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211.
Franklin R. Alvarez Glenn M. Shaul E. Radha Krishnan Daniel L. Perrin Maqsud Rahman 《Journal of the Air & Waste Management Association (1995)》2013,63(6):734-739
ABSTRACT Terpene-based cleaners are being widely used in industrial cleaning formulations because of their ability to replace suspected ozone-depleting chemicals such as 1,1,1-trichloroethane and 1,1,2-trichloro-1,2,2-trifluoroethane (CFC-113). Substitution of chlorinated solvents with ter-pene-based cleaners, however, is expected to result in increased discharges to wastewater from industrial operations. A pilot-scale study was conducted at the U.S. Environmental Protection Agency's (EPA) Test & Evaluation Facility in Cincinnati, OH, to quantify the fate of specific terpene compounds in the activated sludge wastewater treatment process. Biodegradation rates of terpenes were estimated from the difference between the influent terpene mass flow rates and the amounts volatilized to air, partitioned to waste sludge, and passed through the treatment process unchanged. Any chemical transformation of the terpene compounds studied was attributed to biodegradation. Analytical methods were developed to determine ter-pene concentrations in aqueous and gaseous media. The fate of two common terpene compounds (d-limonene and terpinolene) were evaluated in three identical pilot-scale systems: (1) a system with a high target spike range (2–10 mg/L), (2) a system with a low target spike range (0.5–2 mg/L), and (3) a control system (no spike). The study showed that the primary removal mechanism for the terpene compounds in the activated sludge process is biodegradation. Typically, greater than 90% of the mass of terpenes entering the aeration basin of the activated sludge process biodegrades to other compounds; volatilization from the reaction basin accounts for less than 10%, while loss to waste activated sludge and the secondary clarifier effluent accounts for less than 1%. 相似文献
212.
Rahman Humairat H. Niemann Danielle Munson-McGee Stuart H. 《Environmental science and pollution research international》2023,30(8):20147-20158
Environmental Science and Pollution Research - Lung cancer is one of the primary causes of death with poor life expectancy after diagnosis. History of past respiratory diseases such as asthma,... 相似文献
213.
Chronic exposure of arsenic via drinking water and its adverse health impacts on humans 总被引:1,自引:0,他引:1
Mohammad Mahmudur Rahman Jack C. Ng Ravi Naidu 《Environmental geochemistry and health》2009,31(Z1):189-200
Worldwide chronic arsenic (As) toxicity has become a human health threat. Arsenic exposure to humans mainly occurs from the
ingestion of As contaminated water and food. This communication presents a review of current research conducted on the adverse
health effects on humans exposed to As-contaminated water. Chronic exposure of As via drinking water causes various types
of skin lesions such as melanosis, leucomelanosis, and keratosis. Other manifestations include neurological effects, obstetric
problems, high blood pressure, diabetes mellitus, diseases of the respiratory system and of blood vessels including cardiovascular,
and cancers typically involving the skin, lung, and bladder. The skin seems to be quite susceptible to the effects of As.
Arsenic-induced skin lesions seem to be the most common and initial symptoms of arsenicosis. More systematic studies are needed
to determine the link between As exposure and its related cancer and noncancer end points. 相似文献
214.
Kurosawa K Egashira K Tani M Jahiruddin M Moslehuddin AZ Rahman ZM 《Environmental pollution (Barking, Essex : 1987)》2008,156(2):563-565
To clarify the groundwater-soil-crop relationship with respect to arsenic (As) contamination, As concentration was measured in tubewell (TW) water, surface soil from farmyards and paddy fields, and fresh taro (Colocasia esculenta) leaves from farmyards in the farming villages of Bangladesh. The As concentration in TW water from farmyards was at least four times higher than the Bangladesh drinking water standard, and the concentration in fresh taro leaves was equal to or higher than those reported previously for leafy vegetables in Bangladesh. As concentration of surface soils in both farmyards and paddy fields was positively correlated with that of the TW water. Further, the concentration in surface soil was positively correlated with levels in fresh taro leaves in the farmyard. This study, therefore, clarified the groundwater-soil-crop relationship in farmyards and the relationship between groundwater-soil in paddy fields to assess the extent of As contamination in Bangladeshi villages. 相似文献
215.
The chromium species leaching from a coal combustion fly ash landfill has been characterized as well as a novel approach to treat leachates rich in hexavalent chromium, Cr(VI), by using another natural waste by-product, acid mine drainage (AMD), has been investigated during this study. It is observed that as much as 8% (approximately 10 microg g(-1) in fly ash) of total chromium is converted to the Cr(VI) species during oxidative combustion of coal and remains in the resulting ash as a stable species, however, it is significantly mobile in water based leaching. Approximately 1.23 +/- 0.01 microg g(-1) of Cr(VI) was found in the landfill leachate from permanent deposits of aged fly ash. This study also confirmed the use of AMD, which often is in close proximity to coal combustion by-product landfills, is an extremely effective and economical remediation option for the elimination of hexavalent chromium in fly ash generated leachate. Speciated isotope dilution mass spectrometry (SIDMS), as described in EPA Method 6800, was used to analytically evaluate and validate the field application of the ferrous iron and chromate chemistry in the remediation of Cr(VI) runoff. 相似文献
216.
