Aerobic treatment of swine manure to enhance anaerobic digestion and microalgal cultivation

Aerobic treatment of swine manure was coupled with anaerobic digestion and microalgal cultivation. A 14-day aerobic treatment reduced the total solid content of swine manure by >15%. Ammonia and carbon dioxide were stripped by the air supplied, and this off-gas was further used to aerate the culture of Chlorella vulgaris. The microalgal growth rates in Bristol medium and the wastewater with the off-gas increased from 0.08 to 0.22 g/L/d and from 0.15 to 0.24 g/L/d, respectively. Meanwhile, the aerobically treated swine manure showed a higher methane yield during anaerobic digestion. The experimental results were used to establish a demonstration unit consisting of a 100 L composter, a 200 L anaerobic digester, a 60 L tubular photobioreactor, and a 300 L micro-open raceway pond.     

Metal concentrations in used engine oils: Relevance to site assessments of soils

Used engine oils contain metals, which upon entering soils may pose risks to human health or the environment. In this study, previously published concentrations of 23 metals in 213 used engine oil samples from the early 1970s to the mid-1990s are statistically evaluated. Neat (100%) used engine oils were found to contain relatively high concentrations of lead, calcium, and zinc, attributable to piston blow-by of leaded gasoline, calcium salt detergent additives, and zinc-bearing anti-corrosion/anti-oxidation additives, respectively. Wear metal concentrations were lower. The lead concentration in used engine oils in the U.S. declined between the 1970s and early 1990s, potentially providing a basis to constrain the “age” of used engine oil(s) in soils. The concentrations of 23 metals in used engine oils were compared to soil risk benchmarks in 15 representative jurisdictions in the U.S., Canada, Australia, and Europe. The maximum concentrations in neat (100%) used engine oil of eight metals – Be, Co, Fe, Mn, Ni, Se, Ag, and Ti – were lower than their collective minimum benchmarks in soils for the jurisdictions surveyed, indicating their concentrations in soils could not be reasonably expected to exceed any soil benchmarks. Nine metals (As, Ba, Cd, Cr, Cu, Pb, Sn, V and Zn), but particularly arsenic, cadmium, lead, tin, and zinc, were identified as potential contaminants of concern (PCOC) for soils from locations impacted with used engine oils, owing to their higher median concentrations (i.e., 2.5, 1.4, 1038, 5.0, and 922 mg/kg in oil, respectively) relative to most soil benchmarks. Site-specific benchmarks and metal concentrations at reasonable oil in soil concentrations require consideration when developing the suite of PCOC metal analytes for conducting site assessments of soils impacted by used engine oil.     

Measuring the effectiveness of landscape approaches to conservation and development

Landscape approaches attempt to achieve balance amongst multiple goals over long time periods and to adapt to changing conditions. We review project reports and the literature on integrated landscape approaches, and found a lack of documented studies of their long-term effectiveness. The combination of multiple and potentially changing goals presents problems for the conventional measures of impact. We propose more critical use of theories of change and measures of process and progress to complement the conventional impact assessments. Theories of change make the links between project deliverables, outputs, outcomes, and impacts explicit, and allow a full exploration of the landscape context. Landscape approaches are long-term engagements, but short-term process metrics are needed to confirm that progress is being made in negotiation of goals, meaningful stakeholder engagement, existence of connections to policy processes, and effectiveness of governance. Long-term impact metrics are needed to assess progress on achieving landscapes that deliver multiple societal benefits, including conservation, production, and livelihood benefits. Generic criteria for process are proposed, but impact metrics will be highly situation specific and must be derived from an effective process and a credible theory of change.     

A new approach for the modelling of chestnut wood photo-degradation monitored by different spectroscopic techniques

The aim of this work is to study the colour and chemical modifications of the surfaces in chestnut wood samples as a consequence of irradiating in a controlled environment. The changes were investigated by a new analytical approach by combining traditional techniques such as reflectance spectrophotometry in the visible range and Fourier transform infrared spectroscopy with new hyperspectral imaging, in order to obtain forecast models to describe the phenomenon. The statistical elaboration of the experimental data allowed to validate the measurements and to obtain models enabling to relate the investigated parameters; the elaboration of the hyperspectral images by chemometric methods allowed for studying the changes in the reflectance spectra. A result of great importance is the possibility to correlate the oxidation of wood chemical components with the colour change in a totally non-invasive modality. This result is particularly relevant in the field of cultural heritage and in general in the control processes of wooden materials.     

