with findings for adult krill and temperate aquatic species. The finding of comparable body residue-based toxicity of p,p'-DDE between polar and temperate species supports the tissue residue approach for environmental risk assessment of polar ecosystems. 相似文献
175.
Summer time haze characteristics of the urban atmosphere of Gwangju and the rural atmosphere of Anmyon, Korea 总被引:4,自引:0,他引:4
An extensive visibility monitoring was carried out simultaneously in the urban area of Gwangju and the rural area of Anmyon,
Korea. This study examines patterns of visibility impairment and haze-forming pollutant concentrations on both sites resulting
from natural and anthropogenic sources of gases and particles. Optical visibility measurements by a transmissometer, a nephelometer
and an aethalometer provide aerosol light extinction, scattering, and absorption coefficients for both sites. In order to
investigate the physico-chemical characteristics of atmospheric aerosols, aerosol samples were collected by various aerosol
samplers at GJVMS (Gwangju Visibility Monitoring Station) and at KGAWO (Korea Global Atmosphere Watch Observatory), respectively.
In addition, haze characteristics causing visibility impairment at those two sites were analyzed to obtain source contributions
by regionally transported aerosols using grid analysis and display system (GrADS) from NECP reanalysis data. During the intensive
monitoring period, ammonium sulfate was dominantly responsible for the fine particle mass loading at GJVMS, whereas organic
carbon was the largest contributor at KGAWO. Light scattering by particles accounted for 52.8 to 81.3% of the range at the
urban site, GJVMS and for 72.1 to 94.2% of the range at the rural site, KGAWO. Light absorption by the EC and NO2 was between 14.5 and 34.8% at GJVMS, which was higher than the observed 1.1 ∼ 6.8% at KGAWO, respectively. Light scattering
by aerosol was higher in the rural area than in the urban area. And organic carbon concentration was observed to be significantly
higher than the concentration of elemental carbon at KGAWO. These haze-forming carbonaceous particles originate from anthropogenic
pollutants at the urban atmosphere but they can be produced by natural environments such as marine and forest at the rural
atmosphere. 相似文献
176.
This study examined the effects of troposphere ozone (O3) on rice by developing a portable ozone fumigation system and applied to the field in Hanoi, Vietnam. The system was nearly identical to the open top chamber but designed to easily and cheaply assess the O3 sensitivity of local agricultural crops in the actual field. The rice (Oryza sativa L.) was exposed to ozone during the flowering stage at peri-urban experimental site of Hanoi. The fumigation protocols covered five different levels, namely; non-filtered air (ambient) as the control treatment, 32, 62, 85 and 113 ppb in 7-h mean. It was found that observed impacts corresponded well to similar open-top chamber studies in other Asian countries. The methodology and the system left a large room for improvement and called for very careful interpretation and pre-conditions (e.g. low ambient O3 concentration). However, the portable O3 exposure in the field might open a door to the less developed countries to implement the phytotoxic risk assessment of the local agricultural species. 相似文献
177.
Yugo Nomura Kazuo Fujiwara Makoto Takada Satoshi Nakai Masaaki Hosomi 《Journal of Material Cycles and Waste Management》2008,10(1):14-18
In previous studies, we focused on a mechanochemical process for recycling fly ash for use in cement; this process was expected
to immobilize heavy metals in the fly ash, a desirable outcome in light of the fact that recycled fly ash is commonly used
in the synthesis of inorganic materials. Here, we investigated the leaching of lead (Pb) from fly ash treated by a mechanochemical
process and from cement prepared from the treated fly ash. We used lead oxide (PbO), a typical Pb compound in fly ash, as
a model substance. Mechanochemical treatment of the fly ash inhibited Pb leaching by 93%, and further inhibition (more than
99.9%) was observed in cement produced from the treated fly ash. During the mechanochemical treatment, PbO was reduced to
Pb by iron from the stainless-steel mill used for processing, and the lower solubility of Pb in water resulted in immobilization
of the Pb. 相似文献
178.
Akihiko Masui Satoshi Ikawa Nobuaki Fujiwara Hiroaki Hirai 《Journal of Polymers and the Environment》2011,19(3):622-627
The influence on soil environment by continuing use of the biodegradable plastic films (biodegradable mulching films) in farmland
was investigated. The difference was not seen in the amount of soil bacteria between mulching film plowing sections and non-plowing
sections. The total bacteria amount did not increase by the effect of plowing the biodegradable mulching film. Poly-(butylene
succinate and adipate) (PBSA) and poly-(ε-caprolactone) (PCL) decomposing bacteria did not increase in PBSA and PCL mulching
film plowing sections comparing polyethylene covering section (PE) and no-film section. Polylactic acid (PLA) decomposing
bacteria were not detected in all sections. Total denaturing gradient gel electrophoresis (DGGE) band patterns did not show
a clear transition of the bacterial community structure in both the cultivating and promoting sections. In usual usage condition
of the biodegradable plastic films, it was hardly influence to the soil environment such as bacterial community structure
in farmland. 相似文献
179.
Fuma S Watanabe Y Kawaguchi I Takata T Kubota Y Ban-Nai T Yoshida S 《Journal of environmental radioactivity》2012,103(1):15-19
Derivation of effect benchmark values for each taxonomic group, which has been difficult due to lack of experimental effects data, is required for more adequate protection of the environment from ionising radiation. Estimation of effects doses from nuclear DNA mass and subsequent species sensitivity distribution (SSD) analysis were proposed as a method for such a derivation in acute irradiation situations for assumed nuclear accident scenarios. As a case study, 5% hazardous doses (HD5s), at which only 5% of species are acutely affected at 50% or higher lethality, were estimated on a global scale. After nuclear DNA mass data were obtained from a database, 50% lethal doses (LD50s) for 4.8 and 36% of the global Anura and Caudata species, respectively, were estimated by correlative equations between nuclear DNA mass and LD50s. Differences between estimated and experimental LD50s were within a factor of three. The HD5s obtained by the SSD analysis of these estimated LD50s data were 5.0 and 3.1 Gy for Anura and Caudata, respectively. This approach was also applied to the derivation of regional HD5s. The respective HD5s were 6.5 and 3.2 Gy for Anura and Caudata inhabiting Japan. This HD5 value for the Japanese Anura was significantly higher than the global value, while Caudata had no significant difference in global and Japanese HD5s. These results suggest that this approach is also useful for derivation of regional benchmark values, some of which are likely different from the global values. 相似文献
180.
Effects of climate and land use changes on groundwater resources in coastal aquifers 总被引:1,自引:0,他引:1
To estimate the freshwater loss in coastal aquifers due to salinisation, a numerical model based on the sharp interface assumption has been introduced. The developed methodology will be useful in areas where limited hydrological data are available. This model will elaborate on the changes in fresh groundwater loss with respect to climate change, land use pattern and hydrologic soil condition. The aridity index has been introduced to represent the variations in precipitation and temperature. The interesting finding is that the deforestation leads to increase groundwater recharge in arid areas, because deforestation leads to reduce evapotranspiration even though it favors runoff. The combined climate and land use scenarios show that when the aridity index is less than 60, the agricultural lands give higher groundwater recharge than other land use patterns for all hydrologic soil conditions. The calculated recharge was then used to estimate the freshwater-saltwater interface and percentage of freshwater loss due to salinity intrusion. We found that in arid areas, the fresh groundwater loss increases as the percentage of forest cover increases. The combined effects of deforestation and aridity index on fresh groundwater loss show that deforestation causes an increase in the recharge and existing fresh groundwater resource in areas having low precipitation and high temperature (arid climates). 相似文献