全文获取类型
收费全文 | 4736篇 |
免费 | 33篇 |
国内免费 | 9篇 |
专业分类
安全科学 | 82篇 |
废物处理 | 184篇 |
环保管理 | 257篇 |
综合类 | 1627篇 |
基础理论 | 988篇 |
环境理论 | 8篇 |
污染及防治 | 1207篇 |
评价与监测 | 222篇 |
社会与环境 | 194篇 |
灾害及防治 | 9篇 |
出版年
2022年 | 37篇 |
2019年 | 53篇 |
2018年 | 98篇 |
2017年 | 95篇 |
2016年 | 115篇 |
2015年 | 112篇 |
2014年 | 128篇 |
2013年 | 212篇 |
2012年 | 124篇 |
2011年 | 212篇 |
2010年 | 151篇 |
2009年 | 157篇 |
2008年 | 233篇 |
2007年 | 206篇 |
2006年 | 168篇 |
2005年 | 135篇 |
2004年 | 138篇 |
2003年 | 118篇 |
2002年 | 153篇 |
2001年 | 106篇 |
2000年 | 85篇 |
1999年 | 55篇 |
1998年 | 44篇 |
1997年 | 51篇 |
1996年 | 54篇 |
1995年 | 58篇 |
1994年 | 55篇 |
1993年 | 33篇 |
1992年 | 47篇 |
1991年 | 47篇 |
1990年 | 41篇 |
1989年 | 34篇 |
1984年 | 31篇 |
1982年 | 31篇 |
1981年 | 34篇 |
1976年 | 33篇 |
1967年 | 35篇 |
1966年 | 31篇 |
1965年 | 49篇 |
1964年 | 37篇 |
1963年 | 36篇 |
1962年 | 34篇 |
1961年 | 46篇 |
1960年 | 39篇 |
1959年 | 41篇 |
1958年 | 46篇 |
1957年 | 39篇 |
1956年 | 40篇 |
1955年 | 37篇 |
1954年 | 43篇 |
排序方式: 共有4778条查询结果,搜索用时 15 毫秒
21.
Hofschreuder P van der Meulen W Heeres P Slanina S 《Journal of environmental monitoring : JEM》1999,1(2):143-147
Passive samplers provide an excellent opportunity to perform indicative measurements or establish a dense network of measuring sites. A drawback compared with conventional active measuring methods is the larger spread of results. This variation can, to a large extent, be attributed to the influence of temperature, sampler geometry and wind on sampling results. A proper design of sampler geometry and optimum choice of draught shield can reduce the influence of wind velocity on a badge type sampler to less than 10%. Wire mesh screens prove to be inadequate in damping turbulence. Filters give good results. Attention should be paid to the size and isolation value of the walls of the sampler to prevent thermal updrafts occurring within the sampler. Tube type samplers are less influenced by wind, provided that turbulence is prevented from influencing diffusion within the sampler. 相似文献
22.
Development and validation of methods for environmental monitoring of cyclophosphamide in workplaces
Methods to monitor contamination of workplaces with antineoplastic drugs have been developed and validated. Cyclophosphamide (CP) was used as a model compound as it is one of the most commonly used antineoplastic drugs. A wipe sampling method to detect contamination with CP at surfaces was developed. A personal air sampling method to sample gas and vapour on solid sorbent tubes and particles with filters was also developed. Wipe and filter samples were extracted and sorbent samples were eluted, all with ethyl acetate. The samples were analysed with liquid chromatography tandem mass spectrometry. (2)H(6)-labelled cyclophosphamide was used as an internal standard. The between-day precision was 2-5% for wipe samples, 4-6% for sorbent samples and 3-8% for filter samples. The limit of detection was 0.02 ng CP per sample for the wipe and filter methods and 0.03 ng CP per sample for the solid sorbent method. Wipe sampling on surfaces made of different materials resulted in mean recoveries between 78-106%. The desorption recovery was between 97-102% for the wipe samples, 97% for the sorbent samples and 101% for the filter samples. Samples were stable for up to 2 months at 5 degrees C and -20 degrees C and for about 2 d at room temperature. The developed methods were applied to the measurement of contamination with CP in a hospital pharmacy. Trace amounts of CP, 1.3 and 1.4 ng, were detected on surfaces in the pharmacy. 相似文献
23.
A method was developed for the determination of benzene in urine. The sample was pumped through the donor channel of a membrane extraction unit with a micro-porous membrane, separating the donor channel from an identical acceptor channel purged with nitrogen. The analyte reached the acceptor channel by diffusion through the membrane and was then swept by the carrier to a solid sorbent tube, where it was trapped. The analyte was subsequently thermally desorbed and analyzed by gas chromatography (GC) with mass selective detection (MS). After optimization, the recovery was close to quantitative, or 95%. Purging the membrane unit with pure water in between the samples eliminated any memory effects. The linearity was good in the concentration range examined (20-4000 ng l(-1)), with a correlation coefficient of 0.9996. The repeatability at 50 ng l(-1) and 400 ng l(-1) was 1.4% and 1.2%, respectively. The limit of detection was 12 ng l(-1) and the limit of quantification 35 ng l(-1). This enables assessment of benzene exposures of occupationally exposed subjects, of smokers and the majority of the general population. The developed method can be easily automated. 相似文献
24.
B. Beck-Friis M. Pell U. Sonesson H. Jönsson H. Kirchmann 《Environmental monitoring and assessment》2000,62(3):317-331
Composting can be a source of N2O andCH4 production. In this investigation, differentcompost heaps of organic household waste weremonitored with the focus on potential formation ofCH4 and N2O in the heaps and emission ofthese gases from the heaps. The studied compost heapshad different compost ages, turning intervals andcompost sizes. The analysed compost gases containedbetween 1–3421 L of N2O-N L-1 and 0–470 mL of CH4 L-1. The emission rates ofN2O and CH4 from the compost heaps werebetween 1–1464 mg N2O m-2 day-1 and0–119 000 mg CH4 m-2 day-1. These verylarge differences in compost gas composition andemission indicate the importance of compostmanagement. The results also give an understanding ofwhere in the composting process an increasing emissionof N2O and CH4 can occur. 相似文献
25.
26.
Specific PCR amplification and probe hybridization techniques were applied to examine the compositions of airborne fungi in samples from three different environments. The results from microscopic and CFU counting were compared to those of the molecular-based detections. The detection sensitivity for PCR amplifications was 9 to 73 spores and 1.3 to 19.3 CFUs per PCR reaction. The hybridization detection limit was 2 to 4 spores and 0.2 to 1.2 CFU. The hybridization method was more sensitive than PCR amplification and showed less variation among samples. Using specific PCR primers and probes we identified the presence of several fungal groups and species in the air samples. Specific detections through probe hybridization to PCR products amplified with universal or group-specific fungal primers have promising applications in the examination of air samples for environmental monitoring. 相似文献
27.
Application of a checklist for quality assistance in environmental modelling to an energy model 总被引:2,自引:0,他引:2
James Risbey Jeroen van der Sluijs Penny Kloprogge Jerry Ravetz Silvio Funtowicz Serafin Corral Quintana 《Environmental Modeling and Assessment》2005,10(1):63-79
Large, complex energy models present considerable challenges to develop and test. Uncertainty assessments of such models provide only partial guidance on the quality of the results. We have developed a model quality assistance checklist to aid in this purpose. The model checklist provides diagnostic output in the form of a set of pitfalls for the model application. The checklist is applied here to an energy model for the problem of assessing energy use and greenhouse gas emissions. Use of the checklist suggests that results on this issue are contingent on a number of assumptions that are highly value-laden. When these assumptions are held fixed, the model is deemed capable of producing moderately robust results of relevance to climate policy over the longer term. Checklist responses also indicate that a number of details critical to policy choices or outcomes on this issue are not captured in the model, and model results should therefore be supplemented with alternative analyses. 相似文献
28.
Graef F Schmidt G Schröder W Stachow U 《Environmental monitoring and assessment》2005,108(1-3):189-203
A representative environmental monitoring network at the regional scale cannot use raster-based or random sampling designs, but requires a stratified sampling procedure integrating different information layers, and it has to occur in ecologically differing homogeneous regions (ecoregions). These we have determined using a set of spatial strata with ecological variables which we analysed with classification and regression trees (CART). We present a framework for environmental monitoring, that covers different scales, and we transfer the framework to a potential GMO (genetically modified organisms) monitoring network. We use ecoregion and other environmental strata together with existing environmental monitoring networks to determine GMO monitoring sites more precisely. 相似文献
29.
The importance of selenium as an essential trace element has progressively emerged during the last years due to the analysis of selenium deficiency diseases and to the identification and characterization of a number of selenoenzymes. Selenium is incorporated in the catalytic site of the enzymes as an integral selenocysteine residue. The pathway of selenocysteine biosynthesis and incorporation has been elucidated recently for Escherichia coli. This article presents an overview on these subjects and describes the mechanisms which confer selenocysteine specificity in the framework of protein biosynthesis. In addition, some considerations concerning the phylogeny of selenocysteine incorporation are presented and a model for the evolution of the selenocysteine pathway is proposed. 相似文献
30.
E. Lamla F. Boschke G. Traving G. Pfotzer H. Wolter W. Walcher H. D. Dahmen H. J. Queisser W. W. Klingbeil K. Beyermann O. Müller R. R. Ernst D. Reinen H. Muth W. Becker G. Wunsch G. I. Distler L. Jaenicke H. G. v. Schnering H. Werner F. Reiff H. Schimassek W. Höll H. K. Vasil W. F. Angermeier W. Ruppel J. C. Eccles G. Spiteller H. Oettel W. Vogell P. Brosche K. J. Hsü H. -U. Schmincke 《Die Naturwissenschaften》1975,62(3):143-143