Plant species richness of riverbed elevations—the Pripyat river valley case study

Flora of the still unchanged or slightly modified floodplains is particularly valuable. Such are the natural, periodically flooded riparian ecosystems within the Mid-Pripyat river valley in Belarus. Distinctive elements of that area are ‘periodic islands’, which arise from the most elevated parts of the riverbed during flooding and have a specific microtopography. The aim of the research was to recognize floristic composition and ecological conditions of the ‘islands.’ Noted plants were mainly photophilous, by clearly varied in soil moisture, acidity and fertility requirements.     

Development of vegetative and generative organs in magnetic orientation types of radish in a weak permanent magnetic field

Experiments have been performed to evaluate the impact of weak permanent horizontal magnetic field of about 400 A/m on seed formation in the main magnetic orientation types of radish, the north-south (NS) and west-east (WE) types. The results show that external magnetic field exposure retards plant progression through all stages of ontogeny but does not alter the ratio of NS and WE types. Under its effect, the numbers of pods and seeds and seed weight decrease in the NS-type but increase in the WS-type plants. Therefore, external magnetic field acts as an ecological factor that differentiates the responses of radish plants depending on the type of their magnetic orientation. Differences in the sensitivity of plants to magnetic field exposure are explained by specific features of their physiological status.     

Space-time analysis of the Air Quality Model Evaluation International Initiative (AQMEII) Phase 1 air quality simulations

This study presents an evaluation of summertime ozone concentrations over North America (NA) and Europe (EU) using the database generated from Phase 1 of the Air Quality Model Evaluation International Initiative (AQMEII). The analysis focuses on identifying temporal and spatial features that can be used to stratify operational model evaluation metrics and to test the extent to which the various modeling systems can replicate the features seen in the observations. Using a synoptic map typing approach, it is demonstrated that model performance varies with meteorological conditions associated with specific synoptic-scale flow patterns over both eastern NA and EU. For example, the root mean square error of simulated daily maximum 8-hr ozone was twice as high when cloud fractions were high compared with when cloud fractions were low over eastern NA. Furthermore, results show that over both NA and EU the regional models participating in AQMEII were able to better reproduce the observed variance in ambient ozone levels than the global model used to specify chemical boundary conditions, although the variance simulated by almost all regional models is still less that the observed variance on all spatiotemporal scales. In addition, all modeling systems showed poor correlations with observed fluctuations on the intraday time scale over both NA and EU. Furthermore, a methodology is introduced to distinguish between locally influenced and regionally representative sites for the purpose of model evaluation. Results reveal that all models have worse model performance at locally influenced sites. Overall, the analyses presented in this paper show how observed temporal and spatial information can be used to stratify operational model performance statistics and to test the modeling systems’ ability to replicate observed temporal and spatial features, especially at scales the modeling systems are designed to capture.

Implications: The analyses presented in this paper demonstrate how observed temporal and spatial information can be used to stratify operational model performance and to test the modeling systems’ ability to replicate observed temporal and spatial features. Decisions for the improvement of regional air quality models should be based on the information derived from only regionally representative sites.     

The New Zealand experience of varroa invasion highlights research opportunities for Australia

The Varroa mite (Varroa destructor) is implicated as a major disease factor in honey bee (Apis mellifera) populations worldwide. Honey bees are extensively relied upon for pollination services, and in countries such as New Zealand and Australia where honey bees have been introduced specifically for commercial pollinator services, the economic effects of any decline in honey bee numbers are predicted to be profound. V. destructor established in New Zealand in 2000 but as yet, Australia remains Varroa-free. Here we analyze the history of V. destructor invasion and spread in New Zealand and discuss the likely long-term impacts. When the mite was discovered in New Zealand, it was considered too well established for eradication to be feasible. Despite control efforts, V. destructor has since spread throughout the country. Today, assessing the impacts of the arrival of V. destructor in this country is compromised by a paucity of data on pollinator communities as they existed prior to invasion. Australia’s Varroa-free status provides a rare and likely brief window of opportunity for the global bee research community to gain understanding of honey bee-native pollinator community dynamics prior to Varroa invasion.     

Effect of Refractory on the Thermal Stability of SF6

The thermal decomposition of SF₆ is known to be oxygen-independent. Nevertheless, because of its high stability, the use of SF6 as a "conservative" surrogate in incinerator performance evaluation has been advocated and researched. This paper shows that refractory decreases markedly the stability of SF₆. The resulting increase in SF₆ decomposition was from 0 percent to 95 percent at 900°C, and the temperatures at which 90-99 percent decomposition occurred were lowered by 300-150°C. Refractory also decreased the stability of CCl₄ and C₂Cl₄, but to a lesser extent. The difference between the decompositions of C₂Cl₄ and SF₆ was reduced from several orders of magnitude to a factor of 2-4. Such a drastic and adverse change in relative stability could render SF₆ unsuitable as a "conservative" surrogate. The requirements for a "conservative" surrogate and the need for caution in its use are discussed, and further research areas are indicated.