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51.
A mass spectrometer-based continuous emission monitor (MS-CEM) for organic compound emissions from combustion devices was developed and evaluated at the Louisiana State University (LSU) pilot-scale rotary kiln incinerator (RKI). The MS-CEM consists of a stack probe, heat-traced sampling line, vacuum pump, particulate filter, Nafion@ dryer and mass spectrometer. The mass spectrometer includes a computer that controls and optimizes the operation of the unit. The MS-CEM is capable of continuously analyzing up to 40 different volatile organic compounds on a real-time basis. The MS-CEM is capable of analyzing, computing and recording the analytical results for each and up to 40 different organic compounds in less than 0.3 s. Four different volatile organic compounds were mixed together and injected into the baghouse inlet while simultaneously analyzing each organic component exiting the RKI stack gas. The results obtained from MS-CEM were compared with the material balance values. The system response time (including the MS-CEM) varies from 1.1 to 1.5 min. 相似文献
52.
Waste plastics recycling process using coke ovens 总被引:3,自引:0,他引:3
Kenji?KatoEmail author Seiji?Nomura Hiroshi?Uematsu 《Journal of Material Cycles and Waste Management》2003,5(2):98-101
The Japan Iron and Steel Federation (JISF), as its voluntary energy-saving action plan, proposed a 10% energy reduction by 2010 with 1990 as the basis. Further, it has suggested an additional 1.5% energy saving by the use of waste plastics as a metallurgical raw material. The amount of processing of waste plastics which corresponds to this amount of energy conversion is about 1 million t scale during 1 year. Conventional known methods for recycle-processing of waste plastics include, for example, the method of injection into a blast furnace to use waste plastics as an iron-ore reducing agent instead of coal. On the other hand, the coking process is considered to be suitable as a waste plastic recycling facility because the process involves coal carbonization in a high-temperature and reducing atmosphere. Carbonization tests with mixed waste plastics were conducted with laboratory equipment and in actual coke ovens. As a result, it was confirmed that the waste plastics recycling process using coke ovens is feasible. Therefore, a waste plastics recycling process using coke ovens was started as a chemical recycling technology at Nippon Steel. 相似文献
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54.
Nobuyasu Hanari Takamitsu Otake Nobuyasu Itoh Ayaka Wada Masaki Ohata 《Environmental monitoring and assessment》2017,189(2):92
Flame retardants (FRs) are useful because they can prevent combustion and delay the spread of fire after the ignition on commercial products containing plastics. However, such commercial products could be a primary source of environmental contamination with FRs. Plastic disks containing FRs were prepared to elucidate changes in the concentrations of the FRs after weathering tests. Acrylonitrile-butadiene-styrene (ABS) and polycarbonate (PC) resin were separately kneaded with a combination of three organic FRs [Dechlorane plus (DP), tetrabromobisphenol A (TBBPA), and triphenyl phosphate (TPhP)] and one inorganic FR [antimony trioxide (Sb2O3)]. The concentrations of TBBPA/TPhP and DP/Sb2O3 in the final preparations were respectively 1000 and 500 mg/kg in compliance with the RoHS directive on organobromine FR. The concentrations of elements in the final preparations were 300 mg/kg for chlorine, 600 mg/kg for bromine, 100 mg/kg for phosphorus, and 400 mg/kg for antimony, respectively. The analytical concentrations (three FRs and four elements) were consistent with the expected concentrations (maximum difference ?9.5% in the PC disks). The FRs and elements in the disks were sufficiently homogenous (maximum inhomogeneity 4.3% in the PC disks). The prepared disks were subjected to weathering tests; the concentrations of TBBPA in the disks decreased significantly (30 to 40%) whereas the concentrations of the elements did not change under the condition of this study. On the other hand, there were no drastic differences on relationships of FRs and elements such as DP/chlorine and TPhP/phosphorus. 相似文献
55.
Shinsaku Dobashi Yoshiki Yamaguchi Yoshinori Izawa Akihide Wada Michikazu Hara 《Journal of Material Cycles and Waste Management》2009,11(2):148-154
This study demonstrates the applicability of laser mass spectrometry for safety management of the processed gas and the work
environment in a polychlorinated biphenyl (PCB) disposal plant. By utilization of laser ionization/ion trapping storage/time-of-flight
mass spectrometry (LI-IT-TOFMS), we analyzed gaseous PCBs from scrap capacitors with on-line detection. It was confirmed that
few contaminants were detected in the spectrum. By the effect of laser-induced selective ionization, it was considered that
there was little interference with the mass range of PCBs. The accuracy of LI-IT-TOFMS when analyzing environmental gas was
almost the same as that for the PCB standard gas. It was possible to perform on-line analysis of the work environment for
over 2000 h (120 000 data points). LI-IT-TOFMS was thus shown to be a very useful method for ensuring the safety of the work
environment in disposal plants for PCBs. 相似文献
56.
Thomas E. Perardi Michael Y. Kim Eugene Y. Leong Ronald Y. Wada 《Journal of the Air & Waste Management Association (1995)》2013,63(4):358-364
Three regional agencies recently prepared an Air Quality Maintenance Plan for the San Francisco Bay Area oxidant problem. An Eulerian, photochemical model, LIRAQ, provided the technical basis for the plan recommendations. A major LIRAQ input is an emission inventory accurately resolved to one kilometer and one hour increments. The cooperating agencies prepared such inventories, covering 20,000 sq km, for one base and two future years. Several manual and computer-assisted techniques were developed to utilize a variety of independent data bases. Population, land use, employment and transportation data were oganized into a common system of coordinates and units to produce the needed spatial input. Estimates of hourly variation were made by source category based on production rates, fuel use, traffic patterns, flight schedules, and other factors. The result was a series of consistent, detailed inventories which provide a powerful air quality modeling and planning tool. The detail is attained at considerable expense, but the cost is easily justifiable when compared to implementation costs for control strategies. 相似文献
57.
Yasuhiko Wada Takuma Okumoto Nariaki Wada 《Journal of Material Cycles and Waste Management》2008,10(2):173-187
Waste disposal systems conventionally exhibit many problems, such as difficulties in finding final disposal sites for incinerator
residues and the issue of how to recycle waste materials. Some new technologies have been developed to solve such problems,
including ash melting and gasification melting. Furthermore, to improve the power generation efficiency of waste treatment
facilities so that their energy is used more efficiently, combined stoker/gas turbine power generation (super waste power
generation) technology has been developed. Through examination of two cases in this study, environmental impacts and costs
were determined using lifecycle assessment (LCA) and lifecycle cost (LCC) methods in a model city. In case 1, a stoker furnace
was compared to a combined stoker/gas turbine system. In case 2, a stoker furnace plus ash melting system was compared to
a gasification melting system. The results demonstrate that the stoker furnace has a lower environmental impact than the combined
stoker/gas turbine system in case 1, and that the stoker plus ash melting system costs less than the gasification melting
system in case 2, but both systems had strong impacts on the environment. 相似文献
58.
Environmental Economics and Policy Studies - This paper investigates the consumption tax and subsidy as an environmental policy instrument for environmentally aware consumers by applying the model... 相似文献
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