The development of essential services including water and sanitation in many megacities of the economically developing countries of Asia cannot keep pace with their rapidly growing population and accompanying urban and industrial development. The inadequate water supply and poor sanitation services lead to contamination of their water supply. It also leads to the input of sewage water into the groundwater. The problem is seriously acute in Karachi, the largest city in Pakistan with a population of over 12 million and growing at 6 percent. This paper examines the problem of water contamination in Karachi. The paper presents the data on water quality from various sources, mainly municipal water supply, vendors and well water; the three major sources of water for domestic use in Karachi. Except municipal water from some areas and during certain periods, water from most other sources contain coliform bacteria, and in many cases faecal coliform, in amounts several magnitudes higher than any standards permit. Many samples have also been found to contain heavy metals including Chromium, Lead, Nickel and Arsenic in amounts excessive of permitted standards. The probable sources of contaminants for the various types of water (piped, vendors, wells) indicate that groundwater may be the main contributor. The very source of this groundwater is predominantly from sewage. The health hazards from consuming such contaminated water are obvious. The paper also evaluates the solutions that are being practiced, proposed or may be feasible, as well as those that are evolving. 相似文献
217.
FeVO4/CeO2 was applied in the electro-Fenton (EF) degradation of Methyl Orange (MO) as a model of wastewater pollution. The results of the characterization techniques indicate that FeVO4 with triclinic structure and face-centered cubic fluorite CeO2 maintained their structures during the nanocomposite synthesis. The effect of applied current intensity, initial pollutant concentration, initial pH, and catalyst weight was investigated. The MO removal reached 96.31% and chemical oxygen demand (COD) removal 70% for 60 min of the reaction. The presence of CeO2 in the nanocomposite plays a key role in H2O2 electro-generation as a significant factor in the electro-Fenton (EF) system. The metal leaching from FeVO4/CeO2 was negligible (cerium 4.1%, iron 4.3%, and vanadium 1.7%), which indicates that the active species in the nanocomposite are strongly interacting with each other and are stable. The performance of the nanocatalyst in real wastewaters, salty, and binary systems was acceptable and the pollutions were removed efficiently. The synergistic effect between V, Fe, and Ce could be account as the reason for the respectable function of FeVO4/CeO2. The electron transfer proceeds via Haber-Weiss mechanism. A degradation pathway was proposed through by-products analysis using gas chromatography-mass spectrometry (GC–MS) technique. The pseudo-first-order kinetic model described the obtained experimental results (R2 = 0.9906). The electro-Fenton system efficiency was improved by adding persulfate. The nanocomposite preserved almost its efficiency after six cycles. The obtained results demonstrate that the synergistic catalyst (FeVO4/CeO2) has the capability to introduce as a promising replacement of conventional catalysts in the electro-Fenton processes with brilliant proficiency. 相似文献
218.
Health Impact of Injuries: A Population-Based Epidemiological Investigation in a Local Community of Bangladesh 总被引:1,自引:0,他引:1
Due to the lack of valid injury data, the objective of this study was to assess the injury morbidity and mortality in a local community of Bangladesh. A population-based survey of 3,258 households was conducted in 1996. The information was collected by trained field-level health workers using three pretested structured forms. The estimated crude morbidity from injuries was 311 per 1,000 population per year, and injury accounted for 13% of all morbidity. The children and old-age groups experienced higher injury rates than others, and male children aged 5–15 years had the highest incidence rates (546/1,000 person-years). Falls and cutting injuries tended to be the most frequently (62.4%) observed types of injuries in this survey. The home (42%) and workplace (42%) were where most of the injuries occurred, and the majority (70.7%) of the injuries were minor. Of all deaths, mortality from injuries was 2.9%, and drowning (27.8%) and homicide (16.7%) were found as common forms of injury-causing deaths. This study invites more detailed investigation on injury morbidity and mortality. 相似文献
219.
220.
Tabassum Mumtaz Noor Amalina Yahaya Suraini Abd-Aziz Nor’Aini Abdul Rahman Phang Lai Yee Yoshihito Shirai Mohd Ali Hassan 《Journal of Cleaner Production》2010,18(14):1393-1402
Palm oil industries have been contributing significantly towards the country’s economy and increase standard of living among Malaysians. However, it has also been identified as the major contributor for discharging the largest pollution load throughout the country. Owing to high biochemical oxygen demand (BOD) and chemical oxygen demand (COD), the palm oil mill effluent (POME) cannot be discharged directly into the environment. Thus, palm oil industries are facing tremendous challenges in order to comply with environmental regulations. While anaerobic digestion has been employed by most mills as primary treatment, POME can also be a potential source of degradable organic material which can be converted into value-added products and fine chemicals. Organic acids generated during acid-phase anaerobic digestion of POME could be a potential carbon source for the production of polyhydroxyalkanoates (PHA)- a biodegradable thermoplastic material of microbial origin. This paper aims at understanding how organic acids from POME may serve as a renewable feedstock for the biosynthesis of PHA. 相似